Mercury in sediment core samples from deep Siberian ice-rich permafrost
We determine Hg concentrations of various deposits in Siberia’s deep permafrost and link sediment properties and Hg enrichment to establish a first Hg inventory of late Pleistocene permafrost down to a depth of 36 m below surface. As Arctic warming is transforming the ice-rich permafrost of Siberia,...
Published in: | Frontiers in Earth Science |
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2021
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ftufz:oai:ufz.de:25021 2023-12-10T09:44:37+01:00 Mercury in sediment core samples from deep Siberian ice-rich permafrost Rutkowski, C. Lenz, J. Lang, A. Wolter, J. Mothes, Sibylle Reemtsma, Thorsten Grosse, G. Ulrich, M. Fuchs, M. Schirrmeister, L. Fedorov, A. Grigoriev, M. Lantuit, H. Strauss, J. 2021-09-03 application/pdf https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=25021 https://doi.org/10.3389/feart.2021.718153 en eng Frontiers Media, Lausanne Frontiers in Earth Science 9;; art. 718153 https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=25021 https://dx.doi.org/10.3389/feart.2021.718153 info:eu-repo/semantics/openAccess ISSN: 2296-6463 Arctic pollutants heavy metal Arctic warming Polar regions info:eu-repo/semantics/article https://purl.org/dc/dcmitype/Text 2021 ftufz https://doi.org/10.3389/feart.2021.718153 2023-11-12T23:36:49Z We determine Hg concentrations of various deposits in Siberia’s deep permafrost and link sediment properties and Hg enrichment to establish a first Hg inventory of late Pleistocene permafrost down to a depth of 36 m below surface. As Arctic warming is transforming the ice-rich permafrost of Siberia, sediment is released and increases the flux of particulates to the Arctic shelf seas through thawing coasts, lakeshores, and river floodplains. Heavy metals within soils and sediments are also released and may increasingly enter Arctic waters and the biological food chain. High levels of mercury (Hg) have been reported from shallow soils across the Arctic. Rapid thawing is now mobilizing sediment from deeper strata, but so far little is known about Hg concentrations in deep permafrost. Here, forty-one samples from sediment successions at seven sites and of different states of permafrost degradation on Bykovsky Peninsula (northern Yakutian coast) and in the Yukechi Alas region (Central Yakutia) were analyzed for Hg, total carbon, total nitrogen, and total organic carbon as well as grain-size distribution, bulk density, and mass specific magnetic susceptibility. We show average Hg concentrations of 9.72 ± 9.28 μg kg-1 in the deep sediments, an amount comparable to the few previous Arctic studies existing, and a significant correlation of Hg content with total organic carbon, total nitrogen, grain-size distribution, and mass specific magnetic susceptibility. Hg concentrations are higher in the generally sandier sediments of the Bykovsky Peninsula than in the siltier sediments of the Yukechi Alas. The ratio of Hg to total organic carbon in this study is 2.57 g kg-1, including samples with very low carbon content. We conclude that many deep permafrost sediments, some of which have been frozen for millennia, contain elevated concentrations of Hg and the stock of Hg ready to be released by erosion is of significance for the Arctic ecosystem. The Hg mobilized may accumulate on the way to or in the shallow sea, and where it ... Article in Journal/Newspaper Arctic Ice Magnetic susceptibility permafrost Yakutia Siberia UFZ - Publication Index (Helmholtz-Centre for Environmental Research) Arctic Frontiers in Earth Science 9 |
institution |
Open Polar |
collection |
UFZ - Publication Index (Helmholtz-Centre for Environmental Research) |
op_collection_id |
ftufz |
language |
English |
topic |
Arctic pollutants heavy metal Arctic warming Polar regions |
spellingShingle |
Arctic pollutants heavy metal Arctic warming Polar regions Rutkowski, C. Lenz, J. Lang, A. Wolter, J. Mothes, Sibylle Reemtsma, Thorsten Grosse, G. Ulrich, M. Fuchs, M. Schirrmeister, L. Fedorov, A. Grigoriev, M. Lantuit, H. Strauss, J. Mercury in sediment core samples from deep Siberian ice-rich permafrost |
topic_facet |
Arctic pollutants heavy metal Arctic warming Polar regions |
description |
We determine Hg concentrations of various deposits in Siberia’s deep permafrost and link sediment properties and Hg enrichment to establish a first Hg inventory of late Pleistocene permafrost down to a depth of 36 m below surface. As Arctic warming is transforming the ice-rich permafrost of Siberia, sediment is released and increases the flux of particulates to the Arctic shelf seas through thawing coasts, lakeshores, and river floodplains. Heavy metals within soils and sediments are also released and may increasingly enter Arctic waters and the biological food chain. High levels of mercury (Hg) have been reported from shallow soils across the Arctic. Rapid thawing is now mobilizing sediment from deeper strata, but so far little is known about Hg concentrations in deep permafrost. Here, forty-one samples from sediment successions at seven sites and of different states of permafrost degradation on Bykovsky Peninsula (northern Yakutian coast) and in the Yukechi Alas region (Central Yakutia) were analyzed for Hg, total carbon, total nitrogen, and total organic carbon as well as grain-size distribution, bulk density, and mass specific magnetic susceptibility. We show average Hg concentrations of 9.72 ± 9.28 μg kg-1 in the deep sediments, an amount comparable to the few previous Arctic studies existing, and a significant correlation of Hg content with total organic carbon, total nitrogen, grain-size distribution, and mass specific magnetic susceptibility. Hg concentrations are higher in the generally sandier sediments of the Bykovsky Peninsula than in the siltier sediments of the Yukechi Alas. The ratio of Hg to total organic carbon in this study is 2.57 g kg-1, including samples with very low carbon content. We conclude that many deep permafrost sediments, some of which have been frozen for millennia, contain elevated concentrations of Hg and the stock of Hg ready to be released by erosion is of significance for the Arctic ecosystem. The Hg mobilized may accumulate on the way to or in the shallow sea, and where it ... |
format |
Article in Journal/Newspaper |
author |
Rutkowski, C. Lenz, J. Lang, A. Wolter, J. Mothes, Sibylle Reemtsma, Thorsten Grosse, G. Ulrich, M. Fuchs, M. Schirrmeister, L. Fedorov, A. Grigoriev, M. Lantuit, H. Strauss, J. |
author_facet |
Rutkowski, C. Lenz, J. Lang, A. Wolter, J. Mothes, Sibylle Reemtsma, Thorsten Grosse, G. Ulrich, M. Fuchs, M. Schirrmeister, L. Fedorov, A. Grigoriev, M. Lantuit, H. Strauss, J. |
author_sort |
Rutkowski, C. |
title |
Mercury in sediment core samples from deep Siberian ice-rich permafrost |
title_short |
Mercury in sediment core samples from deep Siberian ice-rich permafrost |
title_full |
Mercury in sediment core samples from deep Siberian ice-rich permafrost |
title_fullStr |
Mercury in sediment core samples from deep Siberian ice-rich permafrost |
title_full_unstemmed |
Mercury in sediment core samples from deep Siberian ice-rich permafrost |
title_sort |
mercury in sediment core samples from deep siberian ice-rich permafrost |
publisher |
Frontiers Media, Lausanne |
publishDate |
2021 |
url |
https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=25021 https://doi.org/10.3389/feart.2021.718153 |
geographic |
Arctic |
geographic_facet |
Arctic |
genre |
Arctic Ice Magnetic susceptibility permafrost Yakutia Siberia |
genre_facet |
Arctic Ice Magnetic susceptibility permafrost Yakutia Siberia |
op_source |
ISSN: 2296-6463 |
op_relation |
https://www.ufz.de/index.php?en=20939&ufzPublicationIdentifier=25021 https://dx.doi.org/10.3389/feart.2021.718153 |
op_rights |
info:eu-repo/semantics/openAccess |
op_doi |
https://doi.org/10.3389/feart.2021.718153 |
container_title |
Frontiers in Earth Science |
container_volume |
9 |
_version_ |
1784887764125220864 |