Latitudinal and Seasonal Distribution of Particulate MSA over the Atlantic using a Validated Quantification Method with HR-ToF-AMS

• Published in: Environmental Science & Technology
• Main Authors: Huang, Shan, Poulain, Laurent, van Pinxteren, Dominik, van Pinxteren, Manuela, Wu, Zhijun, Herrmann, Hartmut, Wiedensohler, Alfred
• Other Authors: Poulain, L (reprint author), Leibniz Inst Tropospher Res, D-04318 Leipzig, Sachsen, Germany., Leibniz Inst Tropospher Res, D-04318 Leipzig, Sachsen, Germany., Jinan Univ, Inst Environm & Climate Res, Guangzhou 511443, Guangdong, Peoples R China., Peking Univ, Coll Environm Sci & Engn, Beijing 100871, Peoples R China.
• Format: Journal/Newspaper
• Language: English
• Published: ENVIRONMENTAL SCIENCE & TECHNOLOGY 2017
• Subjects: MARINE BOUNDARY-LAYER; AEROSOL MASS-SPECTROMETER; SEA-SALT SULFATE; ORGANIC-MATTER ENRICHMENT; CHEMICAL-CHARACTERIZATION; SIZE DISTRIBUTIONS; MEDITERRANEAN SEA; DIMETHYL SULFIDE; SULFUR-COMPOUNDS; HIGH-RESOLUTION; South Atlantic Ocean
• Online Access: https://hdl.handle.net/20.500.11897/475779; https://doi.org/10.1021/acs.est.6b03186

Methanesulfonic acid (MSA) has been widely used as a proxy for marine biogenic sources, but it is still a challenge to provide an accurate MSA mass concentration with high time resolution. This study offers an improved MSA quantification method using high resolution time of-flight aerosol mass spectrometer (HR-ToF-AMS). Particularly, the method was validated based on an excellent agreement with parallel offline measurements (slope = 0.88, R-2 = 0.89). This comparison is much better than those using previously reported methods, resulting in underestimations of 31-54% of MSA concentration. With this new method, MSA mass concentrations were obtained during 4 North/South Atlantic cruises in spring and autumn of 2011 and 2012. The seasonal and spatial variation of the particulate MSA mass concentration as well as the MSA to non-sea-salt sulfate ratio (MSA:nssSO(4)) over the North/South Atlantic Ocean were determined for the first time. Seasonal variation of the MSA mass concentration was observed, with higher values in spring (0.03 mu g m(-3)) than in autumn (0.01 mu g m(-3)). The investigation of MSA:nssSO(4) suggests a ubiquitous and significant influence of anthropogenic sources on aerosols in the marine boundary layer. Gottfried Wilhelm Leibniz Association (OCEANET project); [AWI_ANT27/4]; [AWI_ANT28/1]; [AWI_ANT28/5]; [AWIANT29/1] SCI(E) ARTICLE 1 418-426 51