(Table 3) Barium barite and excess comparison, accumulation rates and productivity from surface sediments

• Main Authors: Eagle, Meagan, Paytan, Adina, Arrigo, Kevin R, van Dijken, Gert L, Murray, Richard W
• Format: Dataset
• Language: English
• Published: PANGAEA 2003
• Subjects: 11031802 Spadecore1; 11080400 Spadecore2; 11110100 Spadecore3; 11182336 Multicorer14; 11212105 Multicorer17; 11230530 Multicorer18; 11270742 Multicorer22; 11290827 Multicorer25; 12052336 Multicorer35; Accumulation rate per year; Agulhas Ridge; Aluminium; ANT-XI/2; Barium; flux; Barium/PP (Dymond et al 1992); Barium barite/barium excess ratio; Barium excess; Barium in barite; BC; Box corer; Depth; bottom/max; sediment/rock; top/min; Equatorial Pacific; ERDC; ERDC-088BX; ERDC-125BX; Event label; Export production; f-Ratio; GC; Gravity corer; INMD; INMD-106BX; K7905-21BC; MANOP; Melville; MUC; MultiCorer; Nathaniel B. Palmer; NBP9802; NBP9802-03; NBP9802-04; Southern Ocean
• Online Access: https://doi.pangaea.de/10.1594/PANGAEA.115069; https://doi.org/10.1594/PANGAEA.115069

Since Dymond et al. (1992, doi:10.1029/92PA00181) proposed the paleoproductivity algorithm based on “Bio-Ba”, which relies on a strong correlation between Ba and organic carbon fluxes in sediment traps, this proxy has been applied in many paleoproductivity studies. Barite, the main carrier of particulate barium in the water column and the phase associated with carbon export, has also been suggested as a reliable paleoproductivity proxy in some locations. We demonstrate that Ba(excess) (total barium minus the fraction associated with terrigenous material) frequently overestimates Ba(barite) (barium associated with the mineral barite), most likely due to the inclusion of barium from phases other than barite and terrigenous silicates (e.g., carbonate, organic matter, opal, Fe-Mn oxides, and hydroxides). A comparison between overlying oceanic carbon export and carbon export derived from Ba(excess) shows that the Dymond et al. (1992) algorithm frequently underestimates carbon export but is still a useful carbon export indicator if all caveats are considered before the algorithm is applied. Ba(barite) accumulation rates from a wide range of core top sediments from different oceanic settings are highly correlated to surface ocean 14C and Chlorophyll a measurements of primary production. This relationship varies by ocean basin, but with the application of the appropriate f ratio to 14C and Chlorophyll a primary production estimates, the plot of Ba(barite) accumulation and carbon export for the equatorial Pacific, Atlantic, and Southern Ocean converges to a global relationship that can be used to reconstruct paleo carbon export.