Photoinduced Reaction of Triarylphosphines with Alkenes Forming Fused Tricyclic Phosphonium Salts
Herein reported is a photoinduced reaction of triarylphosphines with alkenes in the presence of carbonic acid. A drastic structural change occurs to produce fused tricyclic phosphonium salts having a phosphatricyclo[4.3.0.0 2.9 ]nonene core structure. The reaction was marked by dearomatizing trans...
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ftsmithonian:oai:figshare.com:article/16826651 2023-05-15T15:52:26+02:00 Photoinduced Reaction of Triarylphosphines with Alkenes Forming Fused Tricyclic Phosphonium Salts Yusuke Masuda (1486120) Masumi Uno (11576681) Masahiro Murakami (8477) 2021-10-18T00:00:00Z https://doi.org/10.1021/acs.orglett.1c03168.s002 unknown https://figshare.com/articles/dataset/Photoinduced_Reaction_of_Triarylphosphines_with_Alkenes_Forming_Fused_Tricyclic_Phosphonium_Salts/16826651 doi:10.1021/acs.orglett.1c03168.s002 CC BY-NC 4.0 CC-BY-NC Biochemistry Cell Biology Genetics Molecular Biology Biotechnology Infectious Diseases Plant Biology Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified phosphatricyclo [ 4 highly endergonic process mild reaction conditions visible light photoinduced reaction phosphorus atom phenyl ring dearomatizing transannulation carbonic acid Dataset 2021 ftsmithonian https://doi.org/10.1021/acs.orglett.1c03168.s002 2021-12-20T00:01:24Z Herein reported is a photoinduced reaction of triarylphosphines with alkenes in the presence of carbonic acid. A drastic structural change occurs to produce fused tricyclic phosphonium salts having a phosphatricyclo[4.3.0.0 2.9 ]nonene core structure. The reaction was marked by dearomatizing transannulation of the phenyl ring, 1,2-migration of the phosphorus atom, and incorporation of an alkene. The highly endergonic process is promoted by cooperation of visible light with a photocatalyst under mild reaction conditions. Dataset Carbonic acid Unknown |
institution |
Open Polar |
collection |
Unknown |
op_collection_id |
ftsmithonian |
language |
unknown |
topic |
Biochemistry Cell Biology Genetics Molecular Biology Biotechnology Infectious Diseases Plant Biology Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified phosphatricyclo [ 4 highly endergonic process mild reaction conditions visible light photoinduced reaction phosphorus atom phenyl ring dearomatizing transannulation carbonic acid |
spellingShingle |
Biochemistry Cell Biology Genetics Molecular Biology Biotechnology Infectious Diseases Plant Biology Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified phosphatricyclo [ 4 highly endergonic process mild reaction conditions visible light photoinduced reaction phosphorus atom phenyl ring dearomatizing transannulation carbonic acid Yusuke Masuda (1486120) Masumi Uno (11576681) Masahiro Murakami (8477) Photoinduced Reaction of Triarylphosphines with Alkenes Forming Fused Tricyclic Phosphonium Salts |
topic_facet |
Biochemistry Cell Biology Genetics Molecular Biology Biotechnology Infectious Diseases Plant Biology Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified phosphatricyclo [ 4 highly endergonic process mild reaction conditions visible light photoinduced reaction phosphorus atom phenyl ring dearomatizing transannulation carbonic acid |
description |
Herein reported is a photoinduced reaction of triarylphosphines with alkenes in the presence of carbonic acid. A drastic structural change occurs to produce fused tricyclic phosphonium salts having a phosphatricyclo[4.3.0.0 2.9 ]nonene core structure. The reaction was marked by dearomatizing transannulation of the phenyl ring, 1,2-migration of the phosphorus atom, and incorporation of an alkene. The highly endergonic process is promoted by cooperation of visible light with a photocatalyst under mild reaction conditions. |
format |
Dataset |
author |
Yusuke Masuda (1486120) Masumi Uno (11576681) Masahiro Murakami (8477) |
author_facet |
Yusuke Masuda (1486120) Masumi Uno (11576681) Masahiro Murakami (8477) |
author_sort |
Yusuke Masuda (1486120) |
title |
Photoinduced Reaction of Triarylphosphines with Alkenes Forming Fused Tricyclic Phosphonium Salts |
title_short |
Photoinduced Reaction of Triarylphosphines with Alkenes Forming Fused Tricyclic Phosphonium Salts |
title_full |
Photoinduced Reaction of Triarylphosphines with Alkenes Forming Fused Tricyclic Phosphonium Salts |
title_fullStr |
Photoinduced Reaction of Triarylphosphines with Alkenes Forming Fused Tricyclic Phosphonium Salts |
title_full_unstemmed |
Photoinduced Reaction of Triarylphosphines with Alkenes Forming Fused Tricyclic Phosphonium Salts |
title_sort |
photoinduced reaction of triarylphosphines with alkenes forming fused tricyclic phosphonium salts |
publishDate |
2021 |
url |
https://doi.org/10.1021/acs.orglett.1c03168.s002 |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_relation |
https://figshare.com/articles/dataset/Photoinduced_Reaction_of_Triarylphosphines_with_Alkenes_Forming_Fused_Tricyclic_Phosphonium_Salts/16826651 doi:10.1021/acs.orglett.1c03168.s002 |
op_rights |
CC BY-NC 4.0 |
op_rightsnorm |
CC-BY-NC |
op_doi |
https://doi.org/10.1021/acs.orglett.1c03168.s002 |
_version_ |
1766387615317098496 |