Direct Determination of Rare Earth Elements at the Subpicogram per Gram Level in Antarctic Ice by ICP-SFMS Using a Desolvation System
International audience A method, based on inductively coupled plasma sector field mass spectrometry coupled with a microflow nebulizer and a desolvation system, has been developed for the direct determination of rare earth elements (REE) (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) down...
Published in: | Analytical Chemistry |
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Format: | Article in Journal/Newspaper |
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Online Access: | https://insu.hal.science/insu-00375470 https://doi.org/10.1021/ac0518957 |
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ftunigrenoble:oai:HAL:insu-00375470v1 2024-05-12T07:53:13+00:00 Direct Determination of Rare Earth Elements at the Subpicogram per Gram Level in Antarctic Ice by ICP-SFMS Using a Desolvation System Gabrielli, Paolo Barbante, Carlo Turetta, Clara Marteel, Alexandrine Boutron, Claude, F. Cozzi, Giulio Cairns, Warren, R. L. Ferrari, Christophe, P. Paolo Cescon, And Environmental Sciences Department University of Ca’ Foscari Venice, Italy Institute for the Dynamics of Environmental Processes-CNR Laboratoire de glaciologie et géophysique de l'environnement (LGGE) Observatoire des Sciences de l'Univers de Grenoble (OSUG) Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS) Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS) Polytech Grenoble European Project for Ice Coring in Antarctica (EPICA) 2006 https://insu.hal.science/insu-00375470 https://doi.org/10.1021/ac0518957 en eng HAL CCSD American Chemical Society info:eu-repo/semantics/altIdentifier/doi/10.1021/ac0518957 insu-00375470 https://insu.hal.science/insu-00375470 doi:10.1021/ac0518957 ISSN: 0003-2700 EISSN: 1520-6882 Analytical Chemistry https://insu.hal.science/insu-00375470 Analytical Chemistry, 2006, 78 (6), pp.1883 à 1889. ⟨10.1021/ac0518957⟩ [SDU.STU.GL]Sciences of the Universe [physics]/Earth Sciences/Glaciology info:eu-repo/semantics/article Journal articles 2006 ftunigrenoble https://doi.org/10.1021/ac0518957 2024-04-18T03:03:14Z International audience A method, based on inductively coupled plasma sector field mass spectrometry coupled with a microflow nebulizer and a desolvation system, has been developed for the direct determination of rare earth elements (REE) (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) down to the subpicogram per gram level (1 pg/g = 10-12 g g-1) in 1 mL of molten Antarctic ice. Contamination problems were carefully taken into account by adopting ultraclean procedures during the sample pretreatment phases. The use of a desolvation system for sample introduction during the analysis greatly reduced spectral interferences from oxide formation; the residual interfering contributions were calculated and subtracted whenever necessary. A matched calibration curve method was used for the quantification of the analytes. Instrumental detection limits ranged from 0.001 pg/g for Ho, Tm, and Lu to 0.03 pg/g for Gd. The precision, in terms of relative standard deviation on 10 replicates, ranged from 2% for La, Ce, Pr, and Lu, up to 10% for Er, Tm, and Yb. This methodology allowed the direct determination of REE in a 1-mL sample of ancient Antarctic ice with concentration ranges between 0.006 and 0.4 pg/g for Tm and 0.9−60 pg/g for Ce. Article in Journal/Newspaper Antarc* Antarctic Université Grenoble Alpes: HAL Antarctic Dy ENVELOPE(11.369,11.369,64.834,64.834) Analytical Chemistry 78 6 1883 1889 |
institution |
Open Polar |
collection |
Université Grenoble Alpes: HAL |
op_collection_id |
ftunigrenoble |
language |
English |
topic |
[SDU.STU.GL]Sciences of the Universe [physics]/Earth Sciences/Glaciology |
spellingShingle |
[SDU.STU.GL]Sciences of the Universe [physics]/Earth Sciences/Glaciology Gabrielli, Paolo Barbante, Carlo Turetta, Clara Marteel, Alexandrine Boutron, Claude, F. Cozzi, Giulio Cairns, Warren, R. L. Ferrari, Christophe, P. Paolo Cescon, And Direct Determination of Rare Earth Elements at the Subpicogram per Gram Level in Antarctic Ice by ICP-SFMS Using a Desolvation System |
topic_facet |
[SDU.STU.GL]Sciences of the Universe [physics]/Earth Sciences/Glaciology |
description |
International audience A method, based on inductively coupled plasma sector field mass spectrometry coupled with a microflow nebulizer and a desolvation system, has been developed for the direct determination of rare earth elements (REE) (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) down to the subpicogram per gram level (1 pg/g = 10-12 g g-1) in 1 mL of molten Antarctic ice. Contamination problems were carefully taken into account by adopting ultraclean procedures during the sample pretreatment phases. The use of a desolvation system for sample introduction during the analysis greatly reduced spectral interferences from oxide formation; the residual interfering contributions were calculated and subtracted whenever necessary. A matched calibration curve method was used for the quantification of the analytes. Instrumental detection limits ranged from 0.001 pg/g for Ho, Tm, and Lu to 0.03 pg/g for Gd. The precision, in terms of relative standard deviation on 10 replicates, ranged from 2% for La, Ce, Pr, and Lu, up to 10% for Er, Tm, and Yb. This methodology allowed the direct determination of REE in a 1-mL sample of ancient Antarctic ice with concentration ranges between 0.006 and 0.4 pg/g for Tm and 0.9−60 pg/g for Ce. |
author2 |
Environmental Sciences Department University of Ca’ Foscari Venice, Italy Institute for the Dynamics of Environmental Processes-CNR Laboratoire de glaciologie et géophysique de l'environnement (LGGE) Observatoire des Sciences de l'Univers de Grenoble (OSUG) Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS) Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS) Polytech Grenoble European Project for Ice Coring in Antarctica (EPICA) |
format |
Article in Journal/Newspaper |
author |
Gabrielli, Paolo Barbante, Carlo Turetta, Clara Marteel, Alexandrine Boutron, Claude, F. Cozzi, Giulio Cairns, Warren, R. L. Ferrari, Christophe, P. Paolo Cescon, And |
author_facet |
Gabrielli, Paolo Barbante, Carlo Turetta, Clara Marteel, Alexandrine Boutron, Claude, F. Cozzi, Giulio Cairns, Warren, R. L. Ferrari, Christophe, P. Paolo Cescon, And |
author_sort |
Gabrielli, Paolo |
title |
Direct Determination of Rare Earth Elements at the Subpicogram per Gram Level in Antarctic Ice by ICP-SFMS Using a Desolvation System |
title_short |
Direct Determination of Rare Earth Elements at the Subpicogram per Gram Level in Antarctic Ice by ICP-SFMS Using a Desolvation System |
title_full |
Direct Determination of Rare Earth Elements at the Subpicogram per Gram Level in Antarctic Ice by ICP-SFMS Using a Desolvation System |
title_fullStr |
Direct Determination of Rare Earth Elements at the Subpicogram per Gram Level in Antarctic Ice by ICP-SFMS Using a Desolvation System |
title_full_unstemmed |
Direct Determination of Rare Earth Elements at the Subpicogram per Gram Level in Antarctic Ice by ICP-SFMS Using a Desolvation System |
title_sort |
direct determination of rare earth elements at the subpicogram per gram level in antarctic ice by icp-sfms using a desolvation system |
publisher |
HAL CCSD |
publishDate |
2006 |
url |
https://insu.hal.science/insu-00375470 https://doi.org/10.1021/ac0518957 |
long_lat |
ENVELOPE(11.369,11.369,64.834,64.834) |
geographic |
Antarctic Dy |
geographic_facet |
Antarctic Dy |
genre |
Antarc* Antarctic |
genre_facet |
Antarc* Antarctic |
op_source |
ISSN: 0003-2700 EISSN: 1520-6882 Analytical Chemistry https://insu.hal.science/insu-00375470 Analytical Chemistry, 2006, 78 (6), pp.1883 à 1889. ⟨10.1021/ac0518957⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1021/ac0518957 insu-00375470 https://insu.hal.science/insu-00375470 doi:10.1021/ac0518957 |
op_doi |
https://doi.org/10.1021/ac0518957 |
container_title |
Analytical Chemistry |
container_volume |
78 |
container_issue |
6 |
container_start_page |
1883 |
op_container_end_page |
1889 |
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1798841574593921024 |