Intercomparison of shipboard and moored CARIOCA buoy seawater fCO 2 measurements in the Sargasso Sea

• Published in: Marine Chemistry
• Main Authors: Bates, Nicholas R., Merlivat, Liliane, Beaumont, Laurence, Pequignet, A.Christine
• Format: Article in Journal/Newspaper
• Language: English
• Published: 2000
• Subjects: North Atlantic
• Online Access: https://eprints.soton.ac.uk/358341/

The ocean is an important sink for carbon and heat, yet high-resolution measurements of biogeochemical properties relevant to global climate change are being made only sporadically in the ocean at present. There is a growing need for automated, real-time, long-term measurements of CO 2 in the ocean using a network of sensors, strategically placed on ships, moorings, free-drifting buoys and autonomous remotely operated vehicles. The ground-truthing of new sensor technologies is a vital component of present and future efforts to monitor changes in the ocean carbon cycle and air–sea exchange of CO 2 . A comparison of a moored Carbon Interface Ocean Atmosphere (CARIOCA) buoy and shipboard fugacity of CO2 (fCO2) measurements was conducted in the western North Atlantic during two extended periods (>1 month) in 1997. The CARIOCA buoy was deployed on the Bermuda Testbed Mooring (BTM), which is located 5 km north of the site of the US Joint Global Ocean Flux Study (JGOFS) Bermuda Atlantic Time-series Study (BATS). The high frequency of sampling revealed that temperature and fCO 2 responded to physical forcing by the atmosphere on timescales from diurnal to 4–8 days. Concurrent with the deployments of the CARIOCA buoy, frequent measurements of surface fCO 2 were made from the R/V Weatherbird II during opportunistic visits to the BTM and BATS sites, providing a direct calibration of the CARIOCA buoy fCO 2 data. Although, the in situ ground-truthing of the CARIOCA buoy was complicated by diurnal processes, sub-mesoscale and fine-scale variability, the CARIOCA buoy fCO 2 data was accurate within 3±6 µatm of shipboard fCO 2 data for periods up to 50 days. Longer-term assessments were not possible due to the CARIOCA buoy breaking free of the BTM and drifting into waters with different fCO 2 -temperature properties. Strategies are put forward for future calibration of other in situ sensors.