Impact of circulation changes on the long-term trend of stratospheric hydrogen fluoride at five NDACC stations

• Main Authors: Prignon, Maxime, Bernath, P.F., Blumenstock, T., Chipperfield, M.P., Hase, F., Schneider, M., Smale, D., Walker, W.A., Chabrillat, S., Servais, Christian, Mahieu, Emmanuel
• Format: Conference Object
• Language: English
• Published: 2017
• Subjects: stratosphere; circulation changes; Climate chemistry; Physical; chemical; mathematical & earth Sciences; Earth sciences & physical geography; Physique; chimie; mathématiques & sciences de la terre; Sciences de la terre & géographie physique; Arrival Heights; Kiruna
• Online Access: https://orbi.uliege.be/handle/2268/211288; https://orbi.uliege.be/bitstream/2268/211288/1/Poster_IRWG2017.pdf

Hydrogen fluoride is mainly produced by the photolysis of anthropogenic source gases such as the chlorofluorocarbons (CFC), the hydrochlorofluorocarbons (HCFC) and the hydrofluorocarbons (HFC). These families of species are known for contributing to ozone depletion and/or to the greenhouse effect. It is thus essential to regulate and monitor their emissions. Despite the fact that the Montreal protocol (1987) has succeeded to reduce and then suppress the CFC emissions, HF is still increasing in the stratosphere because of ongoing emissions of the HCFC and HFC substitution products. In the framework of the recent studies demonstrating the influence of stratospheric circulation changes on the trend of long-lived tracers (e.g. hydrogen chlorine), we decided to investigate the impact of these circulation changes on HF. To achieve this objective, the rates of changes over time of HF total/partial columns at various latitudes of the globe will be determined and critically discussed. Fourier Transform Infrared data produced at five NDACC sites (Kiruna – 68°N, Jungfraujoch – 46°N, Izana – 28°N, Lauder 45°S and Arrival-heights – 78°S) and satellite data (HALOE and ACE) will be used for this study. This preliminary selection of ground-based stations allows to cover both hemispheres and our period of investigation (last two decades). Finally, in order to support our data interpretation, two SLIMCAT simulations (standard and fixed dynamics) will also be included. ACCROSS