Global Synthesis of Air-Sea CO2 Transfer Velocity Estimates From Ship-Based Eddy Covariance Measurements
The air-sea gas transfer velocity (K-660) is typically assessed as a function of the 10-m neutral wind speed (U-10n), but there remains substantial uncertainty in this relationship. Here K-660 of CO2 derived with the eddy covariance (EC) technique from eight datasets (11 research cruises) are reeval...
Published in: | Frontiers in Marine Science |
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Online Access: | https://oceanrep.geomar.de/id/eprint/56814/ https://oceanrep.geomar.de/id/eprint/56814/1/fmars_09_826421.pdf https://www.frontiersin.org/articles/10.3389/fmars.2022.826421/full https://doi.org/10.3389/fmars.2022.826421 |
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ftoceanrep:oai:oceanrep.geomar.de:56814 2024-02-11T10:01:45+01:00 Global Synthesis of Air-Sea CO2 Transfer Velocity Estimates From Ship-Based Eddy Covariance Measurements Yang, Mingxi Bell, Thomas G. Bidlot, Jean-Raymond Blomquist, Byron W. Butterworth, Brian J. Dong, Yuanxu Fairall, Christopher W. Landwehr, Sebastian Marandino, Christa A. Miller, Scott D. Saltzman, Eric S. Zavarsky, Alexander 2022-06-30 text https://oceanrep.geomar.de/id/eprint/56814/ https://oceanrep.geomar.de/id/eprint/56814/1/fmars_09_826421.pdf https://www.frontiersin.org/articles/10.3389/fmars.2022.826421/full https://doi.org/10.3389/fmars.2022.826421 en eng Frontiers https://oceanrep.geomar.de/id/eprint/56814/1/fmars_09_826421.pdf Yang, M., Bell, T. G., Bidlot, J. R., Blomquist, B. W., Butterworth, B. J., Dong, Y., Fairall, C. W., Landwehr, S., Marandino, C. A., Miller, S. D., Saltzman, E. S. and Zavarsky, A. (2022) Global Synthesis of Air-Sea CO2 Transfer Velocity Estimates From Ship-Based Eddy Covariance Measurements. Open Access Frontiers in Marine Science, 9 . Art.Nr. 826421. DOI 10.3389/fmars.2022.826421 <https://doi.org/10.3389/fmars.2022.826421>. doi:10.3389/fmars.2022.826421 cc_by_4.0 info:eu-repo/semantics/openAccess Article PeerReviewed 2022 ftoceanrep https://doi.org/10.3389/fmars.2022.826421 2024-01-15T00:25:56Z The air-sea gas transfer velocity (K-660) is typically assessed as a function of the 10-m neutral wind speed (U-10n), but there remains substantial uncertainty in this relationship. Here K-660 of CO2 derived with the eddy covariance (EC) technique from eight datasets (11 research cruises) are reevaluated with consistent consideration of solubility and Schmidt number and inclusion of the ocean cool skin effect. K-660 shows an approximately linear dependence with the friction velocity (u*) in moderate winds, with an overall relative standard deviation (relative standard error) of about 20% (7%). The largest relative uncertainty in K-660 occurs at low wind speeds, while the largest absolute uncertainty in K-660 occurs at high wind speeds. There is an apparent regional variation in the steepness of the K-660-u* relationships: North Atlantic >= Southern Ocean > other regions (Arctic, Tropics). Accounting for sea state helps to collapse some of this regional variability in K-660 using the wave Reynolds number in very large seas and the mean squared slope of the waves in small to moderate seas. The grand average of EC-derived K-660 ( - 1.47 + 76.67 u * + 20.48 u *(2) o r 0.36 + 1.203 U-10n + 0.167 U (2)(10n) ) is similar at moderate to high winds to widely used dual tracer-based K-660 parametrization, but consistently exceeds the dual tracer estimate in low winds, possibly in part due to the chemical enhancement in air-sea CO2 exchange. Combining the grand average of EC-derived K-660 with the global distribution of wind speed yields a global average transfer velocity that is comparable with the global radiocarbon (C-14) disequilibrium, but is similar to 20% higher than what is implied by dual tracer parametrizations. This analysis suggests that CO2 fluxes computed using a U-10n (2) dependence with zero intercept (e.g., dual tracer) are likely underestimated at relatively low wind speeds. Article in Journal/Newspaper Arctic North Atlantic Southern Ocean OceanRep (GEOMAR Helmholtz Centre für Ocean Research Kiel) Arctic Southern Ocean Frontiers in Marine Science 9 |
institution |
Open Polar |
collection |
OceanRep (GEOMAR Helmholtz Centre für Ocean Research Kiel) |
op_collection_id |
ftoceanrep |
language |
English |
description |
The air-sea gas transfer velocity (K-660) is typically assessed as a function of the 10-m neutral wind speed (U-10n), but there remains substantial uncertainty in this relationship. Here K-660 of CO2 derived with the eddy covariance (EC) technique from eight datasets (11 research cruises) are reevaluated with consistent consideration of solubility and Schmidt number and inclusion of the ocean cool skin effect. K-660 shows an approximately linear dependence with the friction velocity (u*) in moderate winds, with an overall relative standard deviation (relative standard error) of about 20% (7%). The largest relative uncertainty in K-660 occurs at low wind speeds, while the largest absolute uncertainty in K-660 occurs at high wind speeds. There is an apparent regional variation in the steepness of the K-660-u* relationships: North Atlantic >= Southern Ocean > other regions (Arctic, Tropics). Accounting for sea state helps to collapse some of this regional variability in K-660 using the wave Reynolds number in very large seas and the mean squared slope of the waves in small to moderate seas. The grand average of EC-derived K-660 ( - 1.47 + 76.67 u * + 20.48 u *(2) o r 0.36 + 1.203 U-10n + 0.167 U (2)(10n) ) is similar at moderate to high winds to widely used dual tracer-based K-660 parametrization, but consistently exceeds the dual tracer estimate in low winds, possibly in part due to the chemical enhancement in air-sea CO2 exchange. Combining the grand average of EC-derived K-660 with the global distribution of wind speed yields a global average transfer velocity that is comparable with the global radiocarbon (C-14) disequilibrium, but is similar to 20% higher than what is implied by dual tracer parametrizations. This analysis suggests that CO2 fluxes computed using a U-10n (2) dependence with zero intercept (e.g., dual tracer) are likely underestimated at relatively low wind speeds. |
format |
Article in Journal/Newspaper |
author |
Yang, Mingxi Bell, Thomas G. Bidlot, Jean-Raymond Blomquist, Byron W. Butterworth, Brian J. Dong, Yuanxu Fairall, Christopher W. Landwehr, Sebastian Marandino, Christa A. Miller, Scott D. Saltzman, Eric S. Zavarsky, Alexander |
spellingShingle |
Yang, Mingxi Bell, Thomas G. Bidlot, Jean-Raymond Blomquist, Byron W. Butterworth, Brian J. Dong, Yuanxu Fairall, Christopher W. Landwehr, Sebastian Marandino, Christa A. Miller, Scott D. Saltzman, Eric S. Zavarsky, Alexander Global Synthesis of Air-Sea CO2 Transfer Velocity Estimates From Ship-Based Eddy Covariance Measurements |
author_facet |
Yang, Mingxi Bell, Thomas G. Bidlot, Jean-Raymond Blomquist, Byron W. Butterworth, Brian J. Dong, Yuanxu Fairall, Christopher W. Landwehr, Sebastian Marandino, Christa A. Miller, Scott D. Saltzman, Eric S. Zavarsky, Alexander |
author_sort |
Yang, Mingxi |
title |
Global Synthesis of Air-Sea CO2 Transfer Velocity Estimates From Ship-Based Eddy Covariance Measurements |
title_short |
Global Synthesis of Air-Sea CO2 Transfer Velocity Estimates From Ship-Based Eddy Covariance Measurements |
title_full |
Global Synthesis of Air-Sea CO2 Transfer Velocity Estimates From Ship-Based Eddy Covariance Measurements |
title_fullStr |
Global Synthesis of Air-Sea CO2 Transfer Velocity Estimates From Ship-Based Eddy Covariance Measurements |
title_full_unstemmed |
Global Synthesis of Air-Sea CO2 Transfer Velocity Estimates From Ship-Based Eddy Covariance Measurements |
title_sort |
global synthesis of air-sea co2 transfer velocity estimates from ship-based eddy covariance measurements |
publisher |
Frontiers |
publishDate |
2022 |
url |
https://oceanrep.geomar.de/id/eprint/56814/ https://oceanrep.geomar.de/id/eprint/56814/1/fmars_09_826421.pdf https://www.frontiersin.org/articles/10.3389/fmars.2022.826421/full https://doi.org/10.3389/fmars.2022.826421 |
geographic |
Arctic Southern Ocean |
geographic_facet |
Arctic Southern Ocean |
genre |
Arctic North Atlantic Southern Ocean |
genre_facet |
Arctic North Atlantic Southern Ocean |
op_relation |
https://oceanrep.geomar.de/id/eprint/56814/1/fmars_09_826421.pdf Yang, M., Bell, T. G., Bidlot, J. R., Blomquist, B. W., Butterworth, B. J., Dong, Y., Fairall, C. W., Landwehr, S., Marandino, C. A., Miller, S. D., Saltzman, E. S. and Zavarsky, A. (2022) Global Synthesis of Air-Sea CO2 Transfer Velocity Estimates From Ship-Based Eddy Covariance Measurements. Open Access Frontiers in Marine Science, 9 . Art.Nr. 826421. DOI 10.3389/fmars.2022.826421 <https://doi.org/10.3389/fmars.2022.826421>. doi:10.3389/fmars.2022.826421 |
op_rights |
cc_by_4.0 info:eu-repo/semantics/openAccess |
op_doi |
https://doi.org/10.3389/fmars.2022.826421 |
container_title |
Frontiers in Marine Science |
container_volume |
9 |
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1790597548540428288 |