Palladium and organocatalysis: An excellent recipe for asymmetric synthesis
The dual activation of simple substrates by the combination of organocatalysis and palladium catalysis has been successfully applied in a variety of different asymmetric transformations. Thus, the asymmetric α-allylation of carbonyl compounds, α-fluorination of acyl derivatives, decarboxylative prot...
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Online Access: | http://hdl.handle.net/10486/667528 https://doi.org/10.3390/molecules180910108 |
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ftuamadrid:oai:repositorio.uam.es:10486/667528 2023-05-15T17:53:47+02:00 Palladium and organocatalysis: An excellent recipe for asymmetric synthesis Fernández-Ibañez, M. Ángeles Maciá, Beatriz Alonso, Diego A. Pastor, Isidro M. UAM. Departamento de Química Orgánica 2015-07-23T08:02:24Z application/pdf http://hdl.handle.net/10486/667528 https://doi.org/10.3390/molecules180910108 eng eng MDPI Molecules http://dx.doi.org/10.3390/molecules180910108 Comunidad de Madrid. S2009/PPQ-1634/AVANCAT Molecules 18.9 (2013): 10108-10121 1420-3049 http://hdl.handle.net/10486/667528 doi:10.3390/molecules180910108 10108 9 10121 18 © 2013 by the authors Reconocimiento openAccess Allylation Asymmetric synthesis Decarboxylative protonation Dual activation Fluorination Organocatalysis Palladium Tandem reaction Química article info:eu-repo/semantics/publishedVersion 2015 ftuamadrid https://doi.org/10.3390/molecules180910108 2022-05-10T23:16:35Z The dual activation of simple substrates by the combination of organocatalysis and palladium catalysis has been successfully applied in a variety of different asymmetric transformations. Thus, the asymmetric α-allylation of carbonyl compounds, α-fluorination of acyl derivatives, decarboxylative protonation of β-dicarbonyl compounds, cyclization reactions of alkynyl carbonyl compounds and β-functionalization of aldehydes have been efficiently achieved employing this double-catalytic methodology MAFI thanks financial support from the Ministerio de Economía y Competitividad MINECO, CTQ 2012-35790) and the Consejería de Educación de la Comunidad de Madrid (AVANCAT, S2009/PPQ-1634). BM thanks the European Commission for a Marie Curie Integration Grant (FP7-PEOPLE-2012-CIG). IMP thanks financial support from the Ministerio de Ciencia e Innovación (MICINN) of Spain (CTQ2011-24165) and from the University of Alicante. DAA thanks financial support for the European Union (ORCA action CM0905) and from the University of Alicante Article in Journal/Newspaper Orca Universidad Autónoma de Madrid (UAM): Biblos-e Archivo Molecules 18 9 10108 10121 |
institution |
Open Polar |
collection |
Universidad Autónoma de Madrid (UAM): Biblos-e Archivo |
op_collection_id |
ftuamadrid |
language |
English |
topic |
Allylation Asymmetric synthesis Decarboxylative protonation Dual activation Fluorination Organocatalysis Palladium Tandem reaction Química |
spellingShingle |
Allylation Asymmetric synthesis Decarboxylative protonation Dual activation Fluorination Organocatalysis Palladium Tandem reaction Química Fernández-Ibañez, M. Ángeles Maciá, Beatriz Alonso, Diego A. Pastor, Isidro M. Palladium and organocatalysis: An excellent recipe for asymmetric synthesis |
topic_facet |
Allylation Asymmetric synthesis Decarboxylative protonation Dual activation Fluorination Organocatalysis Palladium Tandem reaction Química |
description |
The dual activation of simple substrates by the combination of organocatalysis and palladium catalysis has been successfully applied in a variety of different asymmetric transformations. Thus, the asymmetric α-allylation of carbonyl compounds, α-fluorination of acyl derivatives, decarboxylative protonation of β-dicarbonyl compounds, cyclization reactions of alkynyl carbonyl compounds and β-functionalization of aldehydes have been efficiently achieved employing this double-catalytic methodology MAFI thanks financial support from the Ministerio de Economía y Competitividad MINECO, CTQ 2012-35790) and the Consejería de Educación de la Comunidad de Madrid (AVANCAT, S2009/PPQ-1634). BM thanks the European Commission for a Marie Curie Integration Grant (FP7-PEOPLE-2012-CIG). IMP thanks financial support from the Ministerio de Ciencia e Innovación (MICINN) of Spain (CTQ2011-24165) and from the University of Alicante. DAA thanks financial support for the European Union (ORCA action CM0905) and from the University of Alicante |
author2 |
UAM. Departamento de Química Orgánica |
format |
Article in Journal/Newspaper |
author |
Fernández-Ibañez, M. Ángeles Maciá, Beatriz Alonso, Diego A. Pastor, Isidro M. |
author_facet |
Fernández-Ibañez, M. Ángeles Maciá, Beatriz Alonso, Diego A. Pastor, Isidro M. |
author_sort |
Fernández-Ibañez, M. Ángeles |
title |
Palladium and organocatalysis: An excellent recipe for asymmetric synthesis |
title_short |
Palladium and organocatalysis: An excellent recipe for asymmetric synthesis |
title_full |
Palladium and organocatalysis: An excellent recipe for asymmetric synthesis |
title_fullStr |
Palladium and organocatalysis: An excellent recipe for asymmetric synthesis |
title_full_unstemmed |
Palladium and organocatalysis: An excellent recipe for asymmetric synthesis |
title_sort |
palladium and organocatalysis: an excellent recipe for asymmetric synthesis |
publisher |
MDPI |
publishDate |
2015 |
url |
http://hdl.handle.net/10486/667528 https://doi.org/10.3390/molecules180910108 |
genre |
Orca |
genre_facet |
Orca |
op_relation |
Molecules http://dx.doi.org/10.3390/molecules180910108 Comunidad de Madrid. S2009/PPQ-1634/AVANCAT Molecules 18.9 (2013): 10108-10121 1420-3049 http://hdl.handle.net/10486/667528 doi:10.3390/molecules180910108 10108 9 10121 18 |
op_rights |
© 2013 by the authors Reconocimiento openAccess |
op_doi |
https://doi.org/10.3390/molecules180910108 |
container_title |
Molecules |
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18 |
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9 |
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10108 |
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10121 |
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1766161482464100352 |