KOSMOS 2020 Peru mesocosm study on ecosystem responses to different light and upwelling intensities: dissolved inorganic carbon concentration and total alkalinity of water samples

• Main Authors: Thielecke, Antonia, Meyer, Jana, Ludwig, Andrea, Schulz, Kai Georg
• Format: Dataset
• Language: English
• Published: PANGAEA 2023
• Subjects: Alkalinity; total; AQUACOSM; Automated Infra Red Inorganic Carbon Analyzer (AIRICA); MARIANDA; with a LICOR detector (LI-7000 CO2/H2O Analyzer); Carbon; inorganic; dissolved; Coastal Upwelling System in a Changing Ocean; Comment; CUSCO; DATE/TIME; Day of experiment; Depth; water; experiment; bottom/maximum; top/minimum; DIC; Event label; Field experiment; Gas chromatography - Mass spectrometry (GC-MS); Humboldt Current System; KOSMOS_2020; KOSMOS_2020_Mesocosm-M1; KOSMOS_2020_Mesocosm-M10; KOSMOS_2020_Mesocosm-M2; KOSMOS_2020_Mesocosm-M3; KOSMOS_2020_Mesocosm-M4; KOSMOS_2020_Mesocosm-M5; KOSMOS_2020_Mesocosm-M6; KOSMOS_2020_Mesocosm-M7; KOSMOS_2020_Mesocosm-M8; KOSMOS_2020_Mesocosm-M9; KOSMOS Peru; light limitation; MESO; Mesocosm experiment; Mesocosm label; mesocosm study; Network of Leading European AQUAtic MesoCOSM Facilities Connecting Mountains to Oceans from the Arctic to the Mediterranean; Potentiometric titration; Metrohm 862 Compact Titrosampler; TA alkalinity; Treatment; Treatment: light condition; Arctic
• Online Access: https://doi.pangaea.de/10.1594/PANGAEA.961215; https://doi.org/10.1594/PANGAEA.961215

This data is part of the BMBF project CUSCO (Coastal Upwelling Systems in a Changing Ocean). Here we report the dissolved inorganic carbon concentration and total alkalinity during a 35-day experiment, where we enclosed natural plankton communities in in-situ mesocosms off Peru. The experiment investigated the interactive effects of light and upwelling on the Humboldt upwelling ecosystem by mimicking a gradient of upwelling intensities (0%, 15%, 30%, 45% and 60%) under summer-time high light and winter-time low light. Integrated seawater samples from a depth between 0 and 10m were collected using a 5L Integrating Water sampler (IWS; Hydro-Bios, Kiel). Dissolved inorganic carbon (DIC) and total alkalinity (TA) samples were obtained by 0.2µm gentle pressure filtration, poisoned with saturated 7.5 % mercury chloride (HgCl2) solution and frozen at -20°C until measurement. Samples for Total Alkalinity (TA) were measured by means of potentiometric titration with 0.05 M HCl using an automated titration device (862 Metrohm Compact Titrosampler). All DIC samples taken until day 17 were measured using an Automated Infra-Red Inorganic Carbon Analyzer (AIRICA) with a LICOR detector (LI-7000 CO2/H20 Analyzer, MARIANDA, Kiel). Certified reference material (Dickson standard for oceanic CO2 Measurements - CRM Batch 142 with salinity = 33.389 and DIC = 2038,07 µmol/kg) was measured and used to correct measured sample values. Additional DIC samples were measured using gas chromatography-mass spectrometry (GC-MS) to determine the 13C signal. The data of the GC-MS was adjusted to the AIRICA data using a linear transformation. Missing days were filled using an average of the day before and after.