Formation and transformation of mixed-layer minerals by Tertiary intrusives in Cretaceous mudstones, West Greenland
In the Nuussuaq Basin, West Greenland, a thick succession of Tertiary dolerites has penetrated Upper Cretaceous mudstone. The mixed-layer minerals of mudstone core samples have been analyzed by X-ray diffraction, solid-state Si and Al magic-angle spinning nuclear magnetic resonance, Mössbauer and in...
Published in: | Clays and Clay Minerals |
---|---|
Main Authors: | , , , , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
2007
|
Subjects: | |
Online Access: | https://ddd.uab.cat/record/224784 |
id |
ftuabarcelonapb:oai:ddd.uab.cat:224784 |
---|---|
record_format |
openpolar |
spelling |
ftuabarcelonapb:oai:ddd.uab.cat:224784 2023-06-18T03:40:52+02:00 Formation and transformation of mixed-layer minerals by Tertiary intrusives in Cretaceous mudstones, West Greenland Drits, Victor A. Lindgreen, Holger Sakharov, Boris A. Jakobsen, Hans Jorgen Fallick, Anthony E. Salyn, Alfred L. Dainyak, Lidia G. Zviagina, Bella B. Barfod, Dan N. 2007 application/pdf https://ddd.uab.cat/record/224784 eng eng Clays and Clay Minerals Vol. 55, Núm. 3 (2007), p. 260-283 https://ddd.uab.cat/record/224784 urn:10.1346/CCMN.2007.0550304 urn:oai:ddd.uab.cat:224784 urn:scopus_id:34547424852 urn:articleid:15528367v55n3p260 urn:wos_id:000248320500004 restricted access Tots els drets reservats. https://rightsstatements.org/vocab/InC/1.0/ Burial Diagenesis Greenland Illite-smectite Oil-source Rocks Tobelite Article 2007 ftuabarcelonapb 2023-06-06T23:59:56Z In the Nuussuaq Basin, West Greenland, a thick succession of Tertiary dolerites has penetrated Upper Cretaceous mudstone. The mixed-layer minerals of mudstone core samples have been analyzed by X-ray diffraction, solid-state Si and Al magic-angle spinning nuclear magnetic resonance, Mössbauer and infrared spectroscopies, thermal analysis, chemical analysis, stable isotopes (O/O), and K/Ar dating. The mixed-layer minerals include for each sample two mixed-layer phases consisting of pyrophyllite, margarite, paragonite, tobelite, illite, smectite and vermiculite layers. The main, 80 m thick intrusion resulted in the formation of pyrophyllite, margarite, paragonite and tobelite layers. However, the tobelite layers are absent in samples <21 m from this intrusion. Furthermore, chlorite was formed and kaolinite destroyed in samples adjacent to minor intrusions and at distances <60 m from the large intrusion. For the first time, the detailed, complex mixed-layer structures formed during contact metamorphism of kaolinitic, oil-forming mudstones have been investigated accurately. The formation of tobelite layers reveals that oil formation has taken place during contact metamorphism. Furthermore, K/Ar dating of mixed-layer minerals from shale indicates that the intrusives are of early Eocene age. The 80 m thick intrusive is responsible for the main mixed-layer transformations, whereas two thin (3 m and 0.5 m thick) intrusions contribute little. Thus, the detailed mixed-layer investigation has contributed significantly to the understanding of the regional geology and the contact metamorphic processes. Article in Journal/Newspaper Greenland Nuussuaq Universitat Autònoma de Barcelona: Dipòsit Digital de Documents de la UAB Greenland Nuussuaq ENVELOPE(-51.918,-51.918,66.626,66.626) Clays and Clay Minerals 55 3 260 283 |
institution |
Open Polar |
collection |
Universitat Autònoma de Barcelona: Dipòsit Digital de Documents de la UAB |
op_collection_id |
ftuabarcelonapb |
language |
English |
topic |
Burial Diagenesis Greenland Illite-smectite Oil-source Rocks Tobelite |
spellingShingle |
Burial Diagenesis Greenland Illite-smectite Oil-source Rocks Tobelite Drits, Victor A. Lindgreen, Holger Sakharov, Boris A. Jakobsen, Hans Jorgen Fallick, Anthony E. Salyn, Alfred L. Dainyak, Lidia G. Zviagina, Bella B. Barfod, Dan N. Formation and transformation of mixed-layer minerals by Tertiary intrusives in Cretaceous mudstones, West Greenland |
topic_facet |
Burial Diagenesis Greenland Illite-smectite Oil-source Rocks Tobelite |
description |
In the Nuussuaq Basin, West Greenland, a thick succession of Tertiary dolerites has penetrated Upper Cretaceous mudstone. The mixed-layer minerals of mudstone core samples have been analyzed by X-ray diffraction, solid-state Si and Al magic-angle spinning nuclear magnetic resonance, Mössbauer and infrared spectroscopies, thermal analysis, chemical analysis, stable isotopes (O/O), and K/Ar dating. The mixed-layer minerals include for each sample two mixed-layer phases consisting of pyrophyllite, margarite, paragonite, tobelite, illite, smectite and vermiculite layers. The main, 80 m thick intrusion resulted in the formation of pyrophyllite, margarite, paragonite and tobelite layers. However, the tobelite layers are absent in samples <21 m from this intrusion. Furthermore, chlorite was formed and kaolinite destroyed in samples adjacent to minor intrusions and at distances <60 m from the large intrusion. For the first time, the detailed, complex mixed-layer structures formed during contact metamorphism of kaolinitic, oil-forming mudstones have been investigated accurately. The formation of tobelite layers reveals that oil formation has taken place during contact metamorphism. Furthermore, K/Ar dating of mixed-layer minerals from shale indicates that the intrusives are of early Eocene age. The 80 m thick intrusive is responsible for the main mixed-layer transformations, whereas two thin (3 m and 0.5 m thick) intrusions contribute little. Thus, the detailed mixed-layer investigation has contributed significantly to the understanding of the regional geology and the contact metamorphic processes. |
format |
Article in Journal/Newspaper |
author |
Drits, Victor A. Lindgreen, Holger Sakharov, Boris A. Jakobsen, Hans Jorgen Fallick, Anthony E. Salyn, Alfred L. Dainyak, Lidia G. Zviagina, Bella B. Barfod, Dan N. |
author_facet |
Drits, Victor A. Lindgreen, Holger Sakharov, Boris A. Jakobsen, Hans Jorgen Fallick, Anthony E. Salyn, Alfred L. Dainyak, Lidia G. Zviagina, Bella B. Barfod, Dan N. |
author_sort |
Drits, Victor A. |
title |
Formation and transformation of mixed-layer minerals by Tertiary intrusives in Cretaceous mudstones, West Greenland |
title_short |
Formation and transformation of mixed-layer minerals by Tertiary intrusives in Cretaceous mudstones, West Greenland |
title_full |
Formation and transformation of mixed-layer minerals by Tertiary intrusives in Cretaceous mudstones, West Greenland |
title_fullStr |
Formation and transformation of mixed-layer minerals by Tertiary intrusives in Cretaceous mudstones, West Greenland |
title_full_unstemmed |
Formation and transformation of mixed-layer minerals by Tertiary intrusives in Cretaceous mudstones, West Greenland |
title_sort |
formation and transformation of mixed-layer minerals by tertiary intrusives in cretaceous mudstones, west greenland |
publishDate |
2007 |
url |
https://ddd.uab.cat/record/224784 |
long_lat |
ENVELOPE(-51.918,-51.918,66.626,66.626) |
geographic |
Greenland Nuussuaq |
geographic_facet |
Greenland Nuussuaq |
genre |
Greenland Nuussuaq |
genre_facet |
Greenland Nuussuaq |
op_relation |
Clays and Clay Minerals Vol. 55, Núm. 3 (2007), p. 260-283 https://ddd.uab.cat/record/224784 urn:10.1346/CCMN.2007.0550304 urn:oai:ddd.uab.cat:224784 urn:scopus_id:34547424852 urn:articleid:15528367v55n3p260 urn:wos_id:000248320500004 |
op_rights |
restricted access Tots els drets reservats. https://rightsstatements.org/vocab/InC/1.0/ |
container_title |
Clays and Clay Minerals |
container_volume |
55 |
container_issue |
3 |
container_start_page |
260 |
op_container_end_page |
283 |
_version_ |
1769006223590424576 |