Titan's temporal evolution in stratospheric trace gases near the poles

• Published in: Icarus
• Main Authors: Coustenis, Athena, Jennings, Donald E., Achterberg, Richard K., Bampasidis, Georgios, Lavvas, Panayiotis, Nixon, Conor A., Teanby, Nicholas A., Anderson, Carrie M., Cottini, Valeria, Flasar, F. Michael
• Format: Article in Journal/Newspaper
• Language: English
• Published: 2016
• Subjects: Atmospheres; composition; evolution; structure; Satellites; Titan; atmosphere; South pole
• Online Access: https://hdl.handle.net/1983/33e1ccbe-7b88-420f-b918-727cda117979; https://research-information.bris.ac.uk/en/publications/33e1ccbe-7b88-420f-b918-727cda117979; https://doi.org/10.1016/j.icarus.2015.08.027; https://research-information.bris.ac.uk/ws/files/50705868/Icarus_Coustenis_2015_accepted.pdf; http://www.scopus.com/inward/record.url?scp=84960798590&partnerID=8YFLogxK

We analyze spectra acquired by the Cassini/Composite Infrared Spectrometer (CIRS) at high resolution from October 2010 until September 2014 in nadir mode. Up until mid 2012, Titan's Northern atmosphere exhibited the enriched chemical content found since the Voyager days (November 1980), with a peak around the Northern Spring Equinox (NSE) in 2009. Since then, we have observed the appearance at Titan's south pole of several trace species for the first time, such as HC 3 N and C 6 H 6 , observed only at high northern latitudes before equinox. We investigate here latitudes poleward of 50°S and 50°N from 2010 (after the Southern Autumnal Equinox) until 2014. For some of the most abundant and longest-lived hydrocarbons (C 2 H 2 , C 2 H 6 and C 3 H 8 ) and CO 2 , the evolution in the past 4 years at a given latitude is not very significant within error bars especially until mid-2013. In more recent dates, these molecules show a trend for increase in the south. This trend is dramatically more pronounced for the other trace species, especially in 2013-2014, and at 70°S relative to 50°S. These two regions then demonstrate that they are subject to different dynamical processes in and out of the polar vortex region. For most species, we find higher abundances at 50°N compared to 50°S, with the exception of C 3 H 8 , CO 2 , C 6 H 6 and HC 3 N, which arrive at similar mixing ratios after mid-2013. While the 70°N data show generally no change with a trend rather to a small decrease for most species within 2014, the 70°S results indicate a strong enhancement in trace stratospheric gases after 2012. The 663 cm -1 HC 3 N and the C 6 H 6 674 cm -1 emission bands appeared in late 2011/early 2012 in the south polar regions and have since then exhibited a dramatic increase in their abundances. At 70°S HC 3 N, HCN and C 6 H 6 have increased by 3 orders of magnitude over the past 3-4 years while other molecules, including C 2 H 4 , C 3 H 4 and C 4 H 2 , have increased less sharply (by 1-2 orders of magnitude). This is a strong ...