Influences of Atlantic Ocean thermohaline circulation and Antarctic ice-sheet expansion on Pliocene deep Pacific carbonate chemistry

• Published in: Earth and Planetary Science Letters
• Main Authors: Qin, Bingbin, Li, Tiegang, Xiong, Zhifang, Algeo, Thomas J., Jia, Qi, Nürnberg, Dirk, Shi, Jiangnan
• Format: Article in Journal/Newspaper
• Language: English
• Published: Elsevier 2022
• Subjects: Antarctic; Pacific; Antarc*; Ice Sheet; NADW; North Atlantic Deep Water; North Atlantic; Sea ice
• Online Access: https://oceanrep.geomar.de/id/eprint/57182/; https://oceanrep.geomar.de/id/eprint/57182/1/Qin%20et%20al.,%202022.pdf; https://doi.org/10.1016/j.epsl.2022.117868

Highlights • High-resolution deep-water record for Pliocene western tropical Pacific. • Changes in NADW production at ∼4.6 Ma and ∼2.7 Ma influenced Pacific • These changes controlled a seesaw fluctuation between deep Pacific and Atlantic oceans. • Antarctic ice-sheet/sea-ice expansions influenced deep Pacific • These ice-mass changes resulted in long-term decline during late Pliocene. Abstract Quantifying changes in seawater carbonate chemistry is crucial to deciphering of patterns and drivers of the oceanic carbon cycle and climate change. Here, we present a new deep-water carbonate ion saturation state record for the Pliocene western tropical Pacific, reconstructed from the size-normalized weight of the planktonic foraminifer Trilobatus sacculifer of IODP Site U1490. A steep decline in deep-water occurred at ∼4.6 Ma synchronous to the enhanced production of North Atlantic Deep Water (NADW) related to the closure of the Panamanian Gateway. Subsequently, at the onset of the Northern Hemisphere glaciation at ∼2.7 Ma the weakening of NADW formation resulted in a deep-water peak. The changes in NADW production rate likely controlled a seesaw-like fluctuation in deep-water between the Pacific and Atlantic oceans. During the late Pliocene (∼3.8–2.8 Ma), Antarctic ice-sheet/sea-ice expansions sequestered CO2 in the deep Pacific through ventilation of the deep watermass, leading to a long-term decrease in deep Pacific . We infer that fluctuating NADW production rates at ∼4.6 Ma and ∼2.7 Ma influenced inter-basinal fractionation of deep-ocean carbon between the Atlantic and Pacific, and that deep Pacific carbon storage linked to expansions of Antarctic ice sheet/sea ice contributed to the lowering of atmospheric pCO2 and global cooling during the late Pliocene.