Impact of a moderate volcanic eruption on chemistry in the lower stratosphere: balloon-borne observations and model calculations
International audience The major volcanic eruption of Mount Pinatubo in 1991 has been shown to have significant effects on stratospheric chemistry and ozone depletion even at mid-latitudes. Since then, only "moderate" but recurrent volcanic eruptions have modulated the stratospheric aeroso...
Published in: | Atmospheric Chemistry and Physics |
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Main Authors: | , , , , , , , , , , , , , , , , , , , , , , |
Other Authors: | , , , , , , , , , , , , , , , , , , , , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
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HAL CCSD
2017
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Online Access: | https://insu.hal.science/insu-01367008 https://insu.hal.science/insu-01367008/document https://insu.hal.science/insu-01367008/file/acp-17-2229-2017.pdf https://doi.org/10.5194/acp-17-2229-2017 |
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HAL Sorbonne Université |
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ftsorbonneuniv |
language |
English |
topic |
[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] [SDU.STU.VO]Sciences of the Universe [physics]/Earth Sciences/Volcanology |
spellingShingle |
[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] [SDU.STU.VO]Sciences of the Universe [physics]/Earth Sciences/Volcanology Berthet, Gwenaël Jégou, Fabrice Catoire, Valéry Krysztofiak, Gisèle Renard, Jean-Baptiste Bourassa, Adam E. Degenstein, Doug A. Brogniez, Colette Dorf, Marcel Kreycy, Sebastian Pfeilsticker, Klaus Werner, Bodo Lefèvre, Franck Roberts, Tjarda J. Lurton, Thibaut Vignelles, Damien Bègue, Nelson Bourgeois, Quentin Daugeron, Daniel Chartier, Michel Robert, C Gaubicher, Bertrand Guimbaud, Christophe Impact of a moderate volcanic eruption on chemistry in the lower stratosphere: balloon-borne observations and model calculations |
topic_facet |
[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] [SDU.STU.VO]Sciences of the Universe [physics]/Earth Sciences/Volcanology |
description |
International audience The major volcanic eruption of Mount Pinatubo in 1991 has been shown to have significant effects on stratospheric chemistry and ozone depletion even at mid-latitudes. Since then, only "moderate" but recurrent volcanic eruptions have modulated the stratospheric aerosol loading such as the eruption of the mid-latitude Sarychev volcano which injected 0.9 Tg of sulfur dioxide (about 20 times less than Pinatubo) in June 2009. In this study, we investigate the chemical impacts of the enhanced liquid sulfate aerosol loading resulting from this moderate eruption using data from a balloon campaign conducted in northern Sweden (Kiruna-Esrange, 67.5° N, 21.0° E) in August-September 2009. Balloon-borne observations of NO 2, HNO 3 and BrO from infrared and UV-visible spectrometers are compared with the outputs of a three-dimensional (3-D) Chemistry-Transport Model (CTM). It is shown that differences between observations and model outputs are not due to transport calculation issues but rather reflect the chemical impact of the volcanic plume below 19 km in altitude. Good measurement-model agreement is obtained when the CTM is driven by volcanic aerosol loadings derived from in situ or space-borne data. As a result of enhanced N 2 O 5 hydrolysis in the Sarychev volcanic aerosol conditions, the model calculates reductions of ~ 45 % and increases of ~ 11 % in NO 2 and HNO 3 amounts respectively over the summer 2009 period. The decrease in NO x abundances is limited due to the expected saturation effect for high aerosol loadings. The links between the various chemical catalytic cycles involving chlorine, bromine, nitrogen and HO x compounds in the lower stratosphere are discussed. The increased BrO amounts (~ 22 %) compare rather well with the balloon-borne observations when volcanic aerosol levels are accounted for in the CTM and appear to be mainly controlled by the coupling with nitrogen chemistry rather than by enhanced BrONO 2 hydrolysis. Simulated effects of the Sarychev eruption on chlorine ... |
author2 |
Laboratoire de Physique et Chimie de l'Environnement et de l'Espace (LPC2E) Observatoire des Sciences de l'Univers en région Centre (OSUC) Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris Université Paris Sciences et Lettres (PSL)-Université Paris Sciences et Lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris Université Paris Sciences et Lettres (PSL)-Université Paris Sciences et Lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Centre National d’Études Spatiales Paris (CNES) Institute of Space and Atmospheric Studies Saskatoon (ISAS) Department of Physics and Engineering Physics Saskatoon University of Saskatchewan Saskatoon, Canada (U of S)-University of Saskatchewan Saskatoon, Canada (U of S) Laboratoire d’Optique Atmosphérique - UMR 8518 (LOA) Institut national des sciences de l'Univers (INSU - CNRS)-Université de Lille-Centre National de la Recherche Scientifique (CNRS) Institut für Umweltphysik Heidelberg Universität Heidelberg Heidelberg = Heidelberg University STRATO - LATMOS Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS) Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) Laboratoire de l'Atmosphère et des Cyclones (LACy) Institut national des sciences de l'Univers (INSU - CNRS)-Université de La Réunion (UR)-Centre National de la Recherche Scientifique (CNRS)-Météo-France Department of Meteorology and Bolin Centre for Climate Research Stockholm University Agence Nationale de la Recherche (ANR) European Union ANR-08-BLAN-0300,StraPolEté,Dynamique, aérosols et brome dans la stratosphère polaire en été(2008) ANR-10-LABX-0100,VOLTAIRE,Geofluids and Volatil elements – Earth, Atmosphere, Interfaces – Resources and Environment(2010) European Project: 226365,EC:FP7:ENV,FP7-ENV-2008-1,RECONCILE(2009) European Project: 226224,EC:FP7:ENV,FP7-ENV-2008-1,SHIVA(2009) |
format |
Article in Journal/Newspaper |
author |
Berthet, Gwenaël Jégou, Fabrice Catoire, Valéry Krysztofiak, Gisèle Renard, Jean-Baptiste Bourassa, Adam E. Degenstein, Doug A. Brogniez, Colette Dorf, Marcel Kreycy, Sebastian Pfeilsticker, Klaus Werner, Bodo Lefèvre, Franck Roberts, Tjarda J. Lurton, Thibaut Vignelles, Damien Bègue, Nelson Bourgeois, Quentin Daugeron, Daniel Chartier, Michel Robert, C Gaubicher, Bertrand Guimbaud, Christophe |
author_facet |
Berthet, Gwenaël Jégou, Fabrice Catoire, Valéry Krysztofiak, Gisèle Renard, Jean-Baptiste Bourassa, Adam E. Degenstein, Doug A. Brogniez, Colette Dorf, Marcel Kreycy, Sebastian Pfeilsticker, Klaus Werner, Bodo Lefèvre, Franck Roberts, Tjarda J. Lurton, Thibaut Vignelles, Damien Bègue, Nelson Bourgeois, Quentin Daugeron, Daniel Chartier, Michel Robert, C Gaubicher, Bertrand Guimbaud, Christophe |
author_sort |
Berthet, Gwenaël |
title |
Impact of a moderate volcanic eruption on chemistry in the lower stratosphere: balloon-borne observations and model calculations |
title_short |
Impact of a moderate volcanic eruption on chemistry in the lower stratosphere: balloon-borne observations and model calculations |
title_full |
Impact of a moderate volcanic eruption on chemistry in the lower stratosphere: balloon-borne observations and model calculations |
title_fullStr |
Impact of a moderate volcanic eruption on chemistry in the lower stratosphere: balloon-borne observations and model calculations |
title_full_unstemmed |
Impact of a moderate volcanic eruption on chemistry in the lower stratosphere: balloon-borne observations and model calculations |
title_sort |
impact of a moderate volcanic eruption on chemistry in the lower stratosphere: balloon-borne observations and model calculations |
publisher |
HAL CCSD |
publishDate |
2017 |
url |
https://insu.hal.science/insu-01367008 https://insu.hal.science/insu-01367008/document https://insu.hal.science/insu-01367008/file/acp-17-2229-2017.pdf https://doi.org/10.5194/acp-17-2229-2017 |
long_lat |
ENVELOPE(21.117,21.117,67.883,67.883) |
geographic |
Kiruna Esrange |
geographic_facet |
Kiruna Esrange |
genre |
Arctic Kiruna Northern Sweden |
genre_facet |
Arctic Kiruna Northern Sweden |
op_source |
ISSN: 1680-7316 EISSN: 1680-7324 Atmospheric Chemistry and Physics https://insu.hal.science/insu-01367008 Atmospheric Chemistry and Physics, 2017, 17 (3), pp.2229-2253. ⟨10.5194/acp-17-2229-2017⟩ |
op_relation |
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op_rights |
info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.5194/acp-17-2229-2017 |
container_title |
Atmospheric Chemistry and Physics |
container_volume |
17 |
container_issue |
3 |
container_start_page |
2229 |
op_container_end_page |
2253 |
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1802639067549007872 |
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ftsorbonneuniv:oai:HAL:insu-01367008v1 2024-06-23T07:48:45+00:00 Impact of a moderate volcanic eruption on chemistry in the lower stratosphere: balloon-borne observations and model calculations Berthet, Gwenaël Jégou, Fabrice Catoire, Valéry Krysztofiak, Gisèle Renard, Jean-Baptiste Bourassa, Adam E. Degenstein, Doug A. Brogniez, Colette Dorf, Marcel Kreycy, Sebastian Pfeilsticker, Klaus Werner, Bodo Lefèvre, Franck Roberts, Tjarda J. Lurton, Thibaut Vignelles, Damien Bègue, Nelson Bourgeois, Quentin Daugeron, Daniel Chartier, Michel Robert, C Gaubicher, Bertrand Guimbaud, Christophe Laboratoire de Physique et Chimie de l'Environnement et de l'Espace (LPC2E) Observatoire des Sciences de l'Univers en région Centre (OSUC) Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris Université Paris Sciences et Lettres (PSL)-Université Paris Sciences et Lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris Université Paris Sciences et Lettres (PSL)-Université Paris Sciences et Lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Centre National d’Études Spatiales Paris (CNES) Institute of Space and Atmospheric Studies Saskatoon (ISAS) Department of Physics and Engineering Physics Saskatoon University of Saskatchewan Saskatoon, Canada (U of S)-University of Saskatchewan Saskatoon, Canada (U of S) Laboratoire d’Optique Atmosphérique - UMR 8518 (LOA) Institut national des sciences de l'Univers (INSU - CNRS)-Université de Lille-Centre National de la Recherche Scientifique (CNRS) Institut für Umweltphysik Heidelberg Universität Heidelberg Heidelberg = Heidelberg University STRATO - LATMOS Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS) Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS) Laboratoire de l'Atmosphère et des Cyclones (LACy) Institut national des sciences de l'Univers (INSU - CNRS)-Université de La Réunion (UR)-Centre National de la Recherche Scientifique (CNRS)-Météo-France Department of Meteorology and Bolin Centre for Climate Research Stockholm University Agence Nationale de la Recherche (ANR) European Union ANR-08-BLAN-0300,StraPolEté,Dynamique, aérosols et brome dans la stratosphère polaire en été(2008) ANR-10-LABX-0100,VOLTAIRE,Geofluids and Volatil elements – Earth, Atmosphere, Interfaces – Resources and Environment(2010) European Project: 226365,EC:FP7:ENV,FP7-ENV-2008-1,RECONCILE(2009) European Project: 226224,EC:FP7:ENV,FP7-ENV-2008-1,SHIVA(2009) 2017 https://insu.hal.science/insu-01367008 https://insu.hal.science/insu-01367008/document https://insu.hal.science/insu-01367008/file/acp-17-2229-2017.pdf https://doi.org/10.5194/acp-17-2229-2017 en eng HAL CCSD European Geosciences Union info:eu-repo/semantics/altIdentifier/doi/10.5194/acp-17-2229-2017 info:eu-repo/grantAgreement/EC/FP7/226365/EU/Reconciliation of essential process parameters for an enhanced predictability of arctic stratospheric ozone loss and its climate interactions./RECONCILE info:eu-repo/grantAgreement/EC/FP7/226224/EU/Stratospheric ozone: Halogen Impacts in a Varying Atmosphere/SHIVA insu-01367008 https://insu.hal.science/insu-01367008 https://insu.hal.science/insu-01367008/document https://insu.hal.science/insu-01367008/file/acp-17-2229-2017.pdf doi:10.5194/acp-17-2229-2017 info:eu-repo/semantics/OpenAccess ISSN: 1680-7316 EISSN: 1680-7324 Atmospheric Chemistry and Physics https://insu.hal.science/insu-01367008 Atmospheric Chemistry and Physics, 2017, 17 (3), pp.2229-2253. ⟨10.5194/acp-17-2229-2017⟩ [PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] [SDU.STU.VO]Sciences of the Universe [physics]/Earth Sciences/Volcanology info:eu-repo/semantics/article Journal articles 2017 ftsorbonneuniv https://doi.org/10.5194/acp-17-2229-2017 2024-06-06T23:50:19Z International audience The major volcanic eruption of Mount Pinatubo in 1991 has been shown to have significant effects on stratospheric chemistry and ozone depletion even at mid-latitudes. Since then, only "moderate" but recurrent volcanic eruptions have modulated the stratospheric aerosol loading such as the eruption of the mid-latitude Sarychev volcano which injected 0.9 Tg of sulfur dioxide (about 20 times less than Pinatubo) in June 2009. In this study, we investigate the chemical impacts of the enhanced liquid sulfate aerosol loading resulting from this moderate eruption using data from a balloon campaign conducted in northern Sweden (Kiruna-Esrange, 67.5° N, 21.0° E) in August-September 2009. Balloon-borne observations of NO 2, HNO 3 and BrO from infrared and UV-visible spectrometers are compared with the outputs of a three-dimensional (3-D) Chemistry-Transport Model (CTM). It is shown that differences between observations and model outputs are not due to transport calculation issues but rather reflect the chemical impact of the volcanic plume below 19 km in altitude. Good measurement-model agreement is obtained when the CTM is driven by volcanic aerosol loadings derived from in situ or space-borne data. As a result of enhanced N 2 O 5 hydrolysis in the Sarychev volcanic aerosol conditions, the model calculates reductions of ~ 45 % and increases of ~ 11 % in NO 2 and HNO 3 amounts respectively over the summer 2009 period. The decrease in NO x abundances is limited due to the expected saturation effect for high aerosol loadings. The links between the various chemical catalytic cycles involving chlorine, bromine, nitrogen and HO x compounds in the lower stratosphere are discussed. The increased BrO amounts (~ 22 %) compare rather well with the balloon-borne observations when volcanic aerosol levels are accounted for in the CTM and appear to be mainly controlled by the coupling with nitrogen chemistry rather than by enhanced BrONO 2 hydrolysis. Simulated effects of the Sarychev eruption on chlorine ... Article in Journal/Newspaper Arctic Kiruna Northern Sweden HAL Sorbonne Université Kiruna Esrange ENVELOPE(21.117,21.117,67.883,67.883) Atmospheric Chemistry and Physics 17 3 2229 2253 |