A vibrational spectroscopic study of the anhydrous phosphate mineral sidorenkite Na3Mn(PO4)(CO3)
Sidorenkite is a very rare low-temperature hydrothermal mineral, formed very late in the crystallization of hyperagpaitic pegmatites in a differentiated alkalic massif (Mt. Alluaiv, Kola Peninsula, Russia). Sidorenkite Na3Mn(PO4)(CO3) is a phosphate–carbonate of sodium and manganese. Such a formula...
Published in: | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |
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ftqueensland:oai:eprints.qut.edu.au:83664 2024-01-28T10:07:03+01:00 A vibrational spectroscopic study of the anhydrous phosphate mineral sidorenkite Na3Mn(PO4)(CO3) Frost, Ray Lopez Toro, Andres Scholz, Ricardo Belotti, Fernanda Xi, Yunfei 2015 https://eprints.qut.edu.au/83664/ unknown Elsevier doi:10.1016/j.saa.2014.08.029 Frost, Ray, Lopez Toro, Andres, Scholz, Ricardo, Belotti, Fernanda, & Xi, Yunfei (2015) A vibrational spectroscopic study of the anhydrous phosphate mineral sidorenkite Na3Mn(PO4)(CO3). Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 137, pp. 930-934. https://eprints.qut.edu.au/83664/ Institute for Future Environments; Science & Engineering Faculty; School of Chemistry, Physics & Mechanical Engineering Consult author(s) regarding copyright matters This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy carbonate infrared spectroscopy phosphate raman spectroscopy sidorenkite Contribution to Journal 2015 ftqueensland https://doi.org/10.1016/j.saa.2014.08.029 2024-01-01T23:24:38Z Sidorenkite is a very rare low-temperature hydrothermal mineral, formed very late in the crystallization of hyperagpaitic pegmatites in a differentiated alkalic massif (Mt. Alluaiv, Kola Peninsula, Russia). Sidorenkite Na3Mn(PO4)(CO3) is a phosphate–carbonate of sodium and manganese. Such a formula with two oxyanions lends itself to vibrational spectroscopy. The sharp Raman band at 959 cm−1 and 1012 cm−1 are assigned to the PO43− stretching modes, whilst the Raman bands at 1044 cm−1 and 1074 cm−1 are attributed to the CO32− stretching modes. It is noted that no Raman bands at around 800 cm−1 for sidorenkite were observed. The infrared spectrum of sidorenkite shows a quite intense band at 868 cm−1 with other resolved component bands at 850 and 862 cm−1. These bands are ascribed to the CO32− out-of-plane bend (ν2) bending mode. The series of Raman bands at 622, 635, 645 and 704 cm−1 are assigned to the ν4 phosphate bending modes. The observation of multiple bands supports the concept of a reduction in symmetry of the carbonate anion from D3h or even C2v. Article in Journal/Newspaper kola peninsula Queensland University of Technology: QUT ePrints Alluaiv ENVELOPE(34.533,34.533,67.900,67.900) Kola Peninsula Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 137 930 934 |
institution |
Open Polar |
collection |
Queensland University of Technology: QUT ePrints |
op_collection_id |
ftqueensland |
language |
unknown |
topic |
carbonate infrared spectroscopy phosphate raman spectroscopy sidorenkite |
spellingShingle |
carbonate infrared spectroscopy phosphate raman spectroscopy sidorenkite Frost, Ray Lopez Toro, Andres Scholz, Ricardo Belotti, Fernanda Xi, Yunfei A vibrational spectroscopic study of the anhydrous phosphate mineral sidorenkite Na3Mn(PO4)(CO3) |
topic_facet |
carbonate infrared spectroscopy phosphate raman spectroscopy sidorenkite |
description |
Sidorenkite is a very rare low-temperature hydrothermal mineral, formed very late in the crystallization of hyperagpaitic pegmatites in a differentiated alkalic massif (Mt. Alluaiv, Kola Peninsula, Russia). Sidorenkite Na3Mn(PO4)(CO3) is a phosphate–carbonate of sodium and manganese. Such a formula with two oxyanions lends itself to vibrational spectroscopy. The sharp Raman band at 959 cm−1 and 1012 cm−1 are assigned to the PO43− stretching modes, whilst the Raman bands at 1044 cm−1 and 1074 cm−1 are attributed to the CO32− stretching modes. It is noted that no Raman bands at around 800 cm−1 for sidorenkite were observed. The infrared spectrum of sidorenkite shows a quite intense band at 868 cm−1 with other resolved component bands at 850 and 862 cm−1. These bands are ascribed to the CO32− out-of-plane bend (ν2) bending mode. The series of Raman bands at 622, 635, 645 and 704 cm−1 are assigned to the ν4 phosphate bending modes. The observation of multiple bands supports the concept of a reduction in symmetry of the carbonate anion from D3h or even C2v. |
format |
Article in Journal/Newspaper |
author |
Frost, Ray Lopez Toro, Andres Scholz, Ricardo Belotti, Fernanda Xi, Yunfei |
author_facet |
Frost, Ray Lopez Toro, Andres Scholz, Ricardo Belotti, Fernanda Xi, Yunfei |
author_sort |
Frost, Ray |
title |
A vibrational spectroscopic study of the anhydrous phosphate mineral sidorenkite Na3Mn(PO4)(CO3) |
title_short |
A vibrational spectroscopic study of the anhydrous phosphate mineral sidorenkite Na3Mn(PO4)(CO3) |
title_full |
A vibrational spectroscopic study of the anhydrous phosphate mineral sidorenkite Na3Mn(PO4)(CO3) |
title_fullStr |
A vibrational spectroscopic study of the anhydrous phosphate mineral sidorenkite Na3Mn(PO4)(CO3) |
title_full_unstemmed |
A vibrational spectroscopic study of the anhydrous phosphate mineral sidorenkite Na3Mn(PO4)(CO3) |
title_sort |
vibrational spectroscopic study of the anhydrous phosphate mineral sidorenkite na3mn(po4)(co3) |
publisher |
Elsevier |
publishDate |
2015 |
url |
https://eprints.qut.edu.au/83664/ |
long_lat |
ENVELOPE(34.533,34.533,67.900,67.900) |
geographic |
Alluaiv Kola Peninsula |
geographic_facet |
Alluaiv Kola Peninsula |
genre |
kola peninsula |
genre_facet |
kola peninsula |
op_source |
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |
op_relation |
doi:10.1016/j.saa.2014.08.029 Frost, Ray, Lopez Toro, Andres, Scholz, Ricardo, Belotti, Fernanda, & Xi, Yunfei (2015) A vibrational spectroscopic study of the anhydrous phosphate mineral sidorenkite Na3Mn(PO4)(CO3). Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 137, pp. 930-934. https://eprints.qut.edu.au/83664/ Institute for Future Environments; Science & Engineering Faculty; School of Chemistry, Physics & Mechanical Engineering |
op_rights |
Consult author(s) regarding copyright matters This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au |
op_doi |
https://doi.org/10.1016/j.saa.2014.08.029 |
container_title |
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |
container_volume |
137 |
container_start_page |
930 |
op_container_end_page |
934 |
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1789334373262163968 |