ESI-FTICR-MS Molecular Characterization of DOM Degradation under Warming in Tundra Soils from Utqiagvik (Barrow), Alaska

• Main Authors: Chen, Hongmei, Yang, Ziming, Chu, Rosalie, Tolic, Nikola, Liang, Liyuan, Graham, David, Wullschleger, Stan, Gu, Baohua
• Language: unknown
• Published: 2023
• Subjects: 54 Environmental Sciences; Arctic; Barrow; Nome; north slope; permafrost; Seward Peninsula; Tundra; Alaska
• Online Access: http://www.osti.gov/servlets/purl/1410297; https://www.osti.gov/biblio/1410297; https://doi.org/10.5440/1410297

This dataset provides the results of warming incubation of Arctic soils from trough areas of a high-center polygon at the Barrow Environmental Observatory (BEO) in northern Alaska, United States. The organic-rich soil (8-20 cm below ground surface) and the mineral-rich soil (22-45 cm below surface) were separated, and the thawed and homogenized subsamples from each soil were incubated at -2 degrees C or 8 degrees C for 122 days under anoxic conditions (headspace filled with N2). The extracted DOM from soil samples were analyzed by Fourier transform ion cyclotron resonance mass spectrometry coupled with electrospray ionization (ESI-FTICR-MS). Reported analytes include soil water content, dissolved organic carbon, total organic carbon, MS peaks' m/z and intensities, and elemental composition of identified molecular formulas. This dataset includes five csv files and one pdf file. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).