Comprehensive analytical approaches to determine the sources, fate and effects of marine oil spills

• Main Author: Radović, Jagoš
• Other Authors: Bayona Térmens, Josep Maria, Díez Salvador, Sergi, Santos, Javier, Universitat de Barcelona. Departament de Química Analítica
• Format: Doctoral or Postdoctoral Thesis
• Language: English
• Published: Universitat de Barcelona 2014
• Subjects: Vessaments de petroli; Vertidos de petróleo; Oil spills; Petjada química; Huella química; Chemical fingerprint; Meteorització química; Meteorización química; Chemical weathering; Effect-directed analysis (EDA); Análisis dirigido por los efectos (EDA); Anàlisi dirigit pels efectes (EDA); Ciències Experimentals i Matemàtiques; 543; Arctic
• Online Access: http://hdl.handle.net/10803/283088

In the past two decades we witnessed a decrease in both the number of oil spill incidents, and of the quantity of oil released in these incidents, which led to a diminished interest for basic oil spill science. With the introduction of more stringent oil spill legislation, much of the spill response, assessment and restoration activities were passed to governmental agencies and other stakeholders. Their capabilities were perhaps sufficient to deal with the most frequently occurring small-scale spills, however, recent large, catastrophic incidents such as the sinking of Prestige in 2002, or the Deepwater Horizon blowout in 2010, renewed the need for fundamental science in order to be able to fully understand and estimate the scope of the impacts such spills can have on the environment, economy and society. This is particularly important in the context of new explorations and discoveries of hydrocarbon resources in pristine regions such as Arctic, where extreme weather and the lack of infrastructure emphasize even more the need for a comprehensive assessment of all of the possible effects the future oil production could cause. The objectives of this thesis were set to provide new approaches and methodologies, and to improve and reevaluate the previously existing ones, in a way which can contribute to this comprehensive and proactive strategy. Their scope is comprehensive because it covers all the important aspects of marine oil spills – the sources, environmental fate and possible toxic effects. In addition, particular relevance of this thesis is drawn from the fact that the studies presented here include the investigation of real major oil spills (Prestige, DWH), and of a broad range of oils and oil products that are currently produced and transported worldwide. In order to fulfill the abovementioned general objectives, the following specific objectives had to be accomplished: Firstly, a physicochemical database of frequently transported crude and refined oils was created using elemental analysis, thin-layer ...