The origin of Zn isotope fractionation in sulfides
International audience Isotope fractionation of Zn between aqueous sulfide, chloride, and carbonate species (Zn(2+), Zn(HS)2, Zn(HS)(3)(-), Zn(HS)(4)(2-), ZnS(HS)(-), ZnCl(+), ZnCl(2), ZnHCO(3)(+), and ZnCO(3)) was investigated using ab initio methods. Only little fractionation is found between the...
Published in: | Geochimica et Cosmochimica Acta |
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Online Access: | https://doi.org/10.1016/j.gca.2011.09.036 https://hal-insu.archives-ouvertes.fr/insu-00674540/file/j.gca.2011.09.036.pdf https://hal-insu.archives-ouvertes.fr/insu-00674540 |
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fttriple:oai:gotriple.eu:10670/1.tof86c 2023-05-15T15:52:44+02:00 The origin of Zn isotope fractionation in sulfides Fujii, Toshiyuki Moynier, Frédéric Pons, Marie-Laure Albarède, Francis Research Reactor Institute Kyoto University Kyoto Department of Earth and Planetary Sciences St Louis Washington University in Saint Louis (WUSTL) McDonnell Center for Space Sciences Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement Lyon (LGL-TPE) École normale supérieure - Lyon (ENS Lyon)-Université Claude Bernard Lyon 1 (UCBL) Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) I-CARES, Washington University in Saint Louis 2011-12-01 https://doi.org/10.1016/j.gca.2011.09.036 https://hal-insu.archives-ouvertes.fr/insu-00674540/file/j.gca.2011.09.036.pdf https://hal-insu.archives-ouvertes.fr/insu-00674540 en eng HAL CCSD Elsevier insu-00674540 doi:10.1016/j.gca.2011.09.036 10670/1.tof86c https://hal-insu.archives-ouvertes.fr/insu-00674540/file/j.gca.2011.09.036.pdf https://hal-insu.archives-ouvertes.fr/insu-00674540 other Hyper Article en Ligne - Sciences de l'Homme et de la Société ISSN: 0016-7037 EISSN: 0016-7037 Geochimica et Cosmochimica Acta Geochimica et Cosmochimica Acta, Elsevier, 2011, 75 (23), pp.7632-7643. ⟨10.1016/j.gca.2011.09.036⟩ 1 ATM PRESSURE AQUEOUS-SOLUTION ZINC ISOTOPES CARBONIC-ACID BISULFIDE COMPLEXES NMR-SPECTRA NACL MEDIA CHEMISTRY RAMAN IONIZATION geo envir Journal Article https://vocabularies.coar-repositories.org/resource_types/c_6501/ 2011 fttriple https://doi.org/10.1016/j.gca.2011.09.036 2023-01-22T18:02:17Z International audience Isotope fractionation of Zn between aqueous sulfide, chloride, and carbonate species (Zn(2+), Zn(HS)2, Zn(HS)(3)(-), Zn(HS)(4)(2-), ZnS(HS)(-), ZnCl(+), ZnCl(2), ZnHCO(3)(+), and ZnCO(3)) was investigated using ab initio methods. Only little fractionation is found between the sulfide species, whereas carbonates are up to 1 parts per thousand heavier than the parent solution. At pH > 3 and under atmospheric-like CO(2) pressures, isotope fractionation of Zn sulfides precipitated from sulfidic solutions is affected by aqueous sulfide species and the delta(66)Zn of sulfides reflect these in the parent solutions. Under high P(CO2) conditions, carbonate species become abundant. In high PCO(2) conditions of hydrothermal solutions, Zn precipitated as sulfides is isotopically nearly unfractionated with respect to a low-pH parent fluid. In contrast, negative delta(66)Zn down to at least -0.6 parts per thousand can be expected in sulfides precipitated from solutions with pH > 9. Zinc isotopes in sulfides and rocks therefore represent a potential indicator of mid to high pH in ancient hydrothermal fluids. Article in Journal/Newspaper Carbonic acid Unknown Geochimica et Cosmochimica Acta 75 23 7632 7643 |
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English |
topic |
1 ATM PRESSURE AQUEOUS-SOLUTION ZINC ISOTOPES CARBONIC-ACID BISULFIDE COMPLEXES NMR-SPECTRA NACL MEDIA CHEMISTRY RAMAN IONIZATION geo envir |
spellingShingle |
1 ATM PRESSURE AQUEOUS-SOLUTION ZINC ISOTOPES CARBONIC-ACID BISULFIDE COMPLEXES NMR-SPECTRA NACL MEDIA CHEMISTRY RAMAN IONIZATION geo envir Fujii, Toshiyuki Moynier, Frédéric Pons, Marie-Laure Albarède, Francis The origin of Zn isotope fractionation in sulfides |
topic_facet |
1 ATM PRESSURE AQUEOUS-SOLUTION ZINC ISOTOPES CARBONIC-ACID BISULFIDE COMPLEXES NMR-SPECTRA NACL MEDIA CHEMISTRY RAMAN IONIZATION geo envir |
description |
International audience Isotope fractionation of Zn between aqueous sulfide, chloride, and carbonate species (Zn(2+), Zn(HS)2, Zn(HS)(3)(-), Zn(HS)(4)(2-), ZnS(HS)(-), ZnCl(+), ZnCl(2), ZnHCO(3)(+), and ZnCO(3)) was investigated using ab initio methods. Only little fractionation is found between the sulfide species, whereas carbonates are up to 1 parts per thousand heavier than the parent solution. At pH > 3 and under atmospheric-like CO(2) pressures, isotope fractionation of Zn sulfides precipitated from sulfidic solutions is affected by aqueous sulfide species and the delta(66)Zn of sulfides reflect these in the parent solutions. Under high P(CO2) conditions, carbonate species become abundant. In high PCO(2) conditions of hydrothermal solutions, Zn precipitated as sulfides is isotopically nearly unfractionated with respect to a low-pH parent fluid. In contrast, negative delta(66)Zn down to at least -0.6 parts per thousand can be expected in sulfides precipitated from solutions with pH > 9. Zinc isotopes in sulfides and rocks therefore represent a potential indicator of mid to high pH in ancient hydrothermal fluids. |
author2 |
Research Reactor Institute Kyoto University Kyoto Department of Earth and Planetary Sciences St Louis Washington University in Saint Louis (WUSTL) McDonnell Center for Space Sciences Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement Lyon (LGL-TPE) École normale supérieure - Lyon (ENS Lyon)-Université Claude Bernard Lyon 1 (UCBL) Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) I-CARES, Washington University in Saint Louis |
format |
Article in Journal/Newspaper |
author |
Fujii, Toshiyuki Moynier, Frédéric Pons, Marie-Laure Albarède, Francis |
author_facet |
Fujii, Toshiyuki Moynier, Frédéric Pons, Marie-Laure Albarède, Francis |
author_sort |
Fujii, Toshiyuki |
title |
The origin of Zn isotope fractionation in sulfides |
title_short |
The origin of Zn isotope fractionation in sulfides |
title_full |
The origin of Zn isotope fractionation in sulfides |
title_fullStr |
The origin of Zn isotope fractionation in sulfides |
title_full_unstemmed |
The origin of Zn isotope fractionation in sulfides |
title_sort |
origin of zn isotope fractionation in sulfides |
publisher |
HAL CCSD |
publishDate |
2011 |
url |
https://doi.org/10.1016/j.gca.2011.09.036 https://hal-insu.archives-ouvertes.fr/insu-00674540/file/j.gca.2011.09.036.pdf https://hal-insu.archives-ouvertes.fr/insu-00674540 |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_source |
Hyper Article en Ligne - Sciences de l'Homme et de la Société ISSN: 0016-7037 EISSN: 0016-7037 Geochimica et Cosmochimica Acta Geochimica et Cosmochimica Acta, Elsevier, 2011, 75 (23), pp.7632-7643. ⟨10.1016/j.gca.2011.09.036⟩ |
op_relation |
insu-00674540 doi:10.1016/j.gca.2011.09.036 10670/1.tof86c https://hal-insu.archives-ouvertes.fr/insu-00674540/file/j.gca.2011.09.036.pdf https://hal-insu.archives-ouvertes.fr/insu-00674540 |
op_rights |
other |
op_doi |
https://doi.org/10.1016/j.gca.2011.09.036 |
container_title |
Geochimica et Cosmochimica Acta |
container_volume |
75 |
container_issue |
23 |
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7632 |
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7643 |
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