A Raman spectroscopic study of the mono-hydrogen phosphate mineral dorfmanite Na2(PO3OH).2H2O and in comparison with brushite
Aspects of the molecular structure of the mineral dorfmanite Na2(PO3OH)•2H2O were determined by Raman spectroscopy. The mineral originated from the Kedykverpakhk Mt., Lovozero, Kola Peninsula, Russia. Raman bands are assigned to the hydrogen phosphate units. The intense Raman band at 949 cm-1 and th...
Published in: | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |
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ftqueensland:oai:eprints.qut.edu.au:45969 2024-02-04T10:01:53+01:00 A Raman spectroscopic study of the mono-hydrogen phosphate mineral dorfmanite Na2(PO3OH).2H2O and in comparison with brushite Frost, Ray Palmer, Sara Xi, Yunfei 2011 application/pdf https://eprints.qut.edu.au/45969/ unknown Elsevier https://eprints.qut.edu.au/45969/1/45969A.pdf doi:10.1016/j.saa.2011.07.015 Frost, Ray, Palmer, Sara, & Xi, Yunfei (2011) A Raman spectroscopic study of the mono-hydrogen phosphate mineral dorfmanite Na2(PO3OH).2H2O and in comparison with brushite. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 82(1), pp. 132-136. https://eprints.qut.edu.au/45969/ Faculty of Science and Technology; Biogeoscience; Science & Engineering Faculty free_to_read http://creativecommons.org/licenses/by-nc-nd/2.5/ Consult author(s) regarding copyright matters This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy Catalanoite Disodium hydrogen phosphate Dorfmanite Nahpoite Raman spectroscopy Contribution to Journal 2011 ftqueensland https://doi.org/10.1016/j.saa.2011.07.015 2024-01-08T23:28:21Z Aspects of the molecular structure of the mineral dorfmanite Na2(PO3OH)•2H2O were determined by Raman spectroscopy. The mineral originated from the Kedykverpakhk Mt., Lovozero, Kola Peninsula, Russia. Raman bands are assigned to the hydrogen phosphate units. The intense Raman band at 949 cm-1 and the less intense band at 866 cm-1 are assigned to the PO3 and POH stretching vibrations. Bands at 991, 1066 and 1141 cm-1 are assigned to the ν3 antisymmetric stretching modes. Raman bands at 393, 413 and 448 cm-1 and 514, 541 and 570 cm-1 are attributed to the ν2 and ν4 bending modes of the HPO4 units, respectively. Raman bands at 3373, 3443 and 3492 cm-1 are assigned to water stretching vibrations. POH stretching vibrations are identified by bands at 2904, 3080 and 3134 cm-1. Raman spectroscopy has proven very useful for the study of the structure of the mineral dorfmanite. Article in Journal/Newspaper kola peninsula Queensland University of Technology: QUT ePrints Kola Peninsula Lovozero ENVELOPE(35.016,35.016,68.006,68.006) Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 82 1 132 136 |
institution |
Open Polar |
collection |
Queensland University of Technology: QUT ePrints |
op_collection_id |
ftqueensland |
language |
unknown |
topic |
Catalanoite Disodium hydrogen phosphate Dorfmanite Nahpoite Raman spectroscopy |
spellingShingle |
Catalanoite Disodium hydrogen phosphate Dorfmanite Nahpoite Raman spectroscopy Frost, Ray Palmer, Sara Xi, Yunfei A Raman spectroscopic study of the mono-hydrogen phosphate mineral dorfmanite Na2(PO3OH).2H2O and in comparison with brushite |
topic_facet |
Catalanoite Disodium hydrogen phosphate Dorfmanite Nahpoite Raman spectroscopy |
description |
Aspects of the molecular structure of the mineral dorfmanite Na2(PO3OH)•2H2O were determined by Raman spectroscopy. The mineral originated from the Kedykverpakhk Mt., Lovozero, Kola Peninsula, Russia. Raman bands are assigned to the hydrogen phosphate units. The intense Raman band at 949 cm-1 and the less intense band at 866 cm-1 are assigned to the PO3 and POH stretching vibrations. Bands at 991, 1066 and 1141 cm-1 are assigned to the ν3 antisymmetric stretching modes. Raman bands at 393, 413 and 448 cm-1 and 514, 541 and 570 cm-1 are attributed to the ν2 and ν4 bending modes of the HPO4 units, respectively. Raman bands at 3373, 3443 and 3492 cm-1 are assigned to water stretching vibrations. POH stretching vibrations are identified by bands at 2904, 3080 and 3134 cm-1. Raman spectroscopy has proven very useful for the study of the structure of the mineral dorfmanite. |
format |
Article in Journal/Newspaper |
author |
Frost, Ray Palmer, Sara Xi, Yunfei |
author_facet |
Frost, Ray Palmer, Sara Xi, Yunfei |
author_sort |
Frost, Ray |
title |
A Raman spectroscopic study of the mono-hydrogen phosphate mineral dorfmanite Na2(PO3OH).2H2O and in comparison with brushite |
title_short |
A Raman spectroscopic study of the mono-hydrogen phosphate mineral dorfmanite Na2(PO3OH).2H2O and in comparison with brushite |
title_full |
A Raman spectroscopic study of the mono-hydrogen phosphate mineral dorfmanite Na2(PO3OH).2H2O and in comparison with brushite |
title_fullStr |
A Raman spectroscopic study of the mono-hydrogen phosphate mineral dorfmanite Na2(PO3OH).2H2O and in comparison with brushite |
title_full_unstemmed |
A Raman spectroscopic study of the mono-hydrogen phosphate mineral dorfmanite Na2(PO3OH).2H2O and in comparison with brushite |
title_sort |
raman spectroscopic study of the mono-hydrogen phosphate mineral dorfmanite na2(po3oh).2h2o and in comparison with brushite |
publisher |
Elsevier |
publishDate |
2011 |
url |
https://eprints.qut.edu.au/45969/ |
long_lat |
ENVELOPE(35.016,35.016,68.006,68.006) |
geographic |
Kola Peninsula Lovozero |
geographic_facet |
Kola Peninsula Lovozero |
genre |
kola peninsula |
genre_facet |
kola peninsula |
op_source |
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |
op_relation |
https://eprints.qut.edu.au/45969/1/45969A.pdf doi:10.1016/j.saa.2011.07.015 Frost, Ray, Palmer, Sara, & Xi, Yunfei (2011) A Raman spectroscopic study of the mono-hydrogen phosphate mineral dorfmanite Na2(PO3OH).2H2O and in comparison with brushite. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 82(1), pp. 132-136. https://eprints.qut.edu.au/45969/ Faculty of Science and Technology; Biogeoscience; Science & Engineering Faculty |
op_rights |
free_to_read http://creativecommons.org/licenses/by-nc-nd/2.5/ Consult author(s) regarding copyright matters This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the document is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recognise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to qut.copyright@qut.edu.au |
op_doi |
https://doi.org/10.1016/j.saa.2011.07.015 |
container_title |
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |
container_volume |
82 |
container_issue |
1 |
container_start_page |
132 |
op_container_end_page |
136 |
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1789968113552326656 |