(Table 1) Experimental data for kerogens from DSDP Hole 41-368

• Main Authors: Ishiwatari, Ryoshi, Morinaga, Shigeo, Simoneit, Bernd R T
• Format: Dataset
• Language: English
• Published: PANGAEA 1985
• Subjects: 41-368; Aliphatic acids; Aromaticity factor; Benzenecarboxylic acids; Calculated; Deep Sea Drilling Project; Depth; bottom/max; sediment/rock; top/min; Distance; relative; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Gas chromatography - Mass spectrometry (GC-MS); Glomar Challenger; Hydrogen/Carbon ratio; Leg41; North Atlantic/CONT RISE; Sample code/label; Temperature; technical; Vitrinite reflection; North Atlantic
• Online Access: https://doi.pangaea.de/10.1594/PANGAEA.707883; https://doi.org/10.1594/PANGAEA.707883

Potassium permanganate oxidative degradations were conducted for kerogens isolated from Cretaceous black shales (DSDP Leg 41, Site 368), thermally altered during the Miocene by diabase intrusions and from unaltered samples heated under laboratory conditions (250–500°C). Degradation products of less altered kerogens are dominated by normal C4–C15 alpha,omega-dicarboxylic acids, with lesser amounts of n-C16 and n-C18 monocarboxylic acids, and benzene mono-to-tetracarboxylic acids. On the other hand, thermally altered kerogens show benzene di-to-tetracarboxylic acids as dominant degradation products, with lesser or no amounts (variable depending on the degree of thermal alteration) of alpha,omega-dicarboxylic acids. Essentially no differences between the oxidative degradation products of naturally- and artificially-altered kerogens are observed. As a result of this study, five indices of aromatization (total aromatic acids/kerogen; apparent aromaticity; benzenetetracarboxylic acids/total aromatic acids; benzene-1,2-dicarboxylic acid/benzenedicarboxylic acids; benzene-1,2,3-tricarboxylic acid/benzenetricarboxylic acids) and two indices of aliphatic character (Total aliphatic acids/kerogen; Aliphaticity) are proposed to characterize the degree of thermal alteration of kerogens. Furthermore, a good correlation is observed between apparent aromaticity estimated by the present KMnO4 oxidation method and that from the 13C NMR method (Dennis et al., 1982; doi:10.1016/0016-7037(82)90046-1).