Enzymatic Synthesis and Characterization of Hydrophilic Sugar Based Polyesters and Their Modification with Stearic Acid

Biodegradable and hydrophilic functional polyesters were synthesized enzymatically using xylitol or d-sorbitol together with divinyl adipate and lipase B from Candida antartica (CAL-B). The resulting polyesters had pendant OH-groups from their sugar units which were esterified to different degrees w...

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Bibliographic Details
Published in:Polymers
Main Authors: Bilal, Muhammad Humayun, Prehm, Marko, Njau, Andrew Efraim, Samiullah, Muhammad Haris, Meister, Annette, Kressler, Jörg
Format: Text
Language:English
Published: MDPI 2016
Subjects:
Article
antartic*
Online Access:http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6432536/
https://doi.org/10.3390/polym8030080
Description
Summary:Biodegradable and hydrophilic functional polyesters were synthesized enzymatically using xylitol or d-sorbitol together with divinyl adipate and lipase B from Candida antartica (CAL-B). The resulting polyesters had pendant OH-groups from their sugar units which were esterified to different degrees with stearic acid chloride. The structure and the degrees of polymerization of the resulting graft copolymers based on poly(xylitol adipate) and poly(d-sorbitol adipate) were characterized by (1)H NMR spectroscopy and SEC. DSC, WAXS and SAXS measurements indicated that a phase separation between polymer backbone and stearoyl side chains occurred in the graft copolymers, and, additionally, the side chains were able to crystallize which resulted in the formation of a lamellar morphology. Additionally, nanoparticles of the graft copolymers in an aqueous environment were studied by DLS and negative stain TEM.

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