Lipase-Catalyzed Synthesis of Renewable Plant Oil-Based Polyamides

Enzyme catalyzed synthesis of renewable polyamides was investigated using Candida antarctica lipase B. A fatty acid-derived AB-type functional monomer, having one amine and one methyl ester functionality, was homopolymerized at 80 and 140 °C. Additionally, the organobase 1,5,7-triazabicyclo[4.4.0]de...

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Published in:Polymers
Main Authors: Finnveden, Maja, Hendil-Forssell, Peter, Claudino, Mauro, Johansson, Mats, Martinelle, Mats
Format: Text
Language:English
Published: MDPI 2019
Subjects:
Communication
Antarc*
Antarctica
Online Access:http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6918247/
http://www.ncbi.nlm.nih.gov/pubmed/31652736
https://doi.org/10.3390/polym11111730
id ftpubmed:oai:pubmedcentral.nih.gov:6918247
record_format openpolar
spelling ftpubmed:oai:pubmedcentral.nih.gov:6918247 2023-05-15T13:43:29+02:00 Lipase-Catalyzed Synthesis of Renewable Plant Oil-Based Polyamides Finnveden, Maja Hendil-Forssell, Peter Claudino, Mauro Johansson, Mats Martinelle, Mats 2019-10-23 http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6918247/ http://www.ncbi.nlm.nih.gov/pubmed/31652736 https://doi.org/10.3390/polym11111730 en eng MDPI http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6918247/ http://www.ncbi.nlm.nih.gov/pubmed/31652736 http://dx.doi.org/10.3390/polym11111730 © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). CC-BY Communication Text 2019 ftpubmed https://doi.org/10.3390/polym11111730 2019-12-29T01:23:50Z Enzyme catalyzed synthesis of renewable polyamides was investigated using Candida antarctica lipase B. A fatty acid-derived AB-type functional monomer, having one amine and one methyl ester functionality, was homopolymerized at 80 and 140 °C. Additionally, the organobase 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) was used as a catalyst. The results from the two catalysts were comparable. However, the amount of lipase added was 1.2 × 10(3) times lower, showing that the lipase was a more efficient catalyst for this system as compared to TBD. Moreover, the AB-type monomer was copolymerized with 1,12-diaminododecane to synthesize oligoamides of two different lengths. Text Antarc* Antarctica PubMed Central (PMC) Polymers 11 11 1730
institution Open Polar
collection PubMed Central (PMC)
op_collection_id ftpubmed
language English
topic Communication
spellingShingle Communication
Finnveden, Maja
Hendil-Forssell, Peter
Claudino, Mauro
Johansson, Mats
Martinelle, Mats
Lipase-Catalyzed Synthesis of Renewable Plant Oil-Based Polyamides
topic_facet Communication
description Enzyme catalyzed synthesis of renewable polyamides was investigated using Candida antarctica lipase B. A fatty acid-derived AB-type functional monomer, having one amine and one methyl ester functionality, was homopolymerized at 80 and 140 °C. Additionally, the organobase 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) was used as a catalyst. The results from the two catalysts were comparable. However, the amount of lipase added was 1.2 × 10(3) times lower, showing that the lipase was a more efficient catalyst for this system as compared to TBD. Moreover, the AB-type monomer was copolymerized with 1,12-diaminododecane to synthesize oligoamides of two different lengths.
format Text
author Finnveden, Maja
Hendil-Forssell, Peter
Claudino, Mauro
Johansson, Mats
Martinelle, Mats
author_facet Finnveden, Maja
Hendil-Forssell, Peter
Claudino, Mauro
Johansson, Mats
Martinelle, Mats
author_sort Finnveden, Maja
title Lipase-Catalyzed Synthesis of Renewable Plant Oil-Based Polyamides
title_short Lipase-Catalyzed Synthesis of Renewable Plant Oil-Based Polyamides
title_full Lipase-Catalyzed Synthesis of Renewable Plant Oil-Based Polyamides
title_fullStr Lipase-Catalyzed Synthesis of Renewable Plant Oil-Based Polyamides
title_full_unstemmed Lipase-Catalyzed Synthesis of Renewable Plant Oil-Based Polyamides
title_sort lipase-catalyzed synthesis of renewable plant oil-based polyamides
publisher MDPI
publishDate 2019
url http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6918247/
http://www.ncbi.nlm.nih.gov/pubmed/31652736
https://doi.org/10.3390/polym11111730
genre Antarc*
Antarctica
genre_facet Antarc*
Antarctica
op_relation http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6918247/
http://www.ncbi.nlm.nih.gov/pubmed/31652736
http://dx.doi.org/10.3390/polym11111730
op_rights © 2019 by the authors.
Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
op_rightsnorm CC-BY
op_doi https://doi.org/10.3390/polym11111730
container_title Polymers
container_volume 11
container_issue 11
container_start_page 1730
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