Reactive Halogens in the Marine Boundary Layer (RHaMBLe): The tropical North Atlantic experiments

• Main Authors: Lee, J.D., McFiggans, G., Allan, J.D., Baker, A.R., Ball, S.M., Benton, A.K., Carpenter, L.J., Commane, R., Finley, B.D., Evans, M., Fuentes, E., Furneaux, K., Goddard, A., Good, N., Hamilton, J.F., Heard, D.E., Herrmann, H., Hollingsworth, A., Hopkins, J.R., Ingham, T., Irwin, M., Jones, C.E., Jones, R.L., Keene, W.C., Lawler, M.J., Lehmann, S., Lewis, A.C., Long, M.S., Mahajan, A., Methven, J., Moller, S.J., Müller, K., Müller, T., Niedermeier, N., O'Doherty, S., Oetjen, H., Plane, J.M.C., Pszenny, A.A.P., Read, K.A., Saiz-Lopez, A., Saltzman, E.S., Sander, R., von Glasow, R., Whalley, L., Wiedensohler, A., Young, D.
• Format: Article in Journal/Newspaper
• Language: English
• Published: München : European Geopyhsical Union 2010
• Subjects: ddc:550; aerosol; air mass; atmospheric chemistry; atmospheric structure; black carbon; boundary layer; bromide; chloride; experimental study; halogen; marine atmosphere; measurement method; mixing ratio; nitrogen oxides; Northern Hemisphere; ozone; spatial distribution; trace gas; vertical distribution; North Atlantic
• Online Access: https://oa.tib.eu/renate/handle/123456789/457; https://doi.org/10.34657/1191

The NERC UK SOLAS-funded Reactive Halogens in the Marine Boundary Layer (RHaMBLe) programme comprised three field experiments. This manuscript presents an overview of the measurements made within the two simultaneous remote experiments conducted in the tropical North Atlantic in May and June 2007. Measurements were made from two mobile and one ground-based platforms. The heavily instrumented cruise D319 on the RRS Discovery from Lisbon, Portugal to São Vicente, Cape Verde and back to Falmouth, UK was used to characterise the spatial distribution of boundary layer components likely to play a role in reactive halogen chemistry. Measurements onboard the ARSF Dornier aircraft were used to allow the observations to be interpreted in the context of their vertical distribution and to confirm the interpretation of atmospheric structure in the vicinity of the Cape Verde islands. Long-term ground-based measurements at the Cape Verde Atmospheric Observatory (CVAO) on São Vicente were supplemented by long-term measurements of reactive halogen species and characterisation of additional trace gas and aerosol species during the intensive experimental period. This paper presents a summary of the measurements made within the RHaMBLe remote experiments and discusses them in their meteorological and chemical context as determined from these three platforms and from additional meteorological analyses. Air always arrived at the CVAO from the North East with a range of air mass origins (European, Atlantic and North American continental). Trace gases were present at stable and fairly low concentrations with the exception of a slight increase in some anthropogenic components in air of North American origin, though NOx mixing ratios during this period remained below 20 pptv (note the non-IUPAC adoption in this manuscript of pptv and ppbv, equivalent to pmol mol−1 and nmol mol−1 to reflect common practice). Consistency with these air mass classifications is observed in the time series of soluble gas and aerosol composition measurements, ...