The polar sulfur cycle in the Werenskioldbreen, Spitsbergen:Possible implications for understanding the deposition of sulfate minerals in the North Polar Region of Mars
In this study we investigated the polar cycling of sulfur (S) associated with the Werenskioldbreen glacier in Spitsbergen (Svalbard). Sulfide-derived S comprised 0.02-0.42wt% of the fine-grained fraction of proglacial sediments. These sediments originated from glacial erosion of Precambrian sulfide-...
Published in: | Geochimica et Cosmochimica Acta |
---|---|
Main Authors: | , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
2013
|
Subjects: | |
Online Access: | https://pure.au.dk/portal/da/publications/the-polar-sulfur-cycle-in-the-werenskioldbreen-spitsbergen(caa5ecad-5e9a-47d6-b920-a4276bc592eb).html https://doi.org/10.1016/j.gca.2012.12.041 http://www.scopus.com/inward/record.url?scp=84873418839&partnerID=8YFLogxK |
id |
ftuniaarhuspubl:oai:pure.atira.dk:publications/caa5ecad-5e9a-47d6-b920-a4276bc592eb |
---|---|
record_format |
openpolar |
spelling |
ftuniaarhuspubl:oai:pure.atira.dk:publications/caa5ecad-5e9a-47d6-b920-a4276bc592eb 2023-12-24T10:16:58+01:00 The polar sulfur cycle in the Werenskioldbreen, Spitsbergen:Possible implications for understanding the deposition of sulfate minerals in the North Polar Region of Mars Szynkiewicz, Anna Modelska, Magdalena Buczyński, Sebastian Borrok, David M. Merrison, Jonathan P. 2013-04-01 https://pure.au.dk/portal/da/publications/the-polar-sulfur-cycle-in-the-werenskioldbreen-spitsbergen(caa5ecad-5e9a-47d6-b920-a4276bc592eb).html https://doi.org/10.1016/j.gca.2012.12.041 http://www.scopus.com/inward/record.url?scp=84873418839&partnerID=8YFLogxK eng eng https://pure.au.dk/portal/da/publications/the-polar-sulfur-cycle-in-the-werenskioldbreen-spitsbergen(caa5ecad-5e9a-47d6-b920-a4276bc592eb).html info:eu-repo/semantics/restrictedAccess Szynkiewicz , A , Modelska , M , Buczyński , S , Borrok , D M & Merrison , J P 2013 , ' The polar sulfur cycle in the Werenskioldbreen, Spitsbergen : Possible implications for understanding the deposition of sulfate minerals in the North Polar Region of Mars ' , Geochimica et Cosmochimica Acta , vol. 106 , pp. 326-343 . https://doi.org/10.1016/j.gca.2012.12.041 article 2013 ftuniaarhuspubl https://doi.org/10.1016/j.gca.2012.12.041 2023-11-29T23:59:12Z In this study we investigated the polar cycling of sulfur (S) associated with the Werenskioldbreen glacier in Spitsbergen (Svalbard). Sulfide-derived S comprised 0.02-0.42wt% of the fine-grained fraction of proglacial sediments. These sediments originated from glacial erosion of Precambrian sulfide-rich quartz and carbonate veins. In summer 2008, the δ 34 S of dissolved SO 4 in glacier melt waters (+9‰ to +17‰) was consistent with SO 4 generation from oxidation of primary sulfide minerals in the bedrock (+9‰ to +16‰). The calculated monthly SO 4 load was ~6881kg/month/km 2 in the main glacier stream. Subsequent evaporation and freezing of glacial waters lead to precipitation, accumulation, and temporary storage of sulfate salt efflorescences in the proglacial zone. These salts are presumably ephemeral, as they dissolve during annual snow/glacial melt events.Hydrated sulfates such as gypsum are also important constituents of the low-elevation areas around the polar ice cap of Planum Boreum on Mars. The origin of this gypsum on Mars might be better understood by using the investigated polar S cycle in Spitsbergen as a foundation. Assuming a trace sulfide content in the basaltic bedrock on Mars, the weathering of sulfides within the fine, porous texture of the ancient aeolian strata (basal unit) underlying Planum Boreum could have created elevated SO 4 fluxes (and gypsum precipitation) during episodic thawing/melting events in the past. Limited water activity and prevailing dry conditions on the surface of Mars are the likely factors that accounted for the larger accumulation and preservation of polar gypsum on the surface and its broad aeolian distribution around Planum Boreum. This suggestion is also supported by an experiment showing that gypsum sand can be transported, under dry conditions, over great distances (~2000km) without a significant loss of mass. Article in Journal/Newspaper glacier Ice cap Svalbard Spitsbergen Aarhus University: Research Svalbard Werenskioldbreen ENVELOPE(15.336,15.336,77.077,77.077) Geochimica et Cosmochimica Acta 106 326 343 |
institution |
Open Polar |
collection |
Aarhus University: Research |
op_collection_id |
ftuniaarhuspubl |
language |
English |
description |
In this study we investigated the polar cycling of sulfur (S) associated with the Werenskioldbreen glacier in Spitsbergen (Svalbard). Sulfide-derived S comprised 0.02-0.42wt% of the fine-grained fraction of proglacial sediments. These sediments originated from glacial erosion of Precambrian sulfide-rich quartz and carbonate veins. In summer 2008, the δ 34 S of dissolved SO 4 in glacier melt waters (+9‰ to +17‰) was consistent with SO 4 generation from oxidation of primary sulfide minerals in the bedrock (+9‰ to +16‰). The calculated monthly SO 4 load was ~6881kg/month/km 2 in the main glacier stream. Subsequent evaporation and freezing of glacial waters lead to precipitation, accumulation, and temporary storage of sulfate salt efflorescences in the proglacial zone. These salts are presumably ephemeral, as they dissolve during annual snow/glacial melt events.Hydrated sulfates such as gypsum are also important constituents of the low-elevation areas around the polar ice cap of Planum Boreum on Mars. The origin of this gypsum on Mars might be better understood by using the investigated polar S cycle in Spitsbergen as a foundation. Assuming a trace sulfide content in the basaltic bedrock on Mars, the weathering of sulfides within the fine, porous texture of the ancient aeolian strata (basal unit) underlying Planum Boreum could have created elevated SO 4 fluxes (and gypsum precipitation) during episodic thawing/melting events in the past. Limited water activity and prevailing dry conditions on the surface of Mars are the likely factors that accounted for the larger accumulation and preservation of polar gypsum on the surface and its broad aeolian distribution around Planum Boreum. This suggestion is also supported by an experiment showing that gypsum sand can be transported, under dry conditions, over great distances (~2000km) without a significant loss of mass. |
format |
Article in Journal/Newspaper |
author |
Szynkiewicz, Anna Modelska, Magdalena Buczyński, Sebastian Borrok, David M. Merrison, Jonathan P. |
spellingShingle |
Szynkiewicz, Anna Modelska, Magdalena Buczyński, Sebastian Borrok, David M. Merrison, Jonathan P. The polar sulfur cycle in the Werenskioldbreen, Spitsbergen:Possible implications for understanding the deposition of sulfate minerals in the North Polar Region of Mars |
author_facet |
Szynkiewicz, Anna Modelska, Magdalena Buczyński, Sebastian Borrok, David M. Merrison, Jonathan P. |
author_sort |
Szynkiewicz, Anna |
title |
The polar sulfur cycle in the Werenskioldbreen, Spitsbergen:Possible implications for understanding the deposition of sulfate minerals in the North Polar Region of Mars |
title_short |
The polar sulfur cycle in the Werenskioldbreen, Spitsbergen:Possible implications for understanding the deposition of sulfate minerals in the North Polar Region of Mars |
title_full |
The polar sulfur cycle in the Werenskioldbreen, Spitsbergen:Possible implications for understanding the deposition of sulfate minerals in the North Polar Region of Mars |
title_fullStr |
The polar sulfur cycle in the Werenskioldbreen, Spitsbergen:Possible implications for understanding the deposition of sulfate minerals in the North Polar Region of Mars |
title_full_unstemmed |
The polar sulfur cycle in the Werenskioldbreen, Spitsbergen:Possible implications for understanding the deposition of sulfate minerals in the North Polar Region of Mars |
title_sort |
polar sulfur cycle in the werenskioldbreen, spitsbergen:possible implications for understanding the deposition of sulfate minerals in the north polar region of mars |
publishDate |
2013 |
url |
https://pure.au.dk/portal/da/publications/the-polar-sulfur-cycle-in-the-werenskioldbreen-spitsbergen(caa5ecad-5e9a-47d6-b920-a4276bc592eb).html https://doi.org/10.1016/j.gca.2012.12.041 http://www.scopus.com/inward/record.url?scp=84873418839&partnerID=8YFLogxK |
long_lat |
ENVELOPE(15.336,15.336,77.077,77.077) |
geographic |
Svalbard Werenskioldbreen |
geographic_facet |
Svalbard Werenskioldbreen |
genre |
glacier Ice cap Svalbard Spitsbergen |
genre_facet |
glacier Ice cap Svalbard Spitsbergen |
op_source |
Szynkiewicz , A , Modelska , M , Buczyński , S , Borrok , D M & Merrison , J P 2013 , ' The polar sulfur cycle in the Werenskioldbreen, Spitsbergen : Possible implications for understanding the deposition of sulfate minerals in the North Polar Region of Mars ' , Geochimica et Cosmochimica Acta , vol. 106 , pp. 326-343 . https://doi.org/10.1016/j.gca.2012.12.041 |
op_relation |
https://pure.au.dk/portal/da/publications/the-polar-sulfur-cycle-in-the-werenskioldbreen-spitsbergen(caa5ecad-5e9a-47d6-b920-a4276bc592eb).html |
op_rights |
info:eu-repo/semantics/restrictedAccess |
op_doi |
https://doi.org/10.1016/j.gca.2012.12.041 |
container_title |
Geochimica et Cosmochimica Acta |
container_volume |
106 |
container_start_page |
326 |
op_container_end_page |
343 |
_version_ |
1786204715327946752 |