The biogeochemical cycle of dissolved aluminium in the Atlantic Ocean

• Main Author: Menzel Barraqueta, Jan-Lukas
• Format: Thesis
• Language: English
• Published: 2018
• Subjects: Labrador Sea; North Atlantic
• Online Access: https://oceanrep.geomar.de/id/eprint/44967/; https://oceanrep.geomar.de/id/eprint/44967/1/Menzel_Diss_Abstract.pdf; https://oceanrep.geomar.de/id/eprint/44967/7/DissertationJLMB.pdf; https://macau.uni-kiel.de/receive/diss_mods_00023074

Dissolved aluminium (dAl) is the most abundant metal in the Earth’s crust and has not known biological function. Dissolved aluminium is supplied to the ocean through several sources which include atmospheric deposition, rivers, sedimentary, and hydrothermal sources. The major removal of dAl from seawater is via adsorption onto particles with subsequent sinking of the particles which are finally buried at the seafloor. Dissolved aluminium concentrations in surface waters can be converted into atmospheric deposition fluxes. Atmospheric deposition fluxes to the surface of the ocean are challenging to determine and present large uncertainties due to the inter-seasonal variability in the mechanisms and sources supplying aerosols to the ocean. Therefore it is important to study the distribution and understand the mechanisms that supply and remove dAl to and from the seawater. The work presented in this thesis has focused on the biogeochemical cycling of dAl in surface waters and water column of the Atlantic Ocean. Chapter 3 presents the largest highresolution vertical and lateral dataset of dAl that exists in the North Atlantic Ocean (>40°N) and in the Labrador Sea. The latter regions present large phytoplankton blooms and during this study it was found that diatoms directly influence the transfer of the dAl phase into the particulate aluminium phase. In the North Atlantic Ocean (>40°N) and in the Labrador Sea dAl displayed, in general, a recycled type distribution which differs from other regions in the Atlantic Ocean and seems to be coupled with surface uptake and the dissolution of diatoms frustules at depth. In chapter 4 the potential use of dAl as an atmospheric deposition tracer was studied over four different regions along the Atlantic Ocean. The studied regions showed marked regional differences in the concentration of dAl in surface waters as a consequence of varying degrees of aluminium sources and sinks. The datasets presented in chapter 4 have now filled in gaps for regions were no, or limited, dAl ...