The reaction of Fe(III) myoglobin fluoride with reducing agents.
The reaction of reducing agents with Fe(III) myoglobin fluoride from sperm whale was studied at alkaline pH values. The rate of reduction by dithionite was indistinguishable from the rate of ligand dissociation even when the values of the rate constants for both were only 1.0 X 10(-3)S-1 (at pH 10.6...
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1977
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| Online Access: | http://www.ncbi.nlm.nih.gov/pmc/articles/PMC1183683 http://www.ncbi.nlm.nih.gov/pubmed/23114 |
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ftpubmed:oai:pubmedcentral.nih.gov:1183683 2023-05-15T18:26:40+02:00 The reaction of Fe(III) myoglobin fluoride with reducing agents. Cox, R P 1977-11-01 http://www.ncbi.nlm.nih.gov/pmc/articles/PMC1183683 http://www.ncbi.nlm.nih.gov/pubmed/23114 en eng http://www.ncbi.nlm.nih.gov/pmc/articles/PMC1183683 http://www.ncbi.nlm.nih.gov/pubmed/23114 Research Article Text 1977 ftpubmed 2013-08-30T12:15:12Z The reaction of reducing agents with Fe(III) myoglobin fluoride from sperm whale was studied at alkaline pH values. The rate of reduction by dithionite was indistinguishable from the rate of ligand dissociation even when the values of the rate constants for both were only 1.0 X 10(-3)S-1 (at pH 10.6). Reduction by the reduced Methyl Viologen radical ion and reduced Safranine was faster than the rate of dissociation, providing evidence that these reductants can donate electrons to the iron centre via a pathway involving an (undetectable) liganded Fe(II) intermediate. Text Sperm whale PubMed Central (PMC) |
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Open Polar |
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PubMed Central (PMC) |
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ftpubmed |
| language |
English |
| topic |
Research Article |
| spellingShingle |
Research Article Cox, R P The reaction of Fe(III) myoglobin fluoride with reducing agents. |
| topic_facet |
Research Article |
| description |
The reaction of reducing agents with Fe(III) myoglobin fluoride from sperm whale was studied at alkaline pH values. The rate of reduction by dithionite was indistinguishable from the rate of ligand dissociation even when the values of the rate constants for both were only 1.0 X 10(-3)S-1 (at pH 10.6). Reduction by the reduced Methyl Viologen radical ion and reduced Safranine was faster than the rate of dissociation, providing evidence that these reductants can donate electrons to the iron centre via a pathway involving an (undetectable) liganded Fe(II) intermediate. |
| format |
Text |
| author |
Cox, R P |
| author_facet |
Cox, R P |
| author_sort |
Cox, R P |
| title |
The reaction of Fe(III) myoglobin fluoride with reducing agents. |
| title_short |
The reaction of Fe(III) myoglobin fluoride with reducing agents. |
| title_full |
The reaction of Fe(III) myoglobin fluoride with reducing agents. |
| title_fullStr |
The reaction of Fe(III) myoglobin fluoride with reducing agents. |
| title_full_unstemmed |
The reaction of Fe(III) myoglobin fluoride with reducing agents. |
| title_sort |
reaction of fe(iii) myoglobin fluoride with reducing agents. |
| publishDate |
1977 |
| url |
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC1183683 http://www.ncbi.nlm.nih.gov/pubmed/23114 |
| genre |
Sperm whale |
| genre_facet |
Sperm whale |
| op_relation |
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC1183683 http://www.ncbi.nlm.nih.gov/pubmed/23114 |
| _version_ |
1766208644585619456 |