A geochemical study of Paleozoic alkaline magmatism in the Selwyn Basin and the potential relationship to Zn-Pb mineralization
The Selwyn Basin in the Yukon, Canada, has several occurrences of Paleozoic alkaline volcanic rocks that are spatially and temporally associated with Zn-Pb deposits. The volcanics are represented by ocean island basalt (MacMillan Pass, Misty Creek Embayment), enriched mid ocean ridge basalt (Keno Hi...
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ftqueensuniv:oai:https://qspace.library.queensu.ca:1974/31324 2024-06-02T08:09:48+00:00 A geochemical study of Paleozoic alkaline magmatism in the Selwyn Basin and the potential relationship to Zn-Pb mineralization Scanlan, Emma Geological Sciences and Geological Engineering Leybourne, Matthew Layton-Matthews, Daniel 2022-11-30T17:10:07Z application/pdf http://hdl.handle.net/1974/31324 eng eng Canadian theses http://hdl.handle.net/1974/31324 Queen's University's Thesis/Dissertation Non-Exclusive License for Deposit to QSpace and Library and Archives Canada ProQuest PhD and Master's Theses International Dissemination Agreement Intellectual Property Guidelines at Queen's University Copying and Preserving Your Thesis This publication is made available by the authority of the copyright owner solely for the purpose of private study and research and may not be copied or reproduced except as permitted by the copyright laws without written authority from the copyright owner. Attribution-NonCommercial-NoDerivs 3.0 United States http://creativecommons.org/licenses/by-nc-nd/3.0/us/ igneous petrology geochemistry geology isotope geochemistry sediment-hosted mineralization economic geology thesis 2022 ftqueensuniv 2024-05-06T10:47:33Z The Selwyn Basin in the Yukon, Canada, has several occurrences of Paleozoic alkaline volcanic rocks that are spatially and temporally associated with Zn-Pb deposits. The volcanics are represented by ocean island basalt (MacMillan Pass, Misty Creek Embayment), enriched mid ocean ridge basalt (Keno Hill) and transitional basalts (Anvil District). The OIB signature indicates the MacMillan Pass and Misty Creek Embayment magmas were derived from small partial melts of an enriched lithospheric mantle during small, shallow, degrees of melting. An increased amount of extension resulted in upwelling of the asthenosphere that was sampled during melting of the transitional basalts in the Anvil District. Strontium isotopes of the Selwyn Basin volcanic rocks show evidence for interaction with Paleozoic seawater and several samples display highly radiogenic 87Sr/86Sr values due to crustal contamination. The volcanic rocks have low 143Nd/144Nd values and are representative of the source region. Mixing occurred between a highly radiogenic and less radiogenic Pb source. The Keno Hill samples plot near MORB values. The isotopes for both MacMillan Pass and Anvil volcanics plot between EMII-like and HIMU-like mantle end members, suggesting melting of a heterogenous lithospheric mantle with two end members; an enriched reservoir (low Nd, average Pb, high Sr) and a highly radiogenic Pb reservoir (high Pb, average Nd, low Sr). A depleted mantle source may be contributing to the Keno Hill samples. Thallium isotopes of the volcanic rocks have negative values that decrease with increasing degree of alteration. The MacMillan Pass samples have the smallest ɛ205Tl compositions while the Anvil samples overlap with OIB and MORB values and the measured ɛ205Tl range of mineralized rocks from Anniv East at Howard’s Pass. Ratios of certain trace elements (Tl, Ba, In, Ag) of host rocks for mineralization at Howard’s Pass and MacMillan Pass trend towards the values of Selwyn volcanic rocks. Mineralized samples plot at the overlap between their host ... Thesis Keno Hill Ocean Island Yukon Queen's University, Ontario: QSpace Yukon Canada Selwyn ENVELOPE(-138.287,-138.287,62.799,62.799) Anvil ENVELOPE(-64.267,-64.267,-65.239,-65.239) Keno Hill ENVELOPE(-135.307,-135.307,63.908,63.908) Macmillan Pass ENVELOPE(-130.037,-130.037,63.250,63.250) Misty Creek ENVELOPE(-131.187,-131.187,64.116,64.116) |
institution |
Open Polar |
collection |
Queen's University, Ontario: QSpace |
op_collection_id |
ftqueensuniv |
language |
English |
topic |
igneous petrology geochemistry geology isotope geochemistry sediment-hosted mineralization economic geology |
spellingShingle |
igneous petrology geochemistry geology isotope geochemistry sediment-hosted mineralization economic geology Scanlan, Emma A geochemical study of Paleozoic alkaline magmatism in the Selwyn Basin and the potential relationship to Zn-Pb mineralization |
topic_facet |
igneous petrology geochemistry geology isotope geochemistry sediment-hosted mineralization economic geology |
description |
The Selwyn Basin in the Yukon, Canada, has several occurrences of Paleozoic alkaline volcanic rocks that are spatially and temporally associated with Zn-Pb deposits. The volcanics are represented by ocean island basalt (MacMillan Pass, Misty Creek Embayment), enriched mid ocean ridge basalt (Keno Hill) and transitional basalts (Anvil District). The OIB signature indicates the MacMillan Pass and Misty Creek Embayment magmas were derived from small partial melts of an enriched lithospheric mantle during small, shallow, degrees of melting. An increased amount of extension resulted in upwelling of the asthenosphere that was sampled during melting of the transitional basalts in the Anvil District. Strontium isotopes of the Selwyn Basin volcanic rocks show evidence for interaction with Paleozoic seawater and several samples display highly radiogenic 87Sr/86Sr values due to crustal contamination. The volcanic rocks have low 143Nd/144Nd values and are representative of the source region. Mixing occurred between a highly radiogenic and less radiogenic Pb source. The Keno Hill samples plot near MORB values. The isotopes for both MacMillan Pass and Anvil volcanics plot between EMII-like and HIMU-like mantle end members, suggesting melting of a heterogenous lithospheric mantle with two end members; an enriched reservoir (low Nd, average Pb, high Sr) and a highly radiogenic Pb reservoir (high Pb, average Nd, low Sr). A depleted mantle source may be contributing to the Keno Hill samples. Thallium isotopes of the volcanic rocks have negative values that decrease with increasing degree of alteration. The MacMillan Pass samples have the smallest ɛ205Tl compositions while the Anvil samples overlap with OIB and MORB values and the measured ɛ205Tl range of mineralized rocks from Anniv East at Howard’s Pass. Ratios of certain trace elements (Tl, Ba, In, Ag) of host rocks for mineralization at Howard’s Pass and MacMillan Pass trend towards the values of Selwyn volcanic rocks. Mineralized samples plot at the overlap between their host ... |
author2 |
Geological Sciences and Geological Engineering Leybourne, Matthew Layton-Matthews, Daniel |
format |
Thesis |
author |
Scanlan, Emma |
author_facet |
Scanlan, Emma |
author_sort |
Scanlan, Emma |
title |
A geochemical study of Paleozoic alkaline magmatism in the Selwyn Basin and the potential relationship to Zn-Pb mineralization |
title_short |
A geochemical study of Paleozoic alkaline magmatism in the Selwyn Basin and the potential relationship to Zn-Pb mineralization |
title_full |
A geochemical study of Paleozoic alkaline magmatism in the Selwyn Basin and the potential relationship to Zn-Pb mineralization |
title_fullStr |
A geochemical study of Paleozoic alkaline magmatism in the Selwyn Basin and the potential relationship to Zn-Pb mineralization |
title_full_unstemmed |
A geochemical study of Paleozoic alkaline magmatism in the Selwyn Basin and the potential relationship to Zn-Pb mineralization |
title_sort |
geochemical study of paleozoic alkaline magmatism in the selwyn basin and the potential relationship to zn-pb mineralization |
publishDate |
2022 |
url |
http://hdl.handle.net/1974/31324 |
long_lat |
ENVELOPE(-138.287,-138.287,62.799,62.799) ENVELOPE(-64.267,-64.267,-65.239,-65.239) ENVELOPE(-135.307,-135.307,63.908,63.908) ENVELOPE(-130.037,-130.037,63.250,63.250) ENVELOPE(-131.187,-131.187,64.116,64.116) |
geographic |
Yukon Canada Selwyn Anvil Keno Hill Macmillan Pass Misty Creek |
geographic_facet |
Yukon Canada Selwyn Anvil Keno Hill Macmillan Pass Misty Creek |
genre |
Keno Hill Ocean Island Yukon |
genre_facet |
Keno Hill Ocean Island Yukon |
op_relation |
Canadian theses http://hdl.handle.net/1974/31324 |
op_rights |
Queen's University's Thesis/Dissertation Non-Exclusive License for Deposit to QSpace and Library and Archives Canada ProQuest PhD and Master's Theses International Dissemination Agreement Intellectual Property Guidelines at Queen's University Copying and Preserving Your Thesis This publication is made available by the authority of the copyright owner solely for the purpose of private study and research and may not be copied or reproduced except as permitted by the copyright laws without written authority from the copyright owner. Attribution-NonCommercial-NoDerivs 3.0 United States http://creativecommons.org/licenses/by-nc-nd/3.0/us/ |
_version_ |
1800755572944928768 |