Relationships between atmospheric organic compounds and air-mass exposure to marine biology
Environmental context. The exchange of gases between the atmosphere and oceans impacts Earth’s climate. Over the remote oceans, marine emissions of organic species may have significant impacts on cloud properties and the atmosphere’s oxidative capacity. Quantifying these emissions and their dependen...
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Online Access: | https://oceanrep.geomar.de/id/eprint/47118/ https://doi.org/10.1071/EN09144 |
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ftoceanrep:oai:oceanrep.geomar.de:47118 2023-05-15T18:20:58+02:00 Relationships between atmospheric organic compounds and air-mass exposure to marine biology Arnold, S. R. Spracklen, D. V. Gebhardt, S. Custer, T. Williams, J. Peeken, Ilka Alvain, S. 2010 https://oceanrep.geomar.de/id/eprint/47118/ https://doi.org/10.1071/EN09144 unknown CSIRO Arnold, S. R., Spracklen, D. V., Gebhardt, S., Custer, T., Williams, J., Peeken, I. and Alvain, S. (2010) Relationships between atmospheric organic compounds and air-mass exposure to marine biology. Environmental Chemistry, 7 (3). p. 232. DOI 10.1071/EN09144 <https://doi.org/10.1071/EN09144>. doi:10.1071/EN09144 info:eu-repo/semantics/closedAccess Article PeerReviewed 2010 ftoceanrep https://doi.org/10.1071/EN09144 2023-04-07T15:46:23Z Environmental context. The exchange of gases between the atmosphere and oceans impacts Earth’s climate. Over the remote oceans, marine emissions of organic species may have significant impacts on cloud properties and the atmosphere’s oxidative capacity. Quantifying these emissions and their dependence on ocean biology over the global oceans is a major challenge. Here we present a new method which relates atmospheric abundance of several organic chemicals over the South Atlantic Ocean to the exposure of air to ocean biology over several days before its sampling. Abstract. We have used a Lagrangian transport model and satellite observations of oceanic chlorophyll-a concentrations and phytoplankton community structure, to investigate relationships between air mass biological exposure and atmospheric concentrations of organic compounds over the remote South Atlantic Ocean in January and February 2007. Accounting for spatial and temporal exposure of air masses to chlorophyll from biologically active ocean regions upwind of the observation location produces significant correlations with atmospheric organohalogens, despite insignificant or smaller correlations using commonly applied in-situ chlorophyll. Strongest correlations (r = 0.42–0.53) are obtained with chlorophyll exposure over a 2-day transport history for CHBr3, CH2Br2, CH3I, and dimethylsulfide, and are strengthened further with exposure to specific phytoplankton types. Incorporating daylight and wind-speed terms into the chlorophyll exposure results in reduced correlations. The method demonstrates that conclusions drawn regarding oceanic trace-gas sources from in-situ chlorophyll or satellite chlorophyll averages over arbitrary areas may prove erroneous without accounting for the transport history of air sampled. Article in Journal/Newspaper South Atlantic Ocean OceanRep (GEOMAR Helmholtz Centre für Ocean Research Kiel) Environmental Chemistry 7 3 232 |
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OceanRep (GEOMAR Helmholtz Centre für Ocean Research Kiel) |
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Environmental context. The exchange of gases between the atmosphere and oceans impacts Earth’s climate. Over the remote oceans, marine emissions of organic species may have significant impacts on cloud properties and the atmosphere’s oxidative capacity. Quantifying these emissions and their dependence on ocean biology over the global oceans is a major challenge. Here we present a new method which relates atmospheric abundance of several organic chemicals over the South Atlantic Ocean to the exposure of air to ocean biology over several days before its sampling. Abstract. We have used a Lagrangian transport model and satellite observations of oceanic chlorophyll-a concentrations and phytoplankton community structure, to investigate relationships between air mass biological exposure and atmospheric concentrations of organic compounds over the remote South Atlantic Ocean in January and February 2007. Accounting for spatial and temporal exposure of air masses to chlorophyll from biologically active ocean regions upwind of the observation location produces significant correlations with atmospheric organohalogens, despite insignificant or smaller correlations using commonly applied in-situ chlorophyll. Strongest correlations (r = 0.42–0.53) are obtained with chlorophyll exposure over a 2-day transport history for CHBr3, CH2Br2, CH3I, and dimethylsulfide, and are strengthened further with exposure to specific phytoplankton types. Incorporating daylight and wind-speed terms into the chlorophyll exposure results in reduced correlations. The method demonstrates that conclusions drawn regarding oceanic trace-gas sources from in-situ chlorophyll or satellite chlorophyll averages over arbitrary areas may prove erroneous without accounting for the transport history of air sampled. |
format |
Article in Journal/Newspaper |
author |
Arnold, S. R. Spracklen, D. V. Gebhardt, S. Custer, T. Williams, J. Peeken, Ilka Alvain, S. |
spellingShingle |
Arnold, S. R. Spracklen, D. V. Gebhardt, S. Custer, T. Williams, J. Peeken, Ilka Alvain, S. Relationships between atmospheric organic compounds and air-mass exposure to marine biology |
author_facet |
Arnold, S. R. Spracklen, D. V. Gebhardt, S. Custer, T. Williams, J. Peeken, Ilka Alvain, S. |
author_sort |
Arnold, S. R. |
title |
Relationships between atmospheric organic compounds and air-mass exposure to marine biology |
title_short |
Relationships between atmospheric organic compounds and air-mass exposure to marine biology |
title_full |
Relationships between atmospheric organic compounds and air-mass exposure to marine biology |
title_fullStr |
Relationships between atmospheric organic compounds and air-mass exposure to marine biology |
title_full_unstemmed |
Relationships between atmospheric organic compounds and air-mass exposure to marine biology |
title_sort |
relationships between atmospheric organic compounds and air-mass exposure to marine biology |
publisher |
CSIRO |
publishDate |
2010 |
url |
https://oceanrep.geomar.de/id/eprint/47118/ https://doi.org/10.1071/EN09144 |
genre |
South Atlantic Ocean |
genre_facet |
South Atlantic Ocean |
op_relation |
Arnold, S. R., Spracklen, D. V., Gebhardt, S., Custer, T., Williams, J., Peeken, I. and Alvain, S. (2010) Relationships between atmospheric organic compounds and air-mass exposure to marine biology. Environmental Chemistry, 7 (3). p. 232. DOI 10.1071/EN09144 <https://doi.org/10.1071/EN09144>. doi:10.1071/EN09144 |
op_rights |
info:eu-repo/semantics/closedAccess |
op_doi |
https://doi.org/10.1071/EN09144 |
container_title |
Environmental Chemistry |
container_volume |
7 |
container_issue |
3 |
container_start_page |
232 |
_version_ |
1766199911477411840 |