Mercury distribution and transport in the North Atlantic Ocean along the GEOTRACES-GA01 transect
We report here the results of total mercury (HgT) determinations along the 2014 GEOTRACES GEOVIDE cruise (GA01 transect) in the North Atlantic Ocean (NA) from Lisbon (Portugal) to the Labrador coast (Canada). Ninety-seven percent of the HgT concentrations of unfiltered samples (HgTUNF) ranged betwee...
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Online Access: | https://doi.org/10.5194/bg-15-2309-2018 https://archimer.ifremer.fr/doc/00412/52303/53071.pdf https://archimer.ifremer.fr/doc/00412/52303/53072.pdf https://archimer.ifremer.fr/doc/00412/52303/56301.pdf https://archimer.ifremer.fr/doc/00412/52303/56302.pdf https://archimer.ifremer.fr/doc/00412/52303/ |
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fttriple:oai:gotriple.eu:10670/1.wholu1 2023-05-15T16:28:43+02:00 Mercury distribution and transport in the North Atlantic Ocean along the GEOTRACES-GA01 transect Cossa, Daniel Heimburger, Lars-eric Perez, Fiz F Garcia-ibanez, Maria Isabel Sonke, Jeroen E. Planquette, Helene Lherminier, Pascale Boutorh, Julia Cheize, Marie Barraqueta, Jan Lukas Menzel Shelley, Rachel Sarthou, Geraldine https://doi.org/10.5194/bg-15-2309-2018 https://archimer.ifremer.fr/doc/00412/52303/53071.pdf https://archimer.ifremer.fr/doc/00412/52303/53072.pdf https://archimer.ifremer.fr/doc/00412/52303/56301.pdf https://archimer.ifremer.fr/doc/00412/52303/56302.pdf https://archimer.ifremer.fr/doc/00412/52303/ en eng Copernicus Gesellschaft Mbh doi:10.5194/bg-15-2309-2018 10670/1.wholu1 https://archimer.ifremer.fr/doc/00412/52303/53071.pdf https://archimer.ifremer.fr/doc/00412/52303/53072.pdf https://archimer.ifremer.fr/doc/00412/52303/56301.pdf https://archimer.ifremer.fr/doc/00412/52303/56302.pdf https://archimer.ifremer.fr/doc/00412/52303/ lic_creative-commons other Archimer, archive institutionnelle de l'Ifremer Biogeosciences (1726-4170) (Copernicus Gesellschaft Mbh), 2018-04 , Vol. 15 , N. 8 , P. 2309-2323 envir geo Text https://vocabularies.coar-repositories.org/resource_types/c_18cf/ fttriple https://doi.org/10.5194/bg-15-2309-2018 2023-01-22T16:48:27Z We report here the results of total mercury (HgT) determinations along the 2014 GEOTRACES GEOVIDE cruise (GA01 transect) in the North Atlantic Ocean (NA) from Lisbon (Portugal) to the Labrador coast (Canada). Ninety-seven percent of the HgT concentrations of unfiltered samples (HgTUNF) ranged between 0.16 and 1.00 pmol L−1. The geometric mean was 0.51 pmol L−1 for the 535 samples analysed. The dissolved fraction (< 0.45 μm) of HgT, determined on 141 samples, averaged 78 % of the HgTUNF for the whole water column. HgTUNF concentrations increased eastwards and with depth from Greenland to Europe and from sub-surface to bottom waters, respectively. The Hg distribution mirrored that of dissolved oxygen concentration, with highest HgTUNF levels associated with oxygen-depleted zones. The statistically significant (p < 0.01) relationship between HgTF (filtered samples) and the apparent oxygen utilization confirms the nutrient-like behavior of Hg in the NA. An extended Optimum Multiparameter Analysis allowed us to characterize HgTUNF concentrations in the different Source Water Types (SWTs) present along the transect. Mean HgTUNF concentrations ranged from 0.26 ± 0.03 pmol L−1 in the Irminger Subpolar Mode Water to 1.02 ± 0.02 pmol L−1 in the lower North East Atlantic Deep Water. Anthropogenic Hg-enriched SWTs were found in the upper oceanic layers (i.e., East North Atlantic Central Water and Subarctic Intermediate Water). The change in anthropogenic Hg concentrations in the Labrador Sea Water, during its eastward journey, suggests a continuous decrease of Hg content in this water mass over the last decades. Calculation of the water transport driven by the Atlantic Meridional Overturning Circulation across the Portugal-Greenland transect indicates a northward Hg transport within the upper limb, and a southward Hg transport within the lower limb, with a resulting net transport from low latitudes to the polar zones of about 111 kmol yr−1. Text Greenland Labrador Sea North Atlantic North East Atlantic Subarctic Unknown Canada Greenland Biogeosciences 15 8 2309 2323 |
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language |
English |
topic |
envir geo |
spellingShingle |
envir geo Cossa, Daniel Heimburger, Lars-eric Perez, Fiz F Garcia-ibanez, Maria Isabel Sonke, Jeroen E. Planquette, Helene Lherminier, Pascale Boutorh, Julia Cheize, Marie Barraqueta, Jan Lukas Menzel Shelley, Rachel Sarthou, Geraldine Mercury distribution and transport in the North Atlantic Ocean along the GEOTRACES-GA01 transect |
topic_facet |
envir geo |
description |
We report here the results of total mercury (HgT) determinations along the 2014 GEOTRACES GEOVIDE cruise (GA01 transect) in the North Atlantic Ocean (NA) from Lisbon (Portugal) to the Labrador coast (Canada). Ninety-seven percent of the HgT concentrations of unfiltered samples (HgTUNF) ranged between 0.16 and 1.00 pmol L−1. The geometric mean was 0.51 pmol L−1 for the 535 samples analysed. The dissolved fraction (< 0.45 μm) of HgT, determined on 141 samples, averaged 78 % of the HgTUNF for the whole water column. HgTUNF concentrations increased eastwards and with depth from Greenland to Europe and from sub-surface to bottom waters, respectively. The Hg distribution mirrored that of dissolved oxygen concentration, with highest HgTUNF levels associated with oxygen-depleted zones. The statistically significant (p < 0.01) relationship between HgTF (filtered samples) and the apparent oxygen utilization confirms the nutrient-like behavior of Hg in the NA. An extended Optimum Multiparameter Analysis allowed us to characterize HgTUNF concentrations in the different Source Water Types (SWTs) present along the transect. Mean HgTUNF concentrations ranged from 0.26 ± 0.03 pmol L−1 in the Irminger Subpolar Mode Water to 1.02 ± 0.02 pmol L−1 in the lower North East Atlantic Deep Water. Anthropogenic Hg-enriched SWTs were found in the upper oceanic layers (i.e., East North Atlantic Central Water and Subarctic Intermediate Water). The change in anthropogenic Hg concentrations in the Labrador Sea Water, during its eastward journey, suggests a continuous decrease of Hg content in this water mass over the last decades. Calculation of the water transport driven by the Atlantic Meridional Overturning Circulation across the Portugal-Greenland transect indicates a northward Hg transport within the upper limb, and a southward Hg transport within the lower limb, with a resulting net transport from low latitudes to the polar zones of about 111 kmol yr−1. |
format |
Text |
author |
Cossa, Daniel Heimburger, Lars-eric Perez, Fiz F Garcia-ibanez, Maria Isabel Sonke, Jeroen E. Planquette, Helene Lherminier, Pascale Boutorh, Julia Cheize, Marie Barraqueta, Jan Lukas Menzel Shelley, Rachel Sarthou, Geraldine |
author_facet |
Cossa, Daniel Heimburger, Lars-eric Perez, Fiz F Garcia-ibanez, Maria Isabel Sonke, Jeroen E. Planquette, Helene Lherminier, Pascale Boutorh, Julia Cheize, Marie Barraqueta, Jan Lukas Menzel Shelley, Rachel Sarthou, Geraldine |
author_sort |
Cossa, Daniel |
title |
Mercury distribution and transport in the North Atlantic Ocean along the GEOTRACES-GA01 transect |
title_short |
Mercury distribution and transport in the North Atlantic Ocean along the GEOTRACES-GA01 transect |
title_full |
Mercury distribution and transport in the North Atlantic Ocean along the GEOTRACES-GA01 transect |
title_fullStr |
Mercury distribution and transport in the North Atlantic Ocean along the GEOTRACES-GA01 transect |
title_full_unstemmed |
Mercury distribution and transport in the North Atlantic Ocean along the GEOTRACES-GA01 transect |
title_sort |
mercury distribution and transport in the north atlantic ocean along the geotraces-ga01 transect |
publisher |
Copernicus Gesellschaft Mbh |
url |
https://doi.org/10.5194/bg-15-2309-2018 https://archimer.ifremer.fr/doc/00412/52303/53071.pdf https://archimer.ifremer.fr/doc/00412/52303/53072.pdf https://archimer.ifremer.fr/doc/00412/52303/56301.pdf https://archimer.ifremer.fr/doc/00412/52303/56302.pdf https://archimer.ifremer.fr/doc/00412/52303/ |
geographic |
Canada Greenland |
geographic_facet |
Canada Greenland |
genre |
Greenland Labrador Sea North Atlantic North East Atlantic Subarctic |
genre_facet |
Greenland Labrador Sea North Atlantic North East Atlantic Subarctic |
op_source |
Archimer, archive institutionnelle de l'Ifremer Biogeosciences (1726-4170) (Copernicus Gesellschaft Mbh), 2018-04 , Vol. 15 , N. 8 , P. 2309-2323 |
op_relation |
doi:10.5194/bg-15-2309-2018 10670/1.wholu1 https://archimer.ifremer.fr/doc/00412/52303/53071.pdf https://archimer.ifremer.fr/doc/00412/52303/53072.pdf https://archimer.ifremer.fr/doc/00412/52303/56301.pdf https://archimer.ifremer.fr/doc/00412/52303/56302.pdf https://archimer.ifremer.fr/doc/00412/52303/ |
op_rights |
lic_creative-commons other |
op_doi |
https://doi.org/10.5194/bg-15-2309-2018 |
container_title |
Biogeosciences |
container_volume |
15 |
container_issue |
8 |
container_start_page |
2309 |
op_container_end_page |
2323 |
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