(Table 1) Color, Fe-C-S chemistry and carbonate content from ODP Sites 172-1062 and 172-1063

• Main Authors: Giosan, Liviu, Flood, Roger D, Aller, Robert C
• Format: Dataset
• Language: English
• Published: PANGAEA 2002
• Subjects: 172-1062D; 172-1062E; 172-1063A; Blake-Bahama Outer Ridge; North Atlantic Ocean; Carbon; organic; total; Carbonates; Color; C*; Hue; L*; lightness; Coulometry; Dithionite extraction (Lord; 1980; PhD Thesis Univ Delaware); DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Element analyser CHN; Carlo Erba; Event label; Factor 1; Factor 2; Factor 3; Iron; colorimetric; Ferrozine (Stookey; 1970); Joides Resolution; Leg172; Ocean Drilling Program; ODP; Sample code/label; Spectrophotometer Perkin-Elmer Lambda 6; Sulfur; North Atlantic
• Online Access: https://doi.pangaea.de/10.1594/PANGAEA.764415; https://doi.org/10.1594/PANGAEA.764415

Reflectance spectra collected during ODP Leg 172 were used in concert with solid phase iron chemistry, carbonate content, and organic carbon content measurements to evaluate the agents responsible for setting the color in sediments. Factor analysis has proved a valuable and rapid technique to detect the local and regional primary factors that influence sediment color. On the western North Atlantic drifts, sediment color is the result of primary mineralogy as well as diagenetic changes. Sediment lightness is controlled by the carbonate content while the hue is primarily due to the presence of hematite and Fe2+/Fe3+ changes in clay minerals. Hematite, most likely derived from the Permo-Carboniferous red beds of the Canadian Maritimes, is differentially preserved at various sites due to differences in reductive diagenesis and dilution by other sedimentary components. Various intensities for diagenesis result from changes in organic carbon content, sedimentation rates, and H2S production via anaerobic methane oxidation. Iron monosulfides occur extensively at all high sedimentation sites especially in glacial periods suggesting increased high terrigenous flux and/or increased reactive iron flux in glacials.