The d13C anomaly in the northeastern Atlantic
The δ13C of dissolved inorganic carbon was measured on samples collected at 49°N in the northeast Atlantic in January 1994. Deeper than 2000 m, δ13C exhibits the same negative correlation versus dissolved phosphate that is observed elsewhere in the deep Atlantic. Upward from 2000 m to about 600 m, δ...
Published in: | Global Biogeochemical Cycles |
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AGU (American Geophysical Union)
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ftoceanrep:oai:oceanrep.geomar.de:3616 2024-09-30T14:40:03+00:00 The d13C anomaly in the northeastern Atlantic Keir, Robin Rehder, Gregor Suess, Erwin Erlenkeuser, Helmut 1998 text https://oceanrep.geomar.de/id/eprint/3616/ https://oceanrep.geomar.de/id/eprint/3616/1/Keir_et_al-1998-Global_Biogeochemical_Cycles.pdf https://doi.org/10.1029/98GB02054 en eng AGU (American Geophysical Union) https://oceanrep.geomar.de/id/eprint/3616/1/Keir_et_al-1998-Global_Biogeochemical_Cycles.pdf Keir, R., Rehder, G., Suess, E. and Erlenkeuser, H. (1998) The d13C anomaly in the northeastern Atlantic. Open Access Global Biogeochemical Cycles, 12 (3). pp. 467-477. DOI 10.1029/98GB02054 <https://doi.org/10.1029/98GB02054>. doi:10.1029/98GB02054 info:eu-repo/semantics/openAccess Article PeerReviewed 1998 ftoceanrep https://doi.org/10.1029/98GB02054 2024-09-04T05:04:40Z The δ13C of dissolved inorganic carbon was measured on samples collected at 49°N in the northeast Atlantic in January 1994. Deeper than 2000 m, δ13C exhibits the same negative correlation versus dissolved phosphate that is observed elsewhere in the deep Atlantic. Upward from 2000 m to about 600 m, δ13C shifts to values more negative than expected from the correlation with nutrients at depth, which is likely due to penetration of anthropogenic CO2. From these data, the profile of the anthropogenic δ13C decrease is calculated by using either dissolved phosphate or apparent oxygen utilization as a proxy for the preanthropogenic δ13C distribution. The shape of the anthropogenic anomaly profile derived from phosphate is similar to that of the increase in dissolved inorganic carbon derived by others in the same area. The reconstruction from oxygen utilization results in a lower estimate of the anthropogenic δ13C decrease in the upper water column, and the vertical anomaly profile is less similar to that of the dissolved inorganic carbon increase. A 13C budget for the atmosphere, ocean, and terrestrial biosphere indicates that within the range of probable ocean CO2 uptake the ratio of δ13C to inorganic carbon change should be mostly influenced by the 13C inventory change of the biosphere. However, the uncertainty in the ratio we derive prevents a strong contraint on the size of the exchangeable biosphere. Article in Journal/Newspaper Northeast Atlantic OceanRep (GEOMAR Helmholtz Centre für Ocean Research Kiel) Global Biogeochemical Cycles 12 3 467 477 |
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OceanRep (GEOMAR Helmholtz Centre für Ocean Research Kiel) |
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ftoceanrep |
language |
English |
description |
The δ13C of dissolved inorganic carbon was measured on samples collected at 49°N in the northeast Atlantic in January 1994. Deeper than 2000 m, δ13C exhibits the same negative correlation versus dissolved phosphate that is observed elsewhere in the deep Atlantic. Upward from 2000 m to about 600 m, δ13C shifts to values more negative than expected from the correlation with nutrients at depth, which is likely due to penetration of anthropogenic CO2. From these data, the profile of the anthropogenic δ13C decrease is calculated by using either dissolved phosphate or apparent oxygen utilization as a proxy for the preanthropogenic δ13C distribution. The shape of the anthropogenic anomaly profile derived from phosphate is similar to that of the increase in dissolved inorganic carbon derived by others in the same area. The reconstruction from oxygen utilization results in a lower estimate of the anthropogenic δ13C decrease in the upper water column, and the vertical anomaly profile is less similar to that of the dissolved inorganic carbon increase. A 13C budget for the atmosphere, ocean, and terrestrial biosphere indicates that within the range of probable ocean CO2 uptake the ratio of δ13C to inorganic carbon change should be mostly influenced by the 13C inventory change of the biosphere. However, the uncertainty in the ratio we derive prevents a strong contraint on the size of the exchangeable biosphere. |
format |
Article in Journal/Newspaper |
author |
Keir, Robin Rehder, Gregor Suess, Erwin Erlenkeuser, Helmut |
spellingShingle |
Keir, Robin Rehder, Gregor Suess, Erwin Erlenkeuser, Helmut The d13C anomaly in the northeastern Atlantic |
author_facet |
Keir, Robin Rehder, Gregor Suess, Erwin Erlenkeuser, Helmut |
author_sort |
Keir, Robin |
title |
The d13C anomaly in the northeastern Atlantic |
title_short |
The d13C anomaly in the northeastern Atlantic |
title_full |
The d13C anomaly in the northeastern Atlantic |
title_fullStr |
The d13C anomaly in the northeastern Atlantic |
title_full_unstemmed |
The d13C anomaly in the northeastern Atlantic |
title_sort |
d13c anomaly in the northeastern atlantic |
publisher |
AGU (American Geophysical Union) |
publishDate |
1998 |
url |
https://oceanrep.geomar.de/id/eprint/3616/ https://oceanrep.geomar.de/id/eprint/3616/1/Keir_et_al-1998-Global_Biogeochemical_Cycles.pdf https://doi.org/10.1029/98GB02054 |
genre |
Northeast Atlantic |
genre_facet |
Northeast Atlantic |
op_relation |
https://oceanrep.geomar.de/id/eprint/3616/1/Keir_et_al-1998-Global_Biogeochemical_Cycles.pdf Keir, R., Rehder, G., Suess, E. and Erlenkeuser, H. (1998) The d13C anomaly in the northeastern Atlantic. Open Access Global Biogeochemical Cycles, 12 (3). pp. 467-477. DOI 10.1029/98GB02054 <https://doi.org/10.1029/98GB02054>. doi:10.1029/98GB02054 |
op_rights |
info:eu-repo/semantics/openAccess |
op_doi |
https://doi.org/10.1029/98GB02054 |
container_title |
Global Biogeochemical Cycles |
container_volume |
12 |
container_issue |
3 |
container_start_page |
467 |
op_container_end_page |
477 |
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1811642590206885888 |