Sensitivity of clumped isotope temperatures in fossil benthic and planktic foraminifera to diagenetic alteration
Applying the clumped isotope (Δ 47 ) thermometer to foraminifer microfossils offers the potential to significantly improve paleoclimate reconstructions, owing to its insensitivity to the isotopic composition of seawater (unlike traditional oxygen isotope (δ 18 O) analyses). However, the extent to wh...
Published in: | Geochimica et Cosmochimica Acta |
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Online Access: | https://oro.open.ac.uk/61245/ https://oro.open.ac.uk/61245/1/61245.pdf https://oro.open.ac.uk/61245/8/1-s2.0-S0016703719302625-main.pdf https://doi.org/10.1016/j.gca.2019.05.005 |
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ftopenunivgb:oai:oro.open.ac.uk:61245 2023-06-11T04:14:52+02:00 Sensitivity of clumped isotope temperatures in fossil benthic and planktic foraminifera to diagenetic alteration Leutert, Thomas J. Sexton, Philip Tripati, Aradhna Piasecki, Alison Ling Ho, Sze Meckler, A. Nele 2019-07-15 application/pdf https://oro.open.ac.uk/61245/ https://oro.open.ac.uk/61245/1/61245.pdf https://oro.open.ac.uk/61245/8/1-s2.0-S0016703719302625-main.pdf https://doi.org/10.1016/j.gca.2019.05.005 unknown https://oro.open.ac.uk/61245/1/61245.pdf https://oro.open.ac.uk/61245/8/1-s2.0-S0016703719302625-main.pdf Leutert, Thomas J.; Sexton, Philip <http://oro.open.ac.uk/view/person/pfs67.html>; Tripati, Aradhna; Piasecki, Alison; Ling Ho, Sze and Meckler, A. Nele (2019). Sensitivity of clumped isotope temperatures in fossil benthic and planktic foraminifera to diagenetic alteration. Geochimica et Cosmochimica Acta, 257 pp. 354–372. Journal Item Public PeerReviewed 2019 ftopenunivgb https://doi.org/10.1016/j.gca.2019.05.005 2023-05-28T05:59:48Z Applying the clumped isotope (Δ 47 ) thermometer to foraminifer microfossils offers the potential to significantly improve paleoclimate reconstructions, owing to its insensitivity to the isotopic composition of seawater (unlike traditional oxygen isotope (δ 18 O) analyses). However, the extent to which primary Δ47 signatures of foraminiferal calcites can be overprinted during diagenesis is not well known. Here, we present Δ47 data as well as high-resolution (∼10 kyr) δ 18 O and δ 13 C middle Eocene time series, measured on benthic and planktic foraminifera from ODP/IODP Sites 1408, 1409, 1410, 1050, 1260 and 1263 in the Atlantic Ocean. The sites examined span various oceanographic regimes, including the western tropical to mid-latitude North Atlantic, and the eastern mid-latitude South Atlantic. Comparing data from contemporaneous foraminifera with different preservation states, we test the effects of diagenetic alteration on paleotemperature reconstructions for the deep and surface ocean. We find that overall, primary Δ 47 signatures appear similarly sensitive to diagenetic overprinting as δ 18 O, with differences in sensitivity depending on pore fluid chemistry and the amount of secondary calcite. Where planktic foraminifera are significantly altered, sea surface temperatures derived from Δ 47 and δ 18 O values are biased towards cool temperatures. In comparison, Δ 47 and δ 18 O values of benthic and well preserved planktic foraminifera are less affected by diagenesis and thus likely to yield robust foraminiferal calcification temperatures. With independent estimates of diagenetic calcite fractions, secondary overprints could be corrected for, using end-member modeling and Δ 47 -based temperatures from benthic foraminifera. Article in Journal/Newspaper North Atlantic The Open University: Open Research Online (ORO) Geochimica et Cosmochimica Acta 257 354 372 |
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Open Polar |
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The Open University: Open Research Online (ORO) |
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ftopenunivgb |
language |
unknown |
description |
Applying the clumped isotope (Δ 47 ) thermometer to foraminifer microfossils offers the potential to significantly improve paleoclimate reconstructions, owing to its insensitivity to the isotopic composition of seawater (unlike traditional oxygen isotope (δ 18 O) analyses). However, the extent to which primary Δ47 signatures of foraminiferal calcites can be overprinted during diagenesis is not well known. Here, we present Δ47 data as well as high-resolution (∼10 kyr) δ 18 O and δ 13 C middle Eocene time series, measured on benthic and planktic foraminifera from ODP/IODP Sites 1408, 1409, 1410, 1050, 1260 and 1263 in the Atlantic Ocean. The sites examined span various oceanographic regimes, including the western tropical to mid-latitude North Atlantic, and the eastern mid-latitude South Atlantic. Comparing data from contemporaneous foraminifera with different preservation states, we test the effects of diagenetic alteration on paleotemperature reconstructions for the deep and surface ocean. We find that overall, primary Δ 47 signatures appear similarly sensitive to diagenetic overprinting as δ 18 O, with differences in sensitivity depending on pore fluid chemistry and the amount of secondary calcite. Where planktic foraminifera are significantly altered, sea surface temperatures derived from Δ 47 and δ 18 O values are biased towards cool temperatures. In comparison, Δ 47 and δ 18 O values of benthic and well preserved planktic foraminifera are less affected by diagenesis and thus likely to yield robust foraminiferal calcification temperatures. With independent estimates of diagenetic calcite fractions, secondary overprints could be corrected for, using end-member modeling and Δ 47 -based temperatures from benthic foraminifera. |
format |
Article in Journal/Newspaper |
author |
Leutert, Thomas J. Sexton, Philip Tripati, Aradhna Piasecki, Alison Ling Ho, Sze Meckler, A. Nele |
spellingShingle |
Leutert, Thomas J. Sexton, Philip Tripati, Aradhna Piasecki, Alison Ling Ho, Sze Meckler, A. Nele Sensitivity of clumped isotope temperatures in fossil benthic and planktic foraminifera to diagenetic alteration |
author_facet |
Leutert, Thomas J. Sexton, Philip Tripati, Aradhna Piasecki, Alison Ling Ho, Sze Meckler, A. Nele |
author_sort |
Leutert, Thomas J. |
title |
Sensitivity of clumped isotope temperatures in fossil benthic and planktic foraminifera to diagenetic alteration |
title_short |
Sensitivity of clumped isotope temperatures in fossil benthic and planktic foraminifera to diagenetic alteration |
title_full |
Sensitivity of clumped isotope temperatures in fossil benthic and planktic foraminifera to diagenetic alteration |
title_fullStr |
Sensitivity of clumped isotope temperatures in fossil benthic and planktic foraminifera to diagenetic alteration |
title_full_unstemmed |
Sensitivity of clumped isotope temperatures in fossil benthic and planktic foraminifera to diagenetic alteration |
title_sort |
sensitivity of clumped isotope temperatures in fossil benthic and planktic foraminifera to diagenetic alteration |
publishDate |
2019 |
url |
https://oro.open.ac.uk/61245/ https://oro.open.ac.uk/61245/1/61245.pdf https://oro.open.ac.uk/61245/8/1-s2.0-S0016703719302625-main.pdf https://doi.org/10.1016/j.gca.2019.05.005 |
genre |
North Atlantic |
genre_facet |
North Atlantic |
op_relation |
https://oro.open.ac.uk/61245/1/61245.pdf https://oro.open.ac.uk/61245/8/1-s2.0-S0016703719302625-main.pdf Leutert, Thomas J.; Sexton, Philip <http://oro.open.ac.uk/view/person/pfs67.html>; Tripati, Aradhna; Piasecki, Alison; Ling Ho, Sze and Meckler, A. Nele (2019). Sensitivity of clumped isotope temperatures in fossil benthic and planktic foraminifera to diagenetic alteration. Geochimica et Cosmochimica Acta, 257 pp. 354–372. |
op_doi |
https://doi.org/10.1016/j.gca.2019.05.005 |
container_title |
Geochimica et Cosmochimica Acta |
container_volume |
257 |
container_start_page |
354 |
op_container_end_page |
372 |
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1768371212017205248 |