Dynamic Model of Batch Enzymatic Reactive Distillation for the Production of R-2-Pentyl Butyrate
A dynamic model of batch enzymatic reactive distillation was developed based on equilibrium stage approach. Phenomena within the evaporator, column, and condenser were modeled for nonsteady state operation of the process. A detailed approach to reaction kinetics, including equilibrium limitations, o...
Published in: | Industrial & Engineering Chemistry Research |
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Language: | English |
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Online Access: | http://hdl.handle.net/11420/4267 |
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fttuhamburg:oai:tore.tuhh.de:11420/4267 2023-08-20T04:01:11+02:00 Dynamic Model of Batch Enzymatic Reactive Distillation for the Production of R-2-Pentyl Butyrate Blatkiewicz, Michał Mißfeldt, Fynn Smirnova, Irina 2019 http://hdl.handle.net/11420/4267 en eng Industrial & engineering chemistry research 0888-5885 Industrial and Engineering Chemistry Research 58 (51): 22820-22834 (2019) http://hdl.handle.net/11420/4267 2-s2.0-85076792579 Journal Article Other 2019 fttuhamburg 2023-07-28T09:23:33Z A dynamic model of batch enzymatic reactive distillation was developed based on equilibrium stage approach. Phenomena within the evaporator, column, and condenser were modeled for nonsteady state operation of the process. A detailed approach to reaction kinetics, including equilibrium limitations, overtime deactivation of the catalyst in different temperatures, diffusional limitations in catalytically active xerogel coating, and temperature influence on the catalyst, was undertaken for ethyl butyrate transesterification with R-2-pentanol with the use of Candida antarctica lipase B as the catalyst. The model was validated with experimental data and served as a simulation tool for sensitivity analysis. Article in Journal/Newspaper Antarc* Antarctica TUHH Open Research (TORE - Technische Universität Hamburg) Industrial & Engineering Chemistry Research 58 51 22820 22834 |
institution |
Open Polar |
collection |
TUHH Open Research (TORE - Technische Universität Hamburg) |
op_collection_id |
fttuhamburg |
language |
English |
description |
A dynamic model of batch enzymatic reactive distillation was developed based on equilibrium stage approach. Phenomena within the evaporator, column, and condenser were modeled for nonsteady state operation of the process. A detailed approach to reaction kinetics, including equilibrium limitations, overtime deactivation of the catalyst in different temperatures, diffusional limitations in catalytically active xerogel coating, and temperature influence on the catalyst, was undertaken for ethyl butyrate transesterification with R-2-pentanol with the use of Candida antarctica lipase B as the catalyst. The model was validated with experimental data and served as a simulation tool for sensitivity analysis. |
format |
Article in Journal/Newspaper |
author |
Blatkiewicz, Michał Mißfeldt, Fynn Smirnova, Irina |
spellingShingle |
Blatkiewicz, Michał Mißfeldt, Fynn Smirnova, Irina Dynamic Model of Batch Enzymatic Reactive Distillation for the Production of R-2-Pentyl Butyrate |
author_facet |
Blatkiewicz, Michał Mißfeldt, Fynn Smirnova, Irina |
author_sort |
Blatkiewicz, Michał |
title |
Dynamic Model of Batch Enzymatic Reactive Distillation for the Production of R-2-Pentyl Butyrate |
title_short |
Dynamic Model of Batch Enzymatic Reactive Distillation for the Production of R-2-Pentyl Butyrate |
title_full |
Dynamic Model of Batch Enzymatic Reactive Distillation for the Production of R-2-Pentyl Butyrate |
title_fullStr |
Dynamic Model of Batch Enzymatic Reactive Distillation for the Production of R-2-Pentyl Butyrate |
title_full_unstemmed |
Dynamic Model of Batch Enzymatic Reactive Distillation for the Production of R-2-Pentyl Butyrate |
title_sort |
dynamic model of batch enzymatic reactive distillation for the production of r-2-pentyl butyrate |
publishDate |
2019 |
url |
http://hdl.handle.net/11420/4267 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_relation |
Industrial & engineering chemistry research 0888-5885 Industrial and Engineering Chemistry Research 58 (51): 22820-22834 (2019) http://hdl.handle.net/11420/4267 2-s2.0-85076792579 |
container_title |
Industrial & Engineering Chemistry Research |
container_volume |
58 |
container_issue |
51 |
container_start_page |
22820 |
op_container_end_page |
22834 |
_version_ |
1774723254883188736 |