Stable oxygen isotope ratios in zircons from oceanic crust

• Main Authors: Grimes, Craig B, Ushikubo, Takayuki, John, Barbara E, Valley, John W
• Format: Dataset
• Language: English
• Published: PANGAEA 2011
• Subjects: 118-735B; 179-1105A; 209-1270D; 209-1275D; 304-U1309B; 304-U1309D; 305-U1309D; Atlantic; DRILL; Drilling/drill rig; Exp304; Exp305; Indian Ocean; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; Joides Resolution; Leg118; Leg179; Leg209; Marvel2000; MULT; Multiple investigations; North Atlantic Ocean; Ocean Drilling Program; Oceanic Core Complex Formation; Atlantis Massive 1; Atlantis Massive 2; ODP; South Indian Ridge; South Indian Ocean; Indian; North Atlantic
• Online Access: https://doi.pangaea.de/10.1594/PANGAEA.772319; https://doi.org/10.1594/PANGAEA.772319

Lower ocean crust is primarily gabbroic, although 1-2% felsic igneous rocks that are referred to collectively as plagiogranites occur locally. Recent experimental evidence suggests that plagiogranite magmas can form by hydrous partial melting of gabbro triggered by seawater-derived fluids, and thus they may indicate early, high-temperature hydrothermal fluid circulation. To explore seawater-rock interaction prior to and during the genesis of plagiogranite and other late-stage magmas, oxygen-isotope ratios preserved in igneous zircon have been measured by ion microprobe. A total of 197 zircons from 43 plagiogranite, evolved gabbro, and hydrothermally altered fault rock samples have been analyzed. Samples originate primarily from drill core acquired during Ocean Drilling Program and Integrated Ocean Drilling Program operations near the Mid-Atlantic and Southwest Indian Ridges. With the exception of rare, distinctively luminescent rims, all zircons from ocean crust record remarkably uniform d18O with an average value of 5.2 ± 0.5 per mil (2SD). The average d18O(Zrc) would be in magmatic equilibrium with unaltered MORB [d18O(WR) ~5.6-5.7 per mil], and is consistent with the previously determined value for equilibrium with the mantle. The narrow range of measured d18O values is predicted for zircon crystallization from variable parent melt compositions and temperatures in a closed system, and provides no indication of any interactions between altered rocks or seawater and the evolved parent melts. If plagiogranite forms by hydrous partial melting, the uniform mantle-like d18O(Zrc) requires melting and zircon crystallization prior to significant amounts of water-rock interactions that alter the protolith d18O. Zircons from ocean crust have been proposed as a tectonic analog for >3.9 Ga detrital zircons from the earliest (Hadean) Earth by multiple workers. However, zircons from ocean crust are readily distinguished geochemically from zircons formed in continental crustal environments. Many of the >3.9 Ga zircons ...