Ocean-air N[subscript 2]O trace gas fluxes in Halifax Harbour derived from open-path FTIR measurements
1 online resource (133 pages) : colour illustrations, colour maps, charts (chiefly colour), graphs Includes abstract and appendix. Includes bibliographical references (pages 112-116). Open-Path Fourier Transform Infrared (OP-FTIR) spectroscopy is an established technique for path-average measurement...
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Halifax, N.S. : Saint Mary's University
2022
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ftstmarysunivca:oai:library2:01/31051 2023-05-15T17:45:41+02:00 Ocean-air N[subscript 2]O trace gas fluxes in Halifax Harbour derived from open-path FTIR measurements Ocean-air N2O trace gas fluxes in Halifax Harbour derived from Open-Path FTIR measurements Hellmich, Martin Wiacek, Aldona, 1977- Halifax Harbour (N.S.) 2022-08-30 application/pdf http://library2.smu.ca/xmlui/handle/01/31051 en eng Halifax, N.S. : Saint Mary's University http://library2.smu.ca/xmlui/handle/01/31051 Fourier transform infrared spectroscopy -- Measurement -- Halifax Harbour (N.S.) Ocean-atmosphere interaction -- Halifax Harbour (N.S.) Atmospheric nitrous oxide -- Halifax Harbour (N.S.) Micrometeorology -- Halifax Harbour (N.S.) Text 2022 ftstmarysunivca 2022-10-30T18:33:35Z 1 online resource (133 pages) : colour illustrations, colour maps, charts (chiefly colour), graphs Includes abstract and appendix. Includes bibliographical references (pages 112-116). Open-Path Fourier Transform Infrared (OP-FTIR) spectroscopy is an established technique for path-average measurements of atmospheric trace gas concentrations. We describe the novel application of OP-FTIR to measure ocean-air gas fluxes across 586 m of Halifax Harbour (northwest Atlantic coast), also using a 3-D sonic anemometer and two vertically separated retroreflector arrays. We present spectroscopic retrievals of nitrous oxide (N 2 O) concentration, micrometeorological data characteristics, and flux-gradient method calculations of ocean-air N 2 O flux. From Dec. 2020 to Apr. 2021 the calculated ocean sink of −10.81 kg N2O ha −1 agreed broadly with a global model of thermal (solubility-driven) N 2 O flux. A powerful short-term ocean source event observed on Dec. 15-17 (+2.00 kg N2O ha −1 ) correlated with high winds and strong ocean cooling that plausibly caused surface overturning and the upwelling of N 2 O-rich deeper waters. The method presented is well suited to high frequency monitoring of coastal N 2 O fluxes, necessary to resolve complex physical, chemical and biological processes. Text Northwest Atlantic Saint Mary's University, Halifax: Institutional Repository |
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Saint Mary's University, Halifax: Institutional Repository |
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ftstmarysunivca |
language |
English |
topic |
Fourier transform infrared spectroscopy -- Measurement -- Halifax Harbour (N.S.) Ocean-atmosphere interaction -- Halifax Harbour (N.S.) Atmospheric nitrous oxide -- Halifax Harbour (N.S.) Micrometeorology -- Halifax Harbour (N.S.) |
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Fourier transform infrared spectroscopy -- Measurement -- Halifax Harbour (N.S.) Ocean-atmosphere interaction -- Halifax Harbour (N.S.) Atmospheric nitrous oxide -- Halifax Harbour (N.S.) Micrometeorology -- Halifax Harbour (N.S.) Hellmich, Martin Ocean-air N[subscript 2]O trace gas fluxes in Halifax Harbour derived from open-path FTIR measurements |
topic_facet |
Fourier transform infrared spectroscopy -- Measurement -- Halifax Harbour (N.S.) Ocean-atmosphere interaction -- Halifax Harbour (N.S.) Atmospheric nitrous oxide -- Halifax Harbour (N.S.) Micrometeorology -- Halifax Harbour (N.S.) |
description |
1 online resource (133 pages) : colour illustrations, colour maps, charts (chiefly colour), graphs Includes abstract and appendix. Includes bibliographical references (pages 112-116). Open-Path Fourier Transform Infrared (OP-FTIR) spectroscopy is an established technique for path-average measurements of atmospheric trace gas concentrations. We describe the novel application of OP-FTIR to measure ocean-air gas fluxes across 586 m of Halifax Harbour (northwest Atlantic coast), also using a 3-D sonic anemometer and two vertically separated retroreflector arrays. We present spectroscopic retrievals of nitrous oxide (N 2 O) concentration, micrometeorological data characteristics, and flux-gradient method calculations of ocean-air N 2 O flux. From Dec. 2020 to Apr. 2021 the calculated ocean sink of −10.81 kg N2O ha −1 agreed broadly with a global model of thermal (solubility-driven) N 2 O flux. A powerful short-term ocean source event observed on Dec. 15-17 (+2.00 kg N2O ha −1 ) correlated with high winds and strong ocean cooling that plausibly caused surface overturning and the upwelling of N 2 O-rich deeper waters. The method presented is well suited to high frequency monitoring of coastal N 2 O fluxes, necessary to resolve complex physical, chemical and biological processes. |
author2 |
Wiacek, Aldona, 1977- |
format |
Text |
author |
Hellmich, Martin |
author_facet |
Hellmich, Martin |
author_sort |
Hellmich, Martin |
title |
Ocean-air N[subscript 2]O trace gas fluxes in Halifax Harbour derived from open-path FTIR measurements |
title_short |
Ocean-air N[subscript 2]O trace gas fluxes in Halifax Harbour derived from open-path FTIR measurements |
title_full |
Ocean-air N[subscript 2]O trace gas fluxes in Halifax Harbour derived from open-path FTIR measurements |
title_fullStr |
Ocean-air N[subscript 2]O trace gas fluxes in Halifax Harbour derived from open-path FTIR measurements |
title_full_unstemmed |
Ocean-air N[subscript 2]O trace gas fluxes in Halifax Harbour derived from open-path FTIR measurements |
title_sort |
ocean-air n[subscript 2]o trace gas fluxes in halifax harbour derived from open-path ftir measurements |
publisher |
Halifax, N.S. : Saint Mary's University |
publishDate |
2022 |
url |
http://library2.smu.ca/xmlui/handle/01/31051 |
op_coverage |
Halifax Harbour (N.S.) |
genre |
Northwest Atlantic |
genre_facet |
Northwest Atlantic |
op_relation |
http://library2.smu.ca/xmlui/handle/01/31051 |
_version_ |
1766148896865648640 |