B/Ca in planktonic foraminifera as a proxy for surface seawater pH
Boron isotope systematics indicate that boron incorporation into foraminiferal CaCO3 is determined by the partition coefficient, K D (= $\frac{\left[{\rm B}/{\rm Ca}\right]{\rm CaCO3}}{\left[{\rm B} \left({\rm OH}\right)4- /{\rm HCO}3-\right]\rm seawater), and [B(OH)4 -/HCO3 -]seawater, providing, i...
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ftucambridgeesc:oai:eprints.esc.cam.ac.uk:826 2023-05-15T16:39:13+02:00 B/Ca in planktonic foraminifera as a proxy for surface seawater pH Yu, J. M. Elderfield, H. Hönisch, B. 2007-04 application/pdf http://eprints.esc.cam.ac.uk/826/ http://eprints.esc.cam.ac.uk/826/1/YuElderfield_Paleoc.22.pdf en eng http://eprints.esc.cam.ac.uk/826/1/YuElderfield_Paleoc.22.pdf Yu, J. M. and Elderfield, H. and Hönisch, B. (2007) B/Ca in planktonic foraminifera as a proxy for surface seawater pH. Paleoceanography, 22. PA2202. DOI https://doi.org/10.1029/2006PA001347 <https://doi.org/10.1029/2006PA001347> 01 - Climate Change and Earth-Ocean Atmosphere Systems Article PeerReviewed 2007 ftucambridgeesc https://doi.org/10.1029/2006PA001347 2020-08-27T18:08:43Z Boron isotope systematics indicate that boron incorporation into foraminiferal CaCO3 is determined by the partition coefficient, K D (= $\frac{\left[{\rm B}/{\rm Ca}\right]{\rm CaCO3}}{\left[{\rm B} \left({\rm OH}\right)4- /{\rm HCO}3-\right]\rm seawater), and [B(OH)4 -/HCO3 -]seawater, providing, in principle, a method to estimate seawater pH and PCO2. We have measured B/Ca ratios in Globigerina bulloides and Globorotalia inflata for a series of core tops from the North Atlantic and the Southern Ocean and in Globigerinoides ruber (white) from Ocean Drilling Program (ODP) site 668B on the Sierra Leone Rise in the eastern equatorial Atlantic. B/Ca ratios in these species of planktonic foraminifera seem unaffected by dissolution on the seafloor. K D shows a strong species-specific dependence on calcification temperature, which can be corrected for using the Mg/Ca temperature proxy. A preliminary study of G. inflata from Southern Ocean sediment core CHAT 16K suggests that temperature-corrected B/Ca was ~30% higher during the last glacial. Correspondingly, pH was 0.15 units higher and aqueous PCO2 was 95 μatm lower at this site at the Last Glacial Maximum. The covariation between reconstructed PCO2 and the atmospheric pCO2 from the Vostok ice core demonstrates the feasibility of using B/Ca in planktonic foraminifera for reconstructing past variations in pH and PCO2. Article in Journal/Newspaper ice core North Atlantic Planktonic foraminifera Southern Ocean University of Cambridge, Department of Earth Sciences: ESC Publications Southern Ocean Paleoceanography 22 2 |
institution |
Open Polar |
collection |
University of Cambridge, Department of Earth Sciences: ESC Publications |
op_collection_id |
ftucambridgeesc |
language |
English |
topic |
01 - Climate Change and Earth-Ocean Atmosphere Systems |
spellingShingle |
01 - Climate Change and Earth-Ocean Atmosphere Systems Yu, J. M. Elderfield, H. Hönisch, B. B/Ca in planktonic foraminifera as a proxy for surface seawater pH |
topic_facet |
01 - Climate Change and Earth-Ocean Atmosphere Systems |
description |
Boron isotope systematics indicate that boron incorporation into foraminiferal CaCO3 is determined by the partition coefficient, K D (= $\frac{\left[{\rm B}/{\rm Ca}\right]{\rm CaCO3}}{\left[{\rm B} \left({\rm OH}\right)4- /{\rm HCO}3-\right]\rm seawater), and [B(OH)4 -/HCO3 -]seawater, providing, in principle, a method to estimate seawater pH and PCO2. We have measured B/Ca ratios in Globigerina bulloides and Globorotalia inflata for a series of core tops from the North Atlantic and the Southern Ocean and in Globigerinoides ruber (white) from Ocean Drilling Program (ODP) site 668B on the Sierra Leone Rise in the eastern equatorial Atlantic. B/Ca ratios in these species of planktonic foraminifera seem unaffected by dissolution on the seafloor. K D shows a strong species-specific dependence on calcification temperature, which can be corrected for using the Mg/Ca temperature proxy. A preliminary study of G. inflata from Southern Ocean sediment core CHAT 16K suggests that temperature-corrected B/Ca was ~30% higher during the last glacial. Correspondingly, pH was 0.15 units higher and aqueous PCO2 was 95 μatm lower at this site at the Last Glacial Maximum. The covariation between reconstructed PCO2 and the atmospheric pCO2 from the Vostok ice core demonstrates the feasibility of using B/Ca in planktonic foraminifera for reconstructing past variations in pH and PCO2. |
format |
Article in Journal/Newspaper |
author |
Yu, J. M. Elderfield, H. Hönisch, B. |
author_facet |
Yu, J. M. Elderfield, H. Hönisch, B. |
author_sort |
Yu, J. M. |
title |
B/Ca in planktonic foraminifera as a proxy for surface seawater pH |
title_short |
B/Ca in planktonic foraminifera as a proxy for surface seawater pH |
title_full |
B/Ca in planktonic foraminifera as a proxy for surface seawater pH |
title_fullStr |
B/Ca in planktonic foraminifera as a proxy for surface seawater pH |
title_full_unstemmed |
B/Ca in planktonic foraminifera as a proxy for surface seawater pH |
title_sort |
b/ca in planktonic foraminifera as a proxy for surface seawater ph |
publishDate |
2007 |
url |
http://eprints.esc.cam.ac.uk/826/ http://eprints.esc.cam.ac.uk/826/1/YuElderfield_Paleoc.22.pdf |
geographic |
Southern Ocean |
geographic_facet |
Southern Ocean |
genre |
ice core North Atlantic Planktonic foraminifera Southern Ocean |
genre_facet |
ice core North Atlantic Planktonic foraminifera Southern Ocean |
op_relation |
http://eprints.esc.cam.ac.uk/826/1/YuElderfield_Paleoc.22.pdf Yu, J. M. and Elderfield, H. and Hönisch, B. (2007) B/Ca in planktonic foraminifera as a proxy for surface seawater pH. Paleoceanography, 22. PA2202. DOI https://doi.org/10.1029/2006PA001347 <https://doi.org/10.1029/2006PA001347> |
op_doi |
https://doi.org/10.1029/2006PA001347 |
container_title |
Paleoceanography |
container_volume |
22 |
container_issue |
2 |
_version_ |
1766029552701669376 |