Effects of carbon dioxide hydration kinetics and evaporative convection on pH profile development during interfacial mass transfer of ammonia and carbon dioxide
Interfacial mass transfer of and are important in processes as diverse as emission from animal manure and gas scrubbing for removal of carbon dioxide. Predicting transfer rates is complicated by bidirectional interactions between solution pH and emission rates, which may be affected by physical, che...
Published in: | Heat and Mass Transfer |
---|---|
Main Authors: | , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
2017
|
Subjects: | |
Online Access: | https://pure.au.dk/portal/da/publications/effects-of-carbon-dioxide-hydration-kinetics-and-evaporative-convection-on-ph-profile-development-during-interfacial-mass-transfer-of-ammonia-and-carbon-dioxide(2ab5e244-f7b6-4393-af8e-55745501edd8).html https://doi.org/10.1007/s00231-016-1910-6 |
id |
ftuniaarhuspubl:oai:pure.atira.dk:publications/2ab5e244-f7b6-4393-af8e-55745501edd8 |
---|---|
record_format |
openpolar |
spelling |
ftuniaarhuspubl:oai:pure.atira.dk:publications/2ab5e244-f7b6-4393-af8e-55745501edd8 2023-05-15T15:52:54+02:00 Effects of carbon dioxide hydration kinetics and evaporative convection on pH profile development during interfacial mass transfer of ammonia and carbon dioxide Hafner, Sasha D Sommer, Sven G. Petersen, Valdemar Markfoged, Rikke 2017 https://pure.au.dk/portal/da/publications/effects-of-carbon-dioxide-hydration-kinetics-and-evaporative-convection-on-ph-profile-development-during-interfacial-mass-transfer-of-ammonia-and-carbon-dioxide(2ab5e244-f7b6-4393-af8e-55745501edd8).html https://doi.org/10.1007/s00231-016-1910-6 eng eng info:eu-repo/semantics/restrictedAccess Hafner , S D , Sommer , S G , Petersen , V & Markfoged , R 2017 , ' Effects of carbon dioxide hydration kinetics and evaporative convection on pH profile development during interfacial mass transfer of ammonia and carbon dioxide ' , Heat and Mass Transfer , vol. 53 , no. 4 , pp. 1335-1342 . https://doi.org/10.1007/s00231-016-1910-6 AIR WATER TEMPERATURE ANHYDRASES EXCHANGE GASES article 2017 ftuniaarhuspubl https://doi.org/10.1007/s00231-016-1910-6 2020-09-16T22:44:15Z Interfacial mass transfer of and are important in processes as diverse as emission from animal manure and gas scrubbing for removal of carbon dioxide. Predicting transfer rates is complicated by bidirectional interactions between solution pH and emission rates, which may be affected by physical, chemical, and biological processes. We studied the effects of hydration kinetics and evaporative convection on the development of pH profiles in solutions undergoing simultaneous emission of and . Profiles of pH were measured at a 0.1 mm resolution over 15 h, and interpreted using a reaction-transport model. Under high humidity, surface pH increased quickly (> 0.2 units in 8 min) and an increase gradually extended to deeper depths. An increase in hydration and carbonic acid dehydration rates by addition of carbonic anhydrase increased the elevation of surface pH and the depth to which an increase extended, due to an increase in emission. Results show that unless carbonic anhydrase is present, the equilibrium approach typically used for modeling interfacial transport of and will be inaccurate. Evaporation and resulting convection greatly increased mass transfer rates below an apparent surface film about 1 mm thick. Emission or absorption of can produce steep gradients in pH over small distances (<0.5 to > 20 mm) in systems with and without convective mixing, and the resulting surface pH, in turn, strongly affects transfer. Both convection and the rate of hydration/dehydration reactions are likely to affect pH profile development and rates of and transfer in many systems. Accurately predicting mass transfer rates for these systems will require an understanding of these processes in the systems. Article in Journal/Newspaper Carbonic acid Aarhus University: Research Heat and Mass Transfer 53 4 1335 1342 |
institution |
Open Polar |
collection |
Aarhus University: Research |
op_collection_id |
ftuniaarhuspubl |
language |
English |
topic |
AIR WATER TEMPERATURE ANHYDRASES EXCHANGE GASES |
spellingShingle |
AIR WATER TEMPERATURE ANHYDRASES EXCHANGE GASES Hafner, Sasha D Sommer, Sven G. Petersen, Valdemar Markfoged, Rikke Effects of carbon dioxide hydration kinetics and evaporative convection on pH profile development during interfacial mass transfer of ammonia and carbon dioxide |
topic_facet |
AIR WATER TEMPERATURE ANHYDRASES EXCHANGE GASES |
description |
Interfacial mass transfer of and are important in processes as diverse as emission from animal manure and gas scrubbing for removal of carbon dioxide. Predicting transfer rates is complicated by bidirectional interactions between solution pH and emission rates, which may be affected by physical, chemical, and biological processes. We studied the effects of hydration kinetics and evaporative convection on the development of pH profiles in solutions undergoing simultaneous emission of and . Profiles of pH were measured at a 0.1 mm resolution over 15 h, and interpreted using a reaction-transport model. Under high humidity, surface pH increased quickly (> 0.2 units in 8 min) and an increase gradually extended to deeper depths. An increase in hydration and carbonic acid dehydration rates by addition of carbonic anhydrase increased the elevation of surface pH and the depth to which an increase extended, due to an increase in emission. Results show that unless carbonic anhydrase is present, the equilibrium approach typically used for modeling interfacial transport of and will be inaccurate. Evaporation and resulting convection greatly increased mass transfer rates below an apparent surface film about 1 mm thick. Emission or absorption of can produce steep gradients in pH over small distances (<0.5 to > 20 mm) in systems with and without convective mixing, and the resulting surface pH, in turn, strongly affects transfer. Both convection and the rate of hydration/dehydration reactions are likely to affect pH profile development and rates of and transfer in many systems. Accurately predicting mass transfer rates for these systems will require an understanding of these processes in the systems. |
format |
Article in Journal/Newspaper |
author |
Hafner, Sasha D Sommer, Sven G. Petersen, Valdemar Markfoged, Rikke |
author_facet |
Hafner, Sasha D Sommer, Sven G. Petersen, Valdemar Markfoged, Rikke |
author_sort |
Hafner, Sasha D |
title |
Effects of carbon dioxide hydration kinetics and evaporative convection on pH profile development during interfacial mass transfer of ammonia and carbon dioxide |
title_short |
Effects of carbon dioxide hydration kinetics and evaporative convection on pH profile development during interfacial mass transfer of ammonia and carbon dioxide |
title_full |
Effects of carbon dioxide hydration kinetics and evaporative convection on pH profile development during interfacial mass transfer of ammonia and carbon dioxide |
title_fullStr |
Effects of carbon dioxide hydration kinetics and evaporative convection on pH profile development during interfacial mass transfer of ammonia and carbon dioxide |
title_full_unstemmed |
Effects of carbon dioxide hydration kinetics and evaporative convection on pH profile development during interfacial mass transfer of ammonia and carbon dioxide |
title_sort |
effects of carbon dioxide hydration kinetics and evaporative convection on ph profile development during interfacial mass transfer of ammonia and carbon dioxide |
publishDate |
2017 |
url |
https://pure.au.dk/portal/da/publications/effects-of-carbon-dioxide-hydration-kinetics-and-evaporative-convection-on-ph-profile-development-during-interfacial-mass-transfer-of-ammonia-and-carbon-dioxide(2ab5e244-f7b6-4393-af8e-55745501edd8).html https://doi.org/10.1007/s00231-016-1910-6 |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_source |
Hafner , S D , Sommer , S G , Petersen , V & Markfoged , R 2017 , ' Effects of carbon dioxide hydration kinetics and evaporative convection on pH profile development during interfacial mass transfer of ammonia and carbon dioxide ' , Heat and Mass Transfer , vol. 53 , no. 4 , pp. 1335-1342 . https://doi.org/10.1007/s00231-016-1910-6 |
op_rights |
info:eu-repo/semantics/restrictedAccess |
op_doi |
https://doi.org/10.1007/s00231-016-1910-6 |
container_title |
Heat and Mass Transfer |
container_volume |
53 |
container_issue |
4 |
container_start_page |
1335 |
op_container_end_page |
1342 |
_version_ |
1766387991323869184 |