6-O-glucose palmitate synthesis with lipase: Investigation of some key parameters
Fatty acid sugar esters represent an important class of non-ionic bio-based surfactants. They can be synthesized from vinyl fatty acids and sugars with enzyme as a catalyst. Herein, the influence of the solvent, the lipase and the temperature on a model reaction between vinyl palmitate and glucose v...
Published in: | Molecular Catalysis |
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Language: | English |
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ftoskarbordeaux:oai:oskar-bordeaux.fr:20.500.12278/13959 2023-05-15T13:56:04+02:00 6-O-glucose palmitate synthesis with lipase: Investigation of some key parameters ARCENS, Dounia GRAU, Etienne GRELIER, Stéphane CRAMAIL, Henri PERUCH, Frédéric 2018-12 https://oskar-bordeaux.fr/handle/20.500.12278/13959 https://doi.org/10.1016/j.mcat.2018.09.013 en eng Elsevier 0304-5102 https://oskar-bordeaux.fr/handle/20.500.12278/13959 doi:10.1016/j.mcat.2018.09.013 1911.09920 Glycolipids GlycolipidsEnzymatic synthesisLipase Lipase Enzymatic synthesis Chimie/Catalyse Chimie/Chimie organique Sciences du Vivant [q-bio]/Biochimie Biologie Moléculaire/Biochimie [q-bio.BM] Article de revue 2018 ftoskarbordeaux https://doi.org/10.1016/j.mcat.2018.09.013 2020-11-17T23:28:59Z Fatty acid sugar esters represent an important class of non-ionic bio-based surfactants. They can be synthesized from vinyl fatty acids and sugars with enzyme as a catalyst. Herein, the influence of the solvent, the lipase and the temperature on a model reaction between vinyl palmitate and glucose via enzymatic catalysis has been investigated and the reaction conditions optimized. Full conversion into 6-O-glucose palmitate was reached in 40 h in acetonitrile starting from a reactant ratio 1:1, at only 5%-wt loading of lipase from Candida antarctica B (CALB) without the presence of molecular sieves. Other/Unknown Material Antarc* Antarctica OSKAR Bordeaux (Open Science Knowledge ARchive) Molecular Catalysis 460 63 68 |
institution |
Open Polar |
collection |
OSKAR Bordeaux (Open Science Knowledge ARchive) |
op_collection_id |
ftoskarbordeaux |
language |
English |
topic |
Glycolipids GlycolipidsEnzymatic synthesisLipase Lipase Enzymatic synthesis Chimie/Catalyse Chimie/Chimie organique Sciences du Vivant [q-bio]/Biochimie Biologie Moléculaire/Biochimie [q-bio.BM] |
spellingShingle |
Glycolipids GlycolipidsEnzymatic synthesisLipase Lipase Enzymatic synthesis Chimie/Catalyse Chimie/Chimie organique Sciences du Vivant [q-bio]/Biochimie Biologie Moléculaire/Biochimie [q-bio.BM] ARCENS, Dounia GRAU, Etienne GRELIER, Stéphane CRAMAIL, Henri PERUCH, Frédéric 6-O-glucose palmitate synthesis with lipase: Investigation of some key parameters |
topic_facet |
Glycolipids GlycolipidsEnzymatic synthesisLipase Lipase Enzymatic synthesis Chimie/Catalyse Chimie/Chimie organique Sciences du Vivant [q-bio]/Biochimie Biologie Moléculaire/Biochimie [q-bio.BM] |
description |
Fatty acid sugar esters represent an important class of non-ionic bio-based surfactants. They can be synthesized from vinyl fatty acids and sugars with enzyme as a catalyst. Herein, the influence of the solvent, the lipase and the temperature on a model reaction between vinyl palmitate and glucose via enzymatic catalysis has been investigated and the reaction conditions optimized. Full conversion into 6-O-glucose palmitate was reached in 40 h in acetonitrile starting from a reactant ratio 1:1, at only 5%-wt loading of lipase from Candida antarctica B (CALB) without the presence of molecular sieves. |
format |
Other/Unknown Material |
author |
ARCENS, Dounia GRAU, Etienne GRELIER, Stéphane CRAMAIL, Henri PERUCH, Frédéric |
author_facet |
ARCENS, Dounia GRAU, Etienne GRELIER, Stéphane CRAMAIL, Henri PERUCH, Frédéric |
author_sort |
ARCENS, Dounia |
title |
6-O-glucose palmitate synthesis with lipase: Investigation of some key parameters |
title_short |
6-O-glucose palmitate synthesis with lipase: Investigation of some key parameters |
title_full |
6-O-glucose palmitate synthesis with lipase: Investigation of some key parameters |
title_fullStr |
6-O-glucose palmitate synthesis with lipase: Investigation of some key parameters |
title_full_unstemmed |
6-O-glucose palmitate synthesis with lipase: Investigation of some key parameters |
title_sort |
6-o-glucose palmitate synthesis with lipase: investigation of some key parameters |
publisher |
Elsevier |
publishDate |
2018 |
url |
https://oskar-bordeaux.fr/handle/20.500.12278/13959 https://doi.org/10.1016/j.mcat.2018.09.013 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_relation |
0304-5102 https://oskar-bordeaux.fr/handle/20.500.12278/13959 doi:10.1016/j.mcat.2018.09.013 1911.09920 |
op_doi |
https://doi.org/10.1016/j.mcat.2018.09.013 |
container_title |
Molecular Catalysis |
container_volume |
460 |
container_start_page |
63 |
op_container_end_page |
68 |
_version_ |
1766263289834110976 |