Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block
2,5-Bis(hydroxymethyl)furan is a highly valuable biobased rigid diol resembling aromatic monomers in polyester synthesis. In this work, it was enzymatically polymerized with various diacid ethyl esters by Candida antarctica Lipase B (CALB) via a three-stage method. A series of novel biobased furan p...
Published in: | Biomacromolecules |
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2014
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ftunigroningenpu:oai:pure.rug.nl:publications/1275555d-8a07-4938-9794-c01734ea7e8c 2024-06-23T07:47:55+00:00 Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block Jiang, Yi Woortman, Albert J. J. Alberda van Ekenstein, Gerhard Petrovic, Dejan M. Loos, Katja 2014-07 https://hdl.handle.net/11370/1275555d-8a07-4938-9794-c01734ea7e8c https://research.rug.nl/en/publications/1275555d-8a07-4938-9794-c01734ea7e8c https://doi.org/10.1021/bm500340w eng eng https://research.rug.nl/en/publications/1275555d-8a07-4938-9794-c01734ea7e8c info:eu-repo/semantics/closedAccess Jiang , Y , Woortman , A J J , Alberda van Ekenstein , G , Petrovic , D M & Loos , K 2014 , ' Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block ' , Biomacromolecules , vol. 15 , no. 7 , pp. 2482-2493 . https://doi.org/10.1021/bm500340w ANTARCTICA LIPASE B CROSS-LINKABLE POLYESTERS CATALYZED SYNTHESIS RENEWABLE RESOURCES IMMOBILIZATION POLYAMIDES POLYMERS GREEN COPOLYMERIZATION POLYMERIZATIONS article 2014 ftunigroningenpu https://doi.org/10.1021/bm500340w 2024-06-10T16:15:12Z 2,5-Bis(hydroxymethyl)furan is a highly valuable biobased rigid diol resembling aromatic monomers in polyester synthesis. In this work, it was enzymatically polymerized with various diacid ethyl esters by Candida antarctica Lipase B (CALB) via a three-stage method. A series of novel biobased furan polyesters with number-average molecular weights (M-n) around 2000 g/mol were successfully obtained. The chemical structures and physical properties of 2,5-bis(hydroxymethyl)furan-based polyesters were fully characterized. Furthermore, we discussed the effects of the number of the methylene units in the dicarboxylic segments on the physical properties of the furan polyesters. Article in Journal/Newspaper Antarc* Antarctica University of Groningen research database Biomacromolecules 15 7 2482 2493 |
institution |
Open Polar |
collection |
University of Groningen research database |
op_collection_id |
ftunigroningenpu |
language |
English |
topic |
ANTARCTICA LIPASE B CROSS-LINKABLE POLYESTERS CATALYZED SYNTHESIS RENEWABLE RESOURCES IMMOBILIZATION POLYAMIDES POLYMERS GREEN COPOLYMERIZATION POLYMERIZATIONS |
spellingShingle |
ANTARCTICA LIPASE B CROSS-LINKABLE POLYESTERS CATALYZED SYNTHESIS RENEWABLE RESOURCES IMMOBILIZATION POLYAMIDES POLYMERS GREEN COPOLYMERIZATION POLYMERIZATIONS Jiang, Yi Woortman, Albert J. J. Alberda van Ekenstein, Gerhard Petrovic, Dejan M. Loos, Katja Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block |
topic_facet |
ANTARCTICA LIPASE B CROSS-LINKABLE POLYESTERS CATALYZED SYNTHESIS RENEWABLE RESOURCES IMMOBILIZATION POLYAMIDES POLYMERS GREEN COPOLYMERIZATION POLYMERIZATIONS |
description |
2,5-Bis(hydroxymethyl)furan is a highly valuable biobased rigid diol resembling aromatic monomers in polyester synthesis. In this work, it was enzymatically polymerized with various diacid ethyl esters by Candida antarctica Lipase B (CALB) via a three-stage method. A series of novel biobased furan polyesters with number-average molecular weights (M-n) around 2000 g/mol were successfully obtained. The chemical structures and physical properties of 2,5-bis(hydroxymethyl)furan-based polyesters were fully characterized. Furthermore, we discussed the effects of the number of the methylene units in the dicarboxylic segments on the physical properties of the furan polyesters. |
format |
Article in Journal/Newspaper |
author |
Jiang, Yi Woortman, Albert J. J. Alberda van Ekenstein, Gerhard Petrovic, Dejan M. Loos, Katja |
author_facet |
Jiang, Yi Woortman, Albert J. J. Alberda van Ekenstein, Gerhard Petrovic, Dejan M. Loos, Katja |
author_sort |
Jiang, Yi |
title |
Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block |
title_short |
Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block |
title_full |
Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block |
title_fullStr |
Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block |
title_full_unstemmed |
Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block |
title_sort |
enzymatic synthesis of biobased polyesters using 2,5-bis(hydroxymethyl)furan as the building block |
publishDate |
2014 |
url |
https://hdl.handle.net/11370/1275555d-8a07-4938-9794-c01734ea7e8c https://research.rug.nl/en/publications/1275555d-8a07-4938-9794-c01734ea7e8c https://doi.org/10.1021/bm500340w |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
Jiang , Y , Woortman , A J J , Alberda van Ekenstein , G , Petrovic , D M & Loos , K 2014 , ' Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block ' , Biomacromolecules , vol. 15 , no. 7 , pp. 2482-2493 . https://doi.org/10.1021/bm500340w |
op_relation |
https://research.rug.nl/en/publications/1275555d-8a07-4938-9794-c01734ea7e8c |
op_rights |
info:eu-repo/semantics/closedAccess |
op_doi |
https://doi.org/10.1021/bm500340w |
container_title |
Biomacromolecules |
container_volume |
15 |
container_issue |
7 |
container_start_page |
2482 |
op_container_end_page |
2493 |
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1802638157932396544 |