Synthesis and characterization of alternating poly(amide urethane)s
This thesis deals with the preparation of alternating poly(amide urethane)s which might be of interest for the manufacture of powder coatings. The synthesis of poly(amide urethane)s was performed in environmentally friendly way without using isocyanates or phosgene. The starting materials for the sy...
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Publikationsserver der RWTH Aachen University
2004
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ftrwthaachenpubl:oai:publications.rwth-aachen.de:59627 2023-05-15T15:52:38+02:00 Synthesis and characterization of alternating poly(amide urethane)s Sharma, Bhaskar Höcker, Hartwig DE 2004 https://publications.rwth-aachen.de/record/59627 https://publications.rwth-aachen.de/search?p=id:%22RWTH-CONV-121396%22 eng eng Publikationsserver der RWTH Aachen University info:eu-repo/semantics/altIdentifier/urn/urn:nbn:de:hbz:82-opus-9420 https://publications.rwth-aachen.de/record/59627 https://publications.rwth-aachen.de/search?p=id:%22RWTH-CONV-121396%22 info:eu-repo/semantics/openAccess Aachen : Publikationsserver der RWTH Aachen University IX, 146 S. : graph. Darst. (2004). = Aachen, Techn. Hochsch., Diss., 2004 info:eu-repo/classification/ddc/540 Chemie Polycondensation Modification of end groups Structure-properety relations info:eu-repo/semantics/doctoralThesis info:eu-repo/semantics/publishedVersion 2004 ftrwthaachenpubl 2022-06-30T20:08:25Z This thesis deals with the preparation of alternating poly(amide urethane)s which might be of interest for the manufacture of powder coatings. The synthesis of poly(amide urethane)s was performed in environmentally friendly way without using isocyanates or phosgene. The starting materials for the synthesis were e-caprolactam, e-caprolactone, amino alcohols, diamines and carbonic acid derivatives, i.e. diphenyl carbonate and ethylene carbonate as substitutes for phosgene. A new synthesis was developed where the polycondensation of a-hydroxy-w-O-phenyl urethanes and a-hydroxy-w-O-hydroxy ethyl urethanes plays a key role. It was shown that the polycondensation is influenced by some factors; the use of the catalyst plays an important role. The microstructure of the polymers is different depending on the nature of monomers and the temperature during the polycondensation. Doctoral or Postdoctoral Thesis Carbonic acid RWTH Aachen University: RWTH Publications |
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Open Polar |
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RWTH Aachen University: RWTH Publications |
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ftrwthaachenpubl |
language |
English |
topic |
info:eu-repo/classification/ddc/540 Chemie Polycondensation Modification of end groups Structure-properety relations |
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info:eu-repo/classification/ddc/540 Chemie Polycondensation Modification of end groups Structure-properety relations Sharma, Bhaskar Synthesis and characterization of alternating poly(amide urethane)s |
topic_facet |
info:eu-repo/classification/ddc/540 Chemie Polycondensation Modification of end groups Structure-properety relations |
description |
This thesis deals with the preparation of alternating poly(amide urethane)s which might be of interest for the manufacture of powder coatings. The synthesis of poly(amide urethane)s was performed in environmentally friendly way without using isocyanates or phosgene. The starting materials for the synthesis were e-caprolactam, e-caprolactone, amino alcohols, diamines and carbonic acid derivatives, i.e. diphenyl carbonate and ethylene carbonate as substitutes for phosgene. A new synthesis was developed where the polycondensation of a-hydroxy-w-O-phenyl urethanes and a-hydroxy-w-O-hydroxy ethyl urethanes plays a key role. It was shown that the polycondensation is influenced by some factors; the use of the catalyst plays an important role. The microstructure of the polymers is different depending on the nature of monomers and the temperature during the polycondensation. |
author2 |
Höcker, Hartwig |
format |
Doctoral or Postdoctoral Thesis |
author |
Sharma, Bhaskar |
author_facet |
Sharma, Bhaskar |
author_sort |
Sharma, Bhaskar |
title |
Synthesis and characterization of alternating poly(amide urethane)s |
title_short |
Synthesis and characterization of alternating poly(amide urethane)s |
title_full |
Synthesis and characterization of alternating poly(amide urethane)s |
title_fullStr |
Synthesis and characterization of alternating poly(amide urethane)s |
title_full_unstemmed |
Synthesis and characterization of alternating poly(amide urethane)s |
title_sort |
synthesis and characterization of alternating poly(amide urethane)s |
publisher |
Publikationsserver der RWTH Aachen University |
publishDate |
2004 |
url |
https://publications.rwth-aachen.de/record/59627 https://publications.rwth-aachen.de/search?p=id:%22RWTH-CONV-121396%22 |
op_coverage |
DE |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_source |
Aachen : Publikationsserver der RWTH Aachen University IX, 146 S. : graph. Darst. (2004). = Aachen, Techn. Hochsch., Diss., 2004 |
op_relation |
info:eu-repo/semantics/altIdentifier/urn/urn:nbn:de:hbz:82-opus-9420 https://publications.rwth-aachen.de/record/59627 https://publications.rwth-aachen.de/search?p=id:%22RWTH-CONV-121396%22 |
op_rights |
info:eu-repo/semantics/openAccess |
_version_ |
1766387758261075968 |