Enzymatically catalyzed furan-based copolyesters containing dilinoleic diol as a building block
A more environmentally friendly method for creating sustainable alternatives to traditional aromatic–aliphatic polyesters is a valuable step towards resource-efficiency optimization. A library of furan-based block copolymers was synthesized via temperature-varied two-step polycondensation reaction i...
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The Royal Society of Chemistry
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ftpubmed:oai:pubmedcentral.nih.gov:10363961 2023-08-20T04:00:34+02:00 Enzymatically catalyzed furan-based copolyesters containing dilinoleic diol as a building block Sokołowska, Martyna Nowak-Grzebyta, Jagoda Stachowska, Ewa Miądlicki, Piotr Zdanowicz, Magdalena Michalkiewicz, Beata El Fray, Miroslawa 2023-07-24 http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10363961/ http://www.ncbi.nlm.nih.gov/pubmed/37492515 https://doi.org/10.1039/d3ra03885h en eng The Royal Society of Chemistry http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10363961/ http://www.ncbi.nlm.nih.gov/pubmed/37492515 http://dx.doi.org/10.1039/d3ra03885h This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ RSC Adv Chemistry Text 2023 ftpubmed https://doi.org/10.1039/d3ra03885h 2023-07-30T00:49:16Z A more environmentally friendly method for creating sustainable alternatives to traditional aromatic–aliphatic polyesters is a valuable step towards resource-efficiency optimization. A library of furan-based block copolymers was synthesized via temperature-varied two-step polycondensation reaction in diphenyl ether using Candida antarctica lipase B (CAL-B) as a biocatalyst where dimethyl 2,5-furandicarboxylate (DMFDCA), α,ω-aliphatic linear diols (α,ω-ALD), and bio-based dilinoleic diol (DLD) were used as the starting materials. Nuclear magnetic spectroscopy ((1)H and (13)C NMR), Fourier transform spectroscopy (FTIR) and size exclusion chromatography (SEC) were used to analyze the resulting copolymers. Additionally, crystallization behavior and thermal properties were studied using X-ray diffraction (XRD), digital holographic microscopy (DHM), and differential scanning microscopy (DSC). Finally, oxygen transmission rates (OTR) and dynamic mechanical analysis (DMTA) of furan-based copolyesters indicated their potential for medical packaging. Text Antarc* Antarctica PubMed Central (PMC) RSC Advances 13 32 22234 22249 |
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Chemistry Sokołowska, Martyna Nowak-Grzebyta, Jagoda Stachowska, Ewa Miądlicki, Piotr Zdanowicz, Magdalena Michalkiewicz, Beata El Fray, Miroslawa Enzymatically catalyzed furan-based copolyesters containing dilinoleic diol as a building block |
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Chemistry |
description |
A more environmentally friendly method for creating sustainable alternatives to traditional aromatic–aliphatic polyesters is a valuable step towards resource-efficiency optimization. A library of furan-based block copolymers was synthesized via temperature-varied two-step polycondensation reaction in diphenyl ether using Candida antarctica lipase B (CAL-B) as a biocatalyst where dimethyl 2,5-furandicarboxylate (DMFDCA), α,ω-aliphatic linear diols (α,ω-ALD), and bio-based dilinoleic diol (DLD) were used as the starting materials. Nuclear magnetic spectroscopy ((1)H and (13)C NMR), Fourier transform spectroscopy (FTIR) and size exclusion chromatography (SEC) were used to analyze the resulting copolymers. Additionally, crystallization behavior and thermal properties were studied using X-ray diffraction (XRD), digital holographic microscopy (DHM), and differential scanning microscopy (DSC). Finally, oxygen transmission rates (OTR) and dynamic mechanical analysis (DMTA) of furan-based copolyesters indicated their potential for medical packaging. |
format |
Text |
author |
Sokołowska, Martyna Nowak-Grzebyta, Jagoda Stachowska, Ewa Miądlicki, Piotr Zdanowicz, Magdalena Michalkiewicz, Beata El Fray, Miroslawa |
author_facet |
Sokołowska, Martyna Nowak-Grzebyta, Jagoda Stachowska, Ewa Miądlicki, Piotr Zdanowicz, Magdalena Michalkiewicz, Beata El Fray, Miroslawa |
author_sort |
Sokołowska, Martyna |
title |
Enzymatically catalyzed furan-based copolyesters containing dilinoleic diol as a building block |
title_short |
Enzymatically catalyzed furan-based copolyesters containing dilinoleic diol as a building block |
title_full |
Enzymatically catalyzed furan-based copolyesters containing dilinoleic diol as a building block |
title_fullStr |
Enzymatically catalyzed furan-based copolyesters containing dilinoleic diol as a building block |
title_full_unstemmed |
Enzymatically catalyzed furan-based copolyesters containing dilinoleic diol as a building block |
title_sort |
enzymatically catalyzed furan-based copolyesters containing dilinoleic diol as a building block |
publisher |
The Royal Society of Chemistry |
publishDate |
2023 |
url |
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10363961/ http://www.ncbi.nlm.nih.gov/pubmed/37492515 https://doi.org/10.1039/d3ra03885h |
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Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
RSC Adv |
op_relation |
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10363961/ http://www.ncbi.nlm.nih.gov/pubmed/37492515 http://dx.doi.org/10.1039/d3ra03885h |
op_rights |
This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
op_doi |
https://doi.org/10.1039/d3ra03885h |
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RSC Advances |
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13 |
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32 |
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22234 |
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22249 |
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