Olivine-hosted melt inclusions as an archive of redox heterogeneity in magmatic systems
The redox state of volcanic products determines their leverage on the oxidation of Earth's oceans and atmosphere, providing a long-term feedback on oxygen accumulation at the planet's surface. An archive of redox conditions in volcanic plumbing systems from a magma's mantle source, th...
Published in: | Earth and Planetary Science Letters |
---|---|
Main Authors: | , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
Elsevier
2017
|
Subjects: | |
Online Access: | http://eprints.esc.cam.ac.uk/4099/ http://eprints.esc.cam.ac.uk/4099/1/1-s2.0-S0012821X17305319-main.pdf https://doi.org/10.1016/j.epsl.2017.09.029 |
id |
ftucambridgeesc:oai:eprints.esc.cam.ac.uk:4099 |
---|---|
record_format |
openpolar |
institution |
Open Polar |
collection |
University of Cambridge, Department of Earth Sciences: ESC Publications |
op_collection_id |
ftucambridgeesc |
language |
English |
topic |
05 - Petrology - Igneous Metamorphic and Volcanic Studies |
spellingShingle |
05 - Petrology - Igneous Metamorphic and Volcanic Studies Hartley, Margaret E. Shorttle, Oliver Maclennan, John Moussallam, Yves Edmonds, Marie Olivine-hosted melt inclusions as an archive of redox heterogeneity in magmatic systems |
topic_facet |
05 - Petrology - Igneous Metamorphic and Volcanic Studies |
description |
The redox state of volcanic products determines their leverage on the oxidation of Earth's oceans and atmosphere, providing a long-term feedback on oxygen accumulation at the planet's surface. An archive of redox conditions in volcanic plumbing systems from a magma's mantle source, through crustal storage, to eruption, is carried in pockets of melt trapped within crystals. While melt inclusions have long been exploited for their capacity to retain information on a magma's history, their permeability to fast-diffusing elements such as hydrogen is now well documented and their retention of initial oxygen fugacities () could be similarly diffusion-limited. To test this, we have measured Fe3+/ΣFe by micro-XANES spectroscopy in a suite of 65 olivine-hosted melt inclusions and 9 matrix glasses from the AD 1783 Laki eruption, Iceland. This eruption experienced pre-eruptive mixing of chemically diverse magmas, syn-eruptive degassing at the vent, and post-eruptive degassing during lava flow up to 60 km over land, providing an ideal test of whether changes in the of a magma may be communicated through to its cargo of crystal-hosted melt inclusions. Melt inclusions from rapidly quenched tephra samples have Fe3+/ΣFe of (ΔQFM of +0.7 ± 0.1), with no correlation between their and degree of trace element enrichment or differentiation. These inclusions preserve the redox conditions of the mixed pre-eruptive Laki magma. When corrected for fractional crystallisation to 10 wt.% MgO, these inclusions record a parental magma [Fe3+/ΣFe](10) of 0.18 (ΔQFM of +0.4), significantly more oxidised than the Fe3+/ΣFe of 0.10 that is often assumed for Icelandic basalt magmas. Melt inclusions from quenched lava selvages are more reduced than those from the tephra, having Fe3+/ΣFe between 0.133 and 0.177 (ΔQFM from −0.4 to +0.4). These inclusions have approached equilibrium with their carrier lava, which has been reduced by sulfur degassing. The progressive re-equilibration of between inclusions and carrier melts occurs on timescales of hours to days, causing a drop in the sulfur content at sulfide saturation (SCSS) and driving the exsolution of immiscible sulfide globules in the inclusions. Our data demonstrate the roles of magma mixing, progressive re-equilibration, and degassing in redox evolution within magmatic systems, and the open-system nature of melt inclusions to during these processes. Redox heterogeneity present at the time of inclusion trapping may be overprinted by rapid re-equilibration of melt inclusion with the external environment, both in the magma chamber and during slow cooling in lava at the surface. This can decouple the melt inclusion archives of , major and trace element chemistry, and mask associations between , magmatic differentiation and mantle source heterogeneity unless the assembly of diverse magmas is rapidly followed by eruption. Our tools for understanding the redox conditions of magmas are thus limited; however, careful reconstruction of pre- and post-eruptive magmatic history has enabled us to confirm the relatively oxidised nature of ocean island-type mantle compared to that of mid-ocean ridge mantle. |
format |
Article in Journal/Newspaper |
author |
Hartley, Margaret E. Shorttle, Oliver Maclennan, John Moussallam, Yves Edmonds, Marie |
author_facet |
Hartley, Margaret E. Shorttle, Oliver Maclennan, John Moussallam, Yves Edmonds, Marie |
author_sort |
Hartley, Margaret E. |
title |
Olivine-hosted melt inclusions as an archive of redox heterogeneity in magmatic systems |
title_short |
Olivine-hosted melt inclusions as an archive of redox heterogeneity in magmatic systems |
title_full |
Olivine-hosted melt inclusions as an archive of redox heterogeneity in magmatic systems |
title_fullStr |
Olivine-hosted melt inclusions as an archive of redox heterogeneity in magmatic systems |
title_full_unstemmed |
Olivine-hosted melt inclusions as an archive of redox heterogeneity in magmatic systems |
title_sort |
olivine-hosted melt inclusions as an archive of redox heterogeneity in magmatic systems |
publisher |
Elsevier |
publishDate |
2017 |
url |
http://eprints.esc.cam.ac.uk/4099/ http://eprints.esc.cam.ac.uk/4099/1/1-s2.0-S0012821X17305319-main.pdf https://doi.org/10.1016/j.epsl.2017.09.029 |
long_lat |
ENVELOPE(-18.237,-18.237,64.070,64.070) |
geographic |
Laki |
geographic_facet |
Laki |
genre |
Iceland Ocean Island |
genre_facet |
Iceland Ocean Island |
op_relation |
http://eprints.esc.cam.ac.uk/4099/1/1-s2.0-S0012821X17305319-main.pdf Hartley, Margaret E. and Shorttle, Oliver and Maclennan, John and Moussallam, Yves and Edmonds, Marie (2017) Olivine-hosted melt inclusions as an archive of redox heterogeneity in magmatic systems. Earth and Planetary Science Letters, 479. pp. 192-205. ISSN 0012821X DOI https://doi.org/10.1016/j.epsl.2017.09.029 <https://doi.org/10.1016/j.epsl.2017.09.029> |
op_rights |
cc_by |
op_rightsnorm |
CC-BY |
op_doi |
https://doi.org/10.1016/j.epsl.2017.09.029 |
container_title |
Earth and Planetary Science Letters |
container_volume |
479 |
container_start_page |
192 |
op_container_end_page |
205 |
_version_ |
1766043760135766016 |
spelling |
ftucambridgeesc:oai:eprints.esc.cam.ac.uk:4099 2023-05-15T16:53:15+02:00 Olivine-hosted melt inclusions as an archive of redox heterogeneity in magmatic systems Hartley, Margaret E. Shorttle, Oliver Maclennan, John Moussallam, Yves Edmonds, Marie 2017 text http://eprints.esc.cam.ac.uk/4099/ http://eprints.esc.cam.ac.uk/4099/1/1-s2.0-S0012821X17305319-main.pdf https://doi.org/10.1016/j.epsl.2017.09.029 en eng Elsevier http://eprints.esc.cam.ac.uk/4099/1/1-s2.0-S0012821X17305319-main.pdf Hartley, Margaret E. and Shorttle, Oliver and Maclennan, John and Moussallam, Yves and Edmonds, Marie (2017) Olivine-hosted melt inclusions as an archive of redox heterogeneity in magmatic systems. Earth and Planetary Science Letters, 479. pp. 192-205. ISSN 0012821X DOI https://doi.org/10.1016/j.epsl.2017.09.029 <https://doi.org/10.1016/j.epsl.2017.09.029> cc_by CC-BY 05 - Petrology - Igneous Metamorphic and Volcanic Studies Article PeerReviewed 2017 ftucambridgeesc https://doi.org/10.1016/j.epsl.2017.09.029 2020-08-27T18:09:55Z The redox state of volcanic products determines their leverage on the oxidation of Earth's oceans and atmosphere, providing a long-term feedback on oxygen accumulation at the planet's surface. An archive of redox conditions in volcanic plumbing systems from a magma's mantle source, through crustal storage, to eruption, is carried in pockets of melt trapped within crystals. While melt inclusions have long been exploited for their capacity to retain information on a magma's history, their permeability to fast-diffusing elements such as hydrogen is now well documented and their retention of initial oxygen fugacities () could be similarly diffusion-limited. To test this, we have measured Fe3+/ΣFe by micro-XANES spectroscopy in a suite of 65 olivine-hosted melt inclusions and 9 matrix glasses from the AD 1783 Laki eruption, Iceland. This eruption experienced pre-eruptive mixing of chemically diverse magmas, syn-eruptive degassing at the vent, and post-eruptive degassing during lava flow up to 60 km over land, providing an ideal test of whether changes in the of a magma may be communicated through to its cargo of crystal-hosted melt inclusions. Melt inclusions from rapidly quenched tephra samples have Fe3+/ΣFe of (ΔQFM of +0.7 ± 0.1), with no correlation between their and degree of trace element enrichment or differentiation. These inclusions preserve the redox conditions of the mixed pre-eruptive Laki magma. When corrected for fractional crystallisation to 10 wt.% MgO, these inclusions record a parental magma [Fe3+/ΣFe](10) of 0.18 (ΔQFM of +0.4), significantly more oxidised than the Fe3+/ΣFe of 0.10 that is often assumed for Icelandic basalt magmas. Melt inclusions from quenched lava selvages are more reduced than those from the tephra, having Fe3+/ΣFe between 0.133 and 0.177 (ΔQFM from −0.4 to +0.4). These inclusions have approached equilibrium with their carrier lava, which has been reduced by sulfur degassing. The progressive re-equilibration of between inclusions and carrier melts occurs on timescales of hours to days, causing a drop in the sulfur content at sulfide saturation (SCSS) and driving the exsolution of immiscible sulfide globules in the inclusions. Our data demonstrate the roles of magma mixing, progressive re-equilibration, and degassing in redox evolution within magmatic systems, and the open-system nature of melt inclusions to during these processes. Redox heterogeneity present at the time of inclusion trapping may be overprinted by rapid re-equilibration of melt inclusion with the external environment, both in the magma chamber and during slow cooling in lava at the surface. This can decouple the melt inclusion archives of , major and trace element chemistry, and mask associations between , magmatic differentiation and mantle source heterogeneity unless the assembly of diverse magmas is rapidly followed by eruption. Our tools for understanding the redox conditions of magmas are thus limited; however, careful reconstruction of pre- and post-eruptive magmatic history has enabled us to confirm the relatively oxidised nature of ocean island-type mantle compared to that of mid-ocean ridge mantle. Article in Journal/Newspaper Iceland Ocean Island University of Cambridge, Department of Earth Sciences: ESC Publications Laki ENVELOPE(-18.237,-18.237,64.070,64.070) Earth and Planetary Science Letters 479 192 205 |