Mid-IR spectroscopy and structural features of protonated carbonic acid in the gas phase

(Graph Presented) An anti trihydroxycarbenium ion is revealed to be the gas-phase structure of protonated carbonic acid by IR multiple-photon dissociation spectroscopy (see picture for calculated structure and comparison of experimental and computed spectra). Deprotonation yields anti-H 2CO3 with a...

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Main Authors: Chiavarino, Barbara, Crestoni, Maria Elisa, Fornarini, Simonetta, Lanucara, Francesco, Lemaire, Joel, Maitre, Philippe
Format: Article in Journal/Newspaper
Language:English
Published: 2009
Subjects:
Carbonic acid
Density functional calculations
Ion cyclotron resonance
IR spectroscopy
Protonation
Online Access:https://research.manchester.ac.uk/en/publications/018813cb-3997-4e9d-a921-c22423adb66b
http://www3.interscience.wiley.com/cgi-bin/fulltext/121661597/PDFSTART
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spelling ftumanchesterpub:oai:pure.atira.dk:publications/018813cb-3997-4e9d-a921-c22423adb66b 2023-11-12T04:15:46+01:00 Mid-IR spectroscopy and structural features of protonated carbonic acid in the gas phase Chiavarino, Barbara Crestoni, Maria Elisa Fornarini, Simonetta Lanucara, Francesco Lemaire, Joel Maitre, Philippe 2009-02-23 https://research.manchester.ac.uk/en/publications/018813cb-3997-4e9d-a921-c22423adb66b http://www3.interscience.wiley.com/cgi-bin/fulltext/121661597/PDFSTART eng eng info:eu-repo/semantics/restrictedAccess Chiavarino , B , Crestoni , M E , Fornarini , S , Lanucara , F , Lemaire , J & Maitre , P 2009 , ' Mid-IR spectroscopy and structural features of protonated carbonic acid in the gas phase ' , ChemPhysChem , vol. 10 , no. 3 , pp. 520-522 . < http://www3.interscience.wiley.com/cgi-bin/fulltext/121661597/PDFSTART > Carbonic acid Density functional calculations Ion cyclotron resonance IR spectroscopy Protonation article 2009 ftumanchesterpub 2023-10-30T09:10:59Z (Graph Presented) An anti trihydroxycarbenium ion is revealed to be the gas-phase structure of protonated carbonic acid by IR multiple-photon dissociation spectroscopy (see picture for calculated structure and comparison of experimental and computed spectra). Deprotonation yields anti-H 2CO3 with a nominal gas-phase basicity of 724 kJ mol -1. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA. Article in Journal/Newspaper Carbonic acid The University of Manchester: Research Explorer
institution Open Polar
collection The University of Manchester: Research Explorer
op_collection_id ftumanchesterpub
language English
topic Carbonic acid
Density functional calculations
Ion cyclotron resonance
IR spectroscopy
Protonation
spellingShingle Carbonic acid
Density functional calculations
Ion cyclotron resonance
IR spectroscopy
Protonation
Chiavarino, Barbara
Crestoni, Maria Elisa
Fornarini, Simonetta
Lanucara, Francesco
Lemaire, Joel
Maitre, Philippe
Mid-IR spectroscopy and structural features of protonated carbonic acid in the gas phase
topic_facet Carbonic acid
Density functional calculations
Ion cyclotron resonance
IR spectroscopy
Protonation
description (Graph Presented) An anti trihydroxycarbenium ion is revealed to be the gas-phase structure of protonated carbonic acid by IR multiple-photon dissociation spectroscopy (see picture for calculated structure and comparison of experimental and computed spectra). Deprotonation yields anti-H 2CO3 with a nominal gas-phase basicity of 724 kJ mol -1. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
format Article in Journal/Newspaper
author Chiavarino, Barbara
Crestoni, Maria Elisa
Fornarini, Simonetta
Lanucara, Francesco
Lemaire, Joel
Maitre, Philippe
author_facet Chiavarino, Barbara
Crestoni, Maria Elisa
Fornarini, Simonetta
Lanucara, Francesco
Lemaire, Joel
Maitre, Philippe
author_sort Chiavarino, Barbara
title Mid-IR spectroscopy and structural features of protonated carbonic acid in the gas phase
title_short Mid-IR spectroscopy and structural features of protonated carbonic acid in the gas phase
title_full Mid-IR spectroscopy and structural features of protonated carbonic acid in the gas phase
title_fullStr Mid-IR spectroscopy and structural features of protonated carbonic acid in the gas phase
title_full_unstemmed Mid-IR spectroscopy and structural features of protonated carbonic acid in the gas phase
title_sort mid-ir spectroscopy and structural features of protonated carbonic acid in the gas phase
publishDate 2009
url https://research.manchester.ac.uk/en/publications/018813cb-3997-4e9d-a921-c22423adb66b
http://www3.interscience.wiley.com/cgi-bin/fulltext/121661597/PDFSTART
genre Carbonic acid
genre_facet Carbonic acid
op_source Chiavarino , B , Crestoni , M E , Fornarini , S , Lanucara , F , Lemaire , J & Maitre , P 2009 , ' Mid-IR spectroscopy and structural features of protonated carbonic acid in the gas phase ' , ChemPhysChem , vol. 10 , no. 3 , pp. 520-522 . < http://www3.interscience.wiley.com/cgi-bin/fulltext/121661597/PDFSTART >
op_rights info:eu-repo/semantics/restrictedAccess
_version_ 1782333042136711168

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