Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block

2,5-Bis(hydroxymethyl)furan is a highly valuable biobased rigid diol resembling aromatic monomers in polyester synthesis. In this work, it was enzymatically polymerized with various diacid ethyl esters by Candida antarctica Lipase B (CALB) via a three-stage method. A series of novel biobased furan p...

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Published in:Biomacromolecules
Main Authors: Jiang, Yi, Woortman, Albert J. J., Alberda van Ekenstein, Gerhard, Petrovic, Dejan M., Loos, Katja
Format: Article in Journal/Newspaper
Language:English
Published: 2014
Subjects:
ANTARCTICA LIPASE B
CROSS-LINKABLE POLYESTERS
CATALYZED SYNTHESIS
RENEWABLE RESOURCES
IMMOBILIZATION
POLYAMIDES
POLYMERS
GREEN
COPOLYMERIZATION
POLYMERIZATIONS
Antarc*
Antarctica
Online Access:https://hdl.handle.net/11370/1275555d-8a07-4938-9794-c01734ea7e8c
https://research.rug.nl/en/publications/1275555d-8a07-4938-9794-c01734ea7e8c
https://doi.org/10.1021/bm500340w
id ftunigroningenpu:oai:pure.rug.nl:publications/1275555d-8a07-4938-9794-c01734ea7e8c
record_format openpolar
spelling ftunigroningenpu:oai:pure.rug.nl:publications/1275555d-8a07-4938-9794-c01734ea7e8c 2024-06-23T07:47:55+00:00 Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block Jiang, Yi Woortman, Albert J. J. Alberda van Ekenstein, Gerhard Petrovic, Dejan M. Loos, Katja 2014-07 https://hdl.handle.net/11370/1275555d-8a07-4938-9794-c01734ea7e8c https://research.rug.nl/en/publications/1275555d-8a07-4938-9794-c01734ea7e8c https://doi.org/10.1021/bm500340w eng eng https://research.rug.nl/en/publications/1275555d-8a07-4938-9794-c01734ea7e8c info:eu-repo/semantics/closedAccess Jiang , Y , Woortman , A J J , Alberda van Ekenstein , G , Petrovic , D M & Loos , K 2014 , ' Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block ' , Biomacromolecules , vol. 15 , no. 7 , pp. 2482-2493 . https://doi.org/10.1021/bm500340w ANTARCTICA LIPASE B CROSS-LINKABLE POLYESTERS CATALYZED SYNTHESIS RENEWABLE RESOURCES IMMOBILIZATION POLYAMIDES POLYMERS GREEN COPOLYMERIZATION POLYMERIZATIONS article 2014 ftunigroningenpu https://doi.org/10.1021/bm500340w 2024-06-10T16:15:12Z 2,5-Bis(hydroxymethyl)furan is a highly valuable biobased rigid diol resembling aromatic monomers in polyester synthesis. In this work, it was enzymatically polymerized with various diacid ethyl esters by Candida antarctica Lipase B (CALB) via a three-stage method. A series of novel biobased furan polyesters with number-average molecular weights (M-n) around 2000 g/mol were successfully obtained. The chemical structures and physical properties of 2,5-bis(hydroxymethyl)furan-based polyesters were fully characterized. Furthermore, we discussed the effects of the number of the methylene units in the dicarboxylic segments on the physical properties of the furan polyesters. Article in Journal/Newspaper Antarc* Antarctica University of Groningen research database Biomacromolecules 15 7 2482 2493
institution Open Polar
collection University of Groningen research database
op_collection_id ftunigroningenpu
language English
topic ANTARCTICA LIPASE B
CROSS-LINKABLE POLYESTERS
CATALYZED SYNTHESIS
RENEWABLE RESOURCES
IMMOBILIZATION
POLYAMIDES
POLYMERS
GREEN
COPOLYMERIZATION
POLYMERIZATIONS
spellingShingle ANTARCTICA LIPASE B
CROSS-LINKABLE POLYESTERS
CATALYZED SYNTHESIS
RENEWABLE RESOURCES
IMMOBILIZATION
POLYAMIDES
POLYMERS
GREEN
COPOLYMERIZATION
POLYMERIZATIONS
Jiang, Yi
Woortman, Albert J. J.
Alberda van Ekenstein, Gerhard
Petrovic, Dejan M.
Loos, Katja
Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block
topic_facet ANTARCTICA LIPASE B
CROSS-LINKABLE POLYESTERS
CATALYZED SYNTHESIS
RENEWABLE RESOURCES
IMMOBILIZATION
POLYAMIDES
POLYMERS
GREEN
COPOLYMERIZATION
POLYMERIZATIONS
description 2,5-Bis(hydroxymethyl)furan is a highly valuable biobased rigid diol resembling aromatic monomers in polyester synthesis. In this work, it was enzymatically polymerized with various diacid ethyl esters by Candida antarctica Lipase B (CALB) via a three-stage method. A series of novel biobased furan polyesters with number-average molecular weights (M-n) around 2000 g/mol were successfully obtained. The chemical structures and physical properties of 2,5-bis(hydroxymethyl)furan-based polyesters were fully characterized. Furthermore, we discussed the effects of the number of the methylene units in the dicarboxylic segments on the physical properties of the furan polyesters.
format Article in Journal/Newspaper
author Jiang, Yi
Woortman, Albert J. J.
Alberda van Ekenstein, Gerhard
Petrovic, Dejan M.
Loos, Katja
author_facet Jiang, Yi
Woortman, Albert J. J.
Alberda van Ekenstein, Gerhard
Petrovic, Dejan M.
Loos, Katja
author_sort Jiang, Yi
title Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block
title_short Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block
title_full Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block
title_fullStr Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block
title_full_unstemmed Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block
title_sort enzymatic synthesis of biobased polyesters using 2,5-bis(hydroxymethyl)furan as the building block
publishDate 2014
url https://hdl.handle.net/11370/1275555d-8a07-4938-9794-c01734ea7e8c
https://research.rug.nl/en/publications/1275555d-8a07-4938-9794-c01734ea7e8c
https://doi.org/10.1021/bm500340w
genre Antarc*
Antarctica
genre_facet Antarc*
Antarctica
op_source Jiang , Y , Woortman , A J J , Alberda van Ekenstein , G , Petrovic , D M & Loos , K 2014 , ' Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block ' , Biomacromolecules , vol. 15 , no. 7 , pp. 2482-2493 . https://doi.org/10.1021/bm500340w
op_relation https://research.rug.nl/en/publications/1275555d-8a07-4938-9794-c01734ea7e8c
op_rights info:eu-repo/semantics/closedAccess
op_doi https://doi.org/10.1021/bm500340w
container_title Biomacromolecules
container_volume 15
container_issue 7
container_start_page 2482
op_container_end_page 2493
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