GEMAS: Chemical weathering of silicate parent materials revealed by agricultural soil of Europe
The chemical composition of soil represents to a large extent the primary mineralogy and geochemistry of the source bedrock, the effects of pre- and post-depositional weathering and element mobility, either by leaching or mineral sorting with the addition of secondary products such as clays. Agricul...
Published in: | Chemical Geology |
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Main Authors: | , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , |
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Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
2023
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Online Access: | https://hdl.handle.net/11585/952970 https://doi.org/10.1016/j.chemgeo.2023.121732 |
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ftunibolognairis:oai:cris.unibo.it:11585/952970 |
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openpolar |
institution |
Open Polar |
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IRIS Università degli Studi di Bologna (CRIS - Current Research Information System) |
op_collection_id |
ftunibolognairis |
language |
English |
topic |
Geochemistry Major element Mass balance Soil Ternary plot Weathering |
spellingShingle |
Geochemistry Major element Mass balance Soil Ternary plot Weathering Negrel P. Ladenberger A. Reimann C. Demetriades A. Birke M. Sadeghi M. Albanese S. Andersson M. Baritz R. Batista M. J. Bel-lan A. Cicchella D. De Vivo B. De Vos W. Dinelli E. Duris M. Dusza-Dobek A. Eklund M. Ernstsen V. Filzmoser P. Flem B. Flight D. M. A. Forrester S. Fuchs M. Fugedi U. Gilucis A. Gosar M. Gregorauskiene V. De Groot W. Gulan A. Halamic J. Haslinger E. Hayoz P. Hoffmann R. Hoogewerff J. Hrvatovic H. Husnjak S. Janik L. Jordan G. Kaminari M. Kirby J. Kivisilla J. Klos V. Krone F. Kwecko P. Kuti L. Lima A. Locutura J. Lucivjansky D. P. Mann A. Mackovych D. Matschullat J. McLaughlin M. Malyuk B. I. Maquil R. Meuli R. G. Mol G. O'Connor P. Oorts R. K. Ottesen R. T. Pasieczna A. Petersell W. Pfleiderer S. Ponavic M. Pramuka S. Prazeres C. Rauch U. Radusinovic S. Salpeteur I. Scanlon R. Schedl A. Scheib A. J. Schoeters I. Sefcik P. Sellersjo E. Skopljak F. Slaninka I. Sorsa A. Srvkota R. Stafilov T. Tarvainen T. Trendavilov V. Valera P. Verougstraete V. Vidojevic D. Zissimos A. Zomeni Z. GEMAS: Chemical weathering of silicate parent materials revealed by agricultural soil of Europe |
topic_facet |
Geochemistry Major element Mass balance Soil Ternary plot Weathering |
description |
The chemical composition of soil represents to a large extent the primary mineralogy and geochemistry of the source bedrock, the effects of pre- and post-depositional weathering and element mobility, either by leaching or mineral sorting with the addition of secondary products such as clays. Agricultural soil in Europe (0–20 cm, 33 countries, 5.6 million km2) was sampled during the continental-scale soil mapping project (GEochemical Mapping of Agricultural and grazing land Soil - GEMAS). Total element concentrations were determined by wavelength dispersive X-ray fluorescence spectrometry. Bulk content of major elements (SiO2, TiO2, Al2O3, Fe2O3, MgO, CaO, Na2O, K2O, P2O5) in soil has been used to calculate weathering indices such as chemical index of alteration (CIA), reductive and oxidative mafic indices of alteration (MIA), the change in mass balance (τ calculation relative to immobile Nb) for soil derived from silicate bedrocks (granite, gneiss and schist) at the European continental-scale, which are useful tools for evaluating chemical weathering trends. The greatest variation of CIA values is exhibited by soil derived from granite, followed by soil derived from schist. The CIA results show clearly that Ca and Na are removed from agricultural soil (0–20 cm) during soil development. Geographical distribution of weathering indices shows that weak chemical weathering of agricultural soil samples, sourced from gneissic and granitic bedrock, occurs in the Fennoscandian Shield; intermediate chemical weathering in granite, schist and gneiss occurring in the Iberian Peninsula and France, and intense chemical weathering in schist sourced agricultural soil occurring in areas with intense rainfall and moderate temperature (Wales, England, Ireland and western Iberia). In addition, values of CIA and MIA, higher than those for standard rock compositions, suggest more active enrichment/depletion processes during soil formation and subsequent soil weathering/maturation. The range of the elemental mass transfer coefficient τ ... |
author2 |
Negrel P. Ladenberger A. Reimann C. Demetriades A. Birke M. Sadeghi M. Albanese S. Andersson M. Baritz R. Batista M.J. Bel-lan A. Cicchella D. De Vivo B. De Vos W. Dinelli E. Duris M. Dusza-Dobek A. Eklund M. Ernstsen V. Filzmoser P. Flem B. Flight D.M.A. Forrester S. Fuchs M. Fugedi U. Gilucis A. Gosar M. Gregorauskiene V. De Groot W. Gulan A. Halamic J. Haslinger E. Hayoz P. Hoffmann R. Hoogewerff J. Hrvatovic H. Husnjak S. Janik L. Jordan G. Kaminari M. Kirby J. Kivisilla J. Klos V. Krone F. Kwecko P. Kuti L. Lima A. Locutura J. Lucivjansky D.P. Mann A. |
format |
Article in Journal/Newspaper |
author |
Negrel P. Ladenberger A. Reimann C. Demetriades A. Birke M. Sadeghi M. Albanese S. Andersson M. Baritz R. Batista M. J. Bel-lan A. Cicchella D. De Vivo B. De Vos W. Dinelli E. Duris M. Dusza-Dobek A. Eklund M. Ernstsen V. Filzmoser P. Flem B. Flight D. M. A. Forrester S. Fuchs M. Fugedi U. Gilucis A. Gosar M. Gregorauskiene V. De Groot W. Gulan A. Halamic J. Haslinger E. Hayoz P. Hoffmann R. Hoogewerff J. Hrvatovic H. Husnjak S. Janik L. Jordan G. Kaminari M. Kirby J. Kivisilla J. Klos V. Krone F. Kwecko P. Kuti L. Lima A. Locutura J. Lucivjansky D. P. Mann A. Mackovych D. Matschullat J. McLaughlin M. Malyuk B. I. Maquil R. Meuli R. G. Mol G. O'Connor P. Oorts R. K. Ottesen R. T. Pasieczna A. Petersell W. Pfleiderer S. Ponavic M. Pramuka S. Prazeres C. Rauch U. Radusinovic S. Salpeteur I. Scanlon R. Schedl A. Scheib A. J. Schoeters I. Sefcik P. Sellersjo E. Skopljak F. Slaninka I. Sorsa A. Srvkota R. Stafilov T. Tarvainen T. Trendavilov V. Valera P. Verougstraete V. Vidojevic D. Zissimos A. Zomeni Z. |
author_facet |
Negrel P. Ladenberger A. Reimann C. Demetriades A. Birke M. Sadeghi M. Albanese S. Andersson M. Baritz R. Batista M. J. Bel-lan A. Cicchella D. De Vivo B. De Vos W. Dinelli E. Duris M. Dusza-Dobek A. Eklund M. Ernstsen V. Filzmoser P. Flem B. Flight D. M. A. Forrester S. Fuchs M. Fugedi U. Gilucis A. Gosar M. Gregorauskiene V. De Groot W. Gulan A. Halamic J. Haslinger E. Hayoz P. Hoffmann R. Hoogewerff J. Hrvatovic H. Husnjak S. Janik L. Jordan G. Kaminari M. Kirby J. Kivisilla J. Klos V. Krone F. Kwecko P. Kuti L. Lima A. Locutura J. Lucivjansky D. P. Mann A. Mackovych D. Matschullat J. McLaughlin M. Malyuk B. I. Maquil R. Meuli R. G. Mol G. O'Connor P. Oorts R. K. Ottesen R. T. Pasieczna A. Petersell W. Pfleiderer S. Ponavic M. Pramuka S. Prazeres C. Rauch U. Radusinovic S. Salpeteur I. Scanlon R. Schedl A. Scheib A. J. Schoeters I. Sefcik P. Sellersjo E. Skopljak F. Slaninka I. Sorsa A. Srvkota R. Stafilov T. Tarvainen T. Trendavilov V. Valera P. Verougstraete V. Vidojevic D. Zissimos A. Zomeni Z. |
author_sort |
Negrel P. |
title |
GEMAS: Chemical weathering of silicate parent materials revealed by agricultural soil of Europe |
title_short |
GEMAS: Chemical weathering of silicate parent materials revealed by agricultural soil of Europe |
title_full |
GEMAS: Chemical weathering of silicate parent materials revealed by agricultural soil of Europe |
title_fullStr |
GEMAS: Chemical weathering of silicate parent materials revealed by agricultural soil of Europe |
title_full_unstemmed |
GEMAS: Chemical weathering of silicate parent materials revealed by agricultural soil of Europe |
title_sort |
gemas: chemical weathering of silicate parent materials revealed by agricultural soil of europe |
publishDate |
2023 |
url |
https://hdl.handle.net/11585/952970 https://doi.org/10.1016/j.chemgeo.2023.121732 |
genre |
Fennoscandian |
genre_facet |
Fennoscandian |
op_relation |
info:eu-repo/semantics/altIdentifier/wos/WOS:001084013000001 volume:639 firstpage:1 lastpage:14 numberofpages:14 journal:CHEMICAL GEOLOGY https://hdl.handle.net/11585/952970 doi:10.1016/j.chemgeo.2023.121732 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85171527894 |
op_doi |
https://doi.org/10.1016/j.chemgeo.2023.121732 |
container_title |
Chemical Geology |
container_volume |
639 |
container_start_page |
121732 |
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1796309207386947584 |
spelling |
ftunibolognairis:oai:cris.unibo.it:11585/952970 2024-04-14T08:11:30+00:00 GEMAS: Chemical weathering of silicate parent materials revealed by agricultural soil of Europe Negrel P. Ladenberger A. Reimann C. Demetriades A. Birke M. Sadeghi M. Albanese S. Andersson M. Baritz R. Batista M. J. Bel-lan A. Cicchella D. De Vivo B. De Vos W. Dinelli E. Duris M. Dusza-Dobek A. Eklund M. Ernstsen V. Filzmoser P. Flem B. Flight D. M. A. Forrester S. Fuchs M. Fugedi U. Gilucis A. Gosar M. Gregorauskiene V. De Groot W. Gulan A. Halamic J. Haslinger E. Hayoz P. Hoffmann R. Hoogewerff J. Hrvatovic H. Husnjak S. Janik L. Jordan G. Kaminari M. Kirby J. Kivisilla J. Klos V. Krone F. Kwecko P. Kuti L. Lima A. Locutura J. Lucivjansky D. P. Mann A. Mackovych D. Matschullat J. McLaughlin M. Malyuk B. I. Maquil R. Meuli R. G. Mol G. O'Connor P. Oorts R. K. Ottesen R. T. Pasieczna A. Petersell W. Pfleiderer S. Ponavic M. Pramuka S. Prazeres C. Rauch U. Radusinovic S. Salpeteur I. Scanlon R. Schedl A. Scheib A. J. Schoeters I. Sefcik P. Sellersjo E. Skopljak F. Slaninka I. Sorsa A. Srvkota R. Stafilov T. Tarvainen T. Trendavilov V. Valera P. Verougstraete V. Vidojevic D. Zissimos A. Zomeni Z. Negrel P. Ladenberger A. Reimann C. Demetriades A. Birke M. Sadeghi M. Albanese S. Andersson M. Baritz R. Batista M.J. Bel-lan A. Cicchella D. De Vivo B. De Vos W. Dinelli E. Duris M. Dusza-Dobek A. Eklund M. Ernstsen V. Filzmoser P. Flem B. Flight D.M.A. Forrester S. Fuchs M. Fugedi U. Gilucis A. Gosar M. Gregorauskiene V. De Groot W. Gulan A. Halamic J. Haslinger E. Hayoz P. Hoffmann R. Hoogewerff J. Hrvatovic H. Husnjak S. Janik L. Jordan G. Kaminari M. Kirby J. Kivisilla J. Klos V. Krone F. Kwecko P. Kuti L. Lima A. Locutura J. Lucivjansky D.P. Mann A. 2023 STAMPA https://hdl.handle.net/11585/952970 https://doi.org/10.1016/j.chemgeo.2023.121732 eng eng info:eu-repo/semantics/altIdentifier/wos/WOS:001084013000001 volume:639 firstpage:1 lastpage:14 numberofpages:14 journal:CHEMICAL GEOLOGY https://hdl.handle.net/11585/952970 doi:10.1016/j.chemgeo.2023.121732 info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85171527894 Geochemistry Major element Mass balance Soil Ternary plot Weathering info:eu-repo/semantics/article 2023 ftunibolognairis https://doi.org/10.1016/j.chemgeo.2023.121732 2024-03-21T16:47:40Z The chemical composition of soil represents to a large extent the primary mineralogy and geochemistry of the source bedrock, the effects of pre- and post-depositional weathering and element mobility, either by leaching or mineral sorting with the addition of secondary products such as clays. Agricultural soil in Europe (0–20 cm, 33 countries, 5.6 million km2) was sampled during the continental-scale soil mapping project (GEochemical Mapping of Agricultural and grazing land Soil - GEMAS). Total element concentrations were determined by wavelength dispersive X-ray fluorescence spectrometry. Bulk content of major elements (SiO2, TiO2, Al2O3, Fe2O3, MgO, CaO, Na2O, K2O, P2O5) in soil has been used to calculate weathering indices such as chemical index of alteration (CIA), reductive and oxidative mafic indices of alteration (MIA), the change in mass balance (τ calculation relative to immobile Nb) for soil derived from silicate bedrocks (granite, gneiss and schist) at the European continental-scale, which are useful tools for evaluating chemical weathering trends. The greatest variation of CIA values is exhibited by soil derived from granite, followed by soil derived from schist. The CIA results show clearly that Ca and Na are removed from agricultural soil (0–20 cm) during soil development. Geographical distribution of weathering indices shows that weak chemical weathering of agricultural soil samples, sourced from gneissic and granitic bedrock, occurs in the Fennoscandian Shield; intermediate chemical weathering in granite, schist and gneiss occurring in the Iberian Peninsula and France, and intense chemical weathering in schist sourced agricultural soil occurring in areas with intense rainfall and moderate temperature (Wales, England, Ireland and western Iberia). In addition, values of CIA and MIA, higher than those for standard rock compositions, suggest more active enrichment/depletion processes during soil formation and subsequent soil weathering/maturation. The range of the elemental mass transfer coefficient τ ... Article in Journal/Newspaper Fennoscandian IRIS Università degli Studi di Bologna (CRIS - Current Research Information System) Chemical Geology 639 121732 |