Separating geometry- from stress-induced remanent magnetization in magnetite with ilmenite lamellae from the Stardalur basalts, Iceland

Realistic geometries of magnetite grains from the Stardalur volcano, Iceland, were obtained by Focused Ion Beam Scanning Electron Microscopy nanotomography. These magnetite grains are subdivided by oxidation‐exsolution lamellae of ilmenite. Magnetic properties of these grains were modeled without in...

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Published in:Geochemistry, Geophysics, Geosystems
Main Authors: ter Maat, Geertruida Wilhelmina, Fabian, Karl, Church, Nathan Stewart, McEnroe, Suzanne
Format: Article in Journal/Newspaper
Language:English
Published: AGU, American Geophysical Union and Wiley 2020
Subjects:
Online Access:https://hdl.handle.net/11250/2737827
https://doi.org/10.1029/2019GC008761
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author ter Maat, Geertruida Wilhelmina
Fabian, Karl
Church, Nathan Stewart
McEnroe, Suzanne
author_facet ter Maat, Geertruida Wilhelmina
Fabian, Karl
Church, Nathan Stewart
McEnroe, Suzanne
author_sort ter Maat, Geertruida Wilhelmina
collection NTNU Open Archive (Norwegian University of Science and Technology)
container_issue 2
container_title Geochemistry, Geophysics, Geosystems
container_volume 21
description Realistic geometries of magnetite grains from the Stardalur volcano, Iceland, were obtained by Focused Ion Beam Scanning Electron Microscopy nanotomography. These magnetite grains are subdivided by oxidation‐exsolution lamellae of ilmenite. Magnetic properties of these grains were modeled without internal stress using the three‐dimensional micromagnetic code MERRILL. The influence of grain shape and size was isolated by modeling hysteresis loops of the same grains with and without exsolution microstructures. The resulting coercivities Hc are up to 1.5 times higher, and the Mrs/Ms ratios are twice as high for the grains with exsolution than for those without. Both modeled values are a factor of 10 smaller than the measured bulk data from the same sample. This difference between stress‐free models and measured hysteresis loops suggests that the internal stress due to the formation of the oxidation‐exsolution lamellae is the dominant mechanism of coercivity and remanence enhancement. By comparing the approach‐to‐saturation behavior of modeled and measured hysteresis loops, the internal stress is quantified to about 100 MPa. The formation of lamellae has two effects on magnetic properties. (1) The apparent grain size is geometrically reduced. This effect increases Mrs and Hc by up to a factor of 2. (2) The formation of lamellae produces internal stress fields, which provide additional anisotropy energy that deflect the magnetic spins and apparently increase Mrs and Hc by up to a factor of 10. Accordingly, stress dominates the remanent magnetic properties in the Stardalur basalts and may be the decisive effect explaining its unusual remanent‐dominated ground magnetic anomaly of up to 27,000 nT. publishedVersion ©2020. The Authors. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
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geographic Stardalur
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https://hdl.handle.net/11250/2737827
https://doi.org/10.1029/2019GC008761
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spelling ftntnutrondheimi:oai:ntnuopen.ntnu.no:11250/2737827 2025-05-18T14:03:32+00:00 Separating geometry- from stress-induced remanent magnetization in magnetite with ilmenite lamellae from the Stardalur basalts, Iceland ter Maat, Geertruida Wilhelmina Fabian, Karl Church, Nathan Stewart McEnroe, Suzanne 2020 application/pdf https://hdl.handle.net/11250/2737827 https://doi.org/10.1029/2019GC008761 eng eng AGU, American Geophysical Union and Wiley Norges forskningsråd: 295864 Geochemistry Geophysics Geosystems. 2020, 21 (2), . https://hdl.handle.net/11250/2737827 https://doi.org/10.1029/2019GC008761 cristin:1796587 Navngivelse 4.0 Internasjonal http://creativecommons.org/licenses/by/4.0/deed.no 15 21 Geochemistry Geophysics Geosystems 2 Peer reviewed Journal article 2020 ftntnutrondheimi https://doi.org/10.1029/2019GC008761 2025-04-23T04:50:47Z Realistic geometries of magnetite grains from the Stardalur volcano, Iceland, were obtained by Focused Ion Beam Scanning Electron Microscopy nanotomography. These magnetite grains are subdivided by oxidation‐exsolution lamellae of ilmenite. Magnetic properties of these grains were modeled without internal stress using the three‐dimensional micromagnetic code MERRILL. The influence of grain shape and size was isolated by modeling hysteresis loops of the same grains with and without exsolution microstructures. The resulting coercivities Hc are up to 1.5 times higher, and the Mrs/Ms ratios are twice as high for the grains with exsolution than for those without. Both modeled values are a factor of 10 smaller than the measured bulk data from the same sample. This difference between stress‐free models and measured hysteresis loops suggests that the internal stress due to the formation of the oxidation‐exsolution lamellae is the dominant mechanism of coercivity and remanence enhancement. By comparing the approach‐to‐saturation behavior of modeled and measured hysteresis loops, the internal stress is quantified to about 100 MPa. The formation of lamellae has two effects on magnetic properties. (1) The apparent grain size is geometrically reduced. This effect increases Mrs and Hc by up to a factor of 2. (2) The formation of lamellae produces internal stress fields, which provide additional anisotropy energy that deflect the magnetic spins and apparently increase Mrs and Hc by up to a factor of 10. Accordingly, stress dominates the remanent magnetic properties in the Stardalur basalts and may be the decisive effect explaining its unusual remanent‐dominated ground magnetic anomaly of up to 27,000 nT. publishedVersion ©2020. The Authors. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. Article in Journal/Newspaper Iceland NTNU Open Archive (Norwegian University of Science and Technology) Stardalur ENVELOPE(-21.482,-21.482,64.210,64.210) Geochemistry, Geophysics, Geosystems 21 2
spellingShingle ter Maat, Geertruida Wilhelmina
Fabian, Karl
Church, Nathan Stewart
McEnroe, Suzanne
Separating geometry- from stress-induced remanent magnetization in magnetite with ilmenite lamellae from the Stardalur basalts, Iceland
title Separating geometry- from stress-induced remanent magnetization in magnetite with ilmenite lamellae from the Stardalur basalts, Iceland
title_full Separating geometry- from stress-induced remanent magnetization in magnetite with ilmenite lamellae from the Stardalur basalts, Iceland
title_fullStr Separating geometry- from stress-induced remanent magnetization in magnetite with ilmenite lamellae from the Stardalur basalts, Iceland
title_full_unstemmed Separating geometry- from stress-induced remanent magnetization in magnetite with ilmenite lamellae from the Stardalur basalts, Iceland
title_short Separating geometry- from stress-induced remanent magnetization in magnetite with ilmenite lamellae from the Stardalur basalts, Iceland
title_sort separating geometry- from stress-induced remanent magnetization in magnetite with ilmenite lamellae from the stardalur basalts, iceland
url https://hdl.handle.net/11250/2737827
https://doi.org/10.1029/2019GC008761