Investigating the Atmospheric Production of Perchlorate: Inference from Polar Ice Cores
Perchlorate (ClO4) in the environment is of concern, because of potential health risks to humans, among other reasons. Evidence suggests that the majority of environmental perchlorate is formed in the atmosphere (likely in the stratosphere), in chemical processes involving ozone and stratospheric ch...
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ftsdakotastateun:oai:openprairie.sdstate.edu:etd-2690 2023-11-12T04:05:33+01:00 Investigating the Atmospheric Production of Perchlorate: Inference from Polar Ice Cores Cox, Thomas S. 2017-01-01T08:00:00Z application/pdf https://openprairie.sdstate.edu/etd/1664 https://openprairie.sdstate.edu/context/etd/article/2690/viewcontent/Cox_Thomas_2017.pdf en eng Open PRAIRIE: Open Public Research Access Institutional Repository and Information Exchange https://openprairie.sdstate.edu/etd/1664 https://openprairie.sdstate.edu/context/etd/article/2690/viewcontent/Cox_Thomas_2017.pdf Electronic Theses and Dissertations atmospheric production ice core ozone Perchlorate post-depositional loss stratospheric chlorine Analytical Chemistry Atmospheric Sciences Environmental Sciences text 2017 ftsdakotastateun 2023-10-30T09:48:36Z Perchlorate (ClO4) in the environment is of concern, because of potential health risks to humans, among other reasons. Evidence suggests that the majority of environmental perchlorate is formed in the atmosphere (likely in the stratosphere), in chemical processes involving ozone and stratospheric chlorine. A lack of knowledge in regards to the processes has resulted in a limited understanding of the environmental conditions and variables that influence perchlorate production and consequently perchlorate prevalence and variability in the environment. In this study, perchlorate was measured, using an established ion chromatography-‐electrospray ionization-‐tandem mass spectrometry (IC-‐ESI-‐ MS/MS) technique, in over 1,600 snowpit and ice core samples collected at several Antarctic locations. Several ice core records were developed covering the 20th century; however, interpretation of the records is complicated by depositional and post-‐depositional processes that affect perchlorate concentrations in snow. It appears that wet deposition is significant at sites where accumulation is high and dry deposition is significant where accumulation is low; additionally, perchlorate concentration in snow may undergo significant changes (~50% decrease) at low accumulation sites. Yet, the records suggest that perchlorate is produced from activated chlorine species (chlorine free radicals) in the stratosphere and that increases in stratospheric chlorine -‐ due to anthropogenic emissions of chlorine compounds (CFCs) -‐ are likely driving the increasing trend of perchlorate production. Furthermore, perchlorate variability appears to also be indirectly influenced by stratospheric temperature and stratospheric sulfate aerosols. Text Antarc* Antarctic ice core South Dakota State University (SDSU): Open PRAIRIE (Public Research Access Institutional Repository and Information Exchange) Antarctic |
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Open Polar |
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South Dakota State University (SDSU): Open PRAIRIE (Public Research Access Institutional Repository and Information Exchange) |
op_collection_id |
ftsdakotastateun |
language |
English |
topic |
atmospheric production ice core ozone Perchlorate post-depositional loss stratospheric chlorine Analytical Chemistry Atmospheric Sciences Environmental Sciences |
spellingShingle |
atmospheric production ice core ozone Perchlorate post-depositional loss stratospheric chlorine Analytical Chemistry Atmospheric Sciences Environmental Sciences Cox, Thomas S. Investigating the Atmospheric Production of Perchlorate: Inference from Polar Ice Cores |
topic_facet |
atmospheric production ice core ozone Perchlorate post-depositional loss stratospheric chlorine Analytical Chemistry Atmospheric Sciences Environmental Sciences |
description |
Perchlorate (ClO4) in the environment is of concern, because of potential health risks to humans, among other reasons. Evidence suggests that the majority of environmental perchlorate is formed in the atmosphere (likely in the stratosphere), in chemical processes involving ozone and stratospheric chlorine. A lack of knowledge in regards to the processes has resulted in a limited understanding of the environmental conditions and variables that influence perchlorate production and consequently perchlorate prevalence and variability in the environment. In this study, perchlorate was measured, using an established ion chromatography-‐electrospray ionization-‐tandem mass spectrometry (IC-‐ESI-‐ MS/MS) technique, in over 1,600 snowpit and ice core samples collected at several Antarctic locations. Several ice core records were developed covering the 20th century; however, interpretation of the records is complicated by depositional and post-‐depositional processes that affect perchlorate concentrations in snow. It appears that wet deposition is significant at sites where accumulation is high and dry deposition is significant where accumulation is low; additionally, perchlorate concentration in snow may undergo significant changes (~50% decrease) at low accumulation sites. Yet, the records suggest that perchlorate is produced from activated chlorine species (chlorine free radicals) in the stratosphere and that increases in stratospheric chlorine -‐ due to anthropogenic emissions of chlorine compounds (CFCs) -‐ are likely driving the increasing trend of perchlorate production. Furthermore, perchlorate variability appears to also be indirectly influenced by stratospheric temperature and stratospheric sulfate aerosols. |
format |
Text |
author |
Cox, Thomas S. |
author_facet |
Cox, Thomas S. |
author_sort |
Cox, Thomas S. |
title |
Investigating the Atmospheric Production of Perchlorate: Inference from Polar Ice Cores |
title_short |
Investigating the Atmospheric Production of Perchlorate: Inference from Polar Ice Cores |
title_full |
Investigating the Atmospheric Production of Perchlorate: Inference from Polar Ice Cores |
title_fullStr |
Investigating the Atmospheric Production of Perchlorate: Inference from Polar Ice Cores |
title_full_unstemmed |
Investigating the Atmospheric Production of Perchlorate: Inference from Polar Ice Cores |
title_sort |
investigating the atmospheric production of perchlorate: inference from polar ice cores |
publisher |
Open PRAIRIE: Open Public Research Access Institutional Repository and Information Exchange |
publishDate |
2017 |
url |
https://openprairie.sdstate.edu/etd/1664 https://openprairie.sdstate.edu/context/etd/article/2690/viewcontent/Cox_Thomas_2017.pdf |
geographic |
Antarctic |
geographic_facet |
Antarctic |
genre |
Antarc* Antarctic ice core |
genre_facet |
Antarc* Antarctic ice core |
op_source |
Electronic Theses and Dissertations |
op_relation |
https://openprairie.sdstate.edu/etd/1664 https://openprairie.sdstate.edu/context/etd/article/2690/viewcontent/Cox_Thomas_2017.pdf |
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1782342022989873152 |