Investigation of Copper Recovery from a New Copper Deposit (Nussir) in Northern-Norway: Thionocarbamates and Xanthate-Thionocarbamate Blend as Collectors

Norway has newly seen an upsurge of interest in exploiting its mineral deposits influenced by fresh Government focus and survey support for previously under-prospected areas. One of the major areas of interest is a huge copper deposit, operated by Nussir ASA, located in the Repparfjord tectonic wind...

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Published in:Minerals
Main Authors: Dhar, Priyanka, Thornhill, Maria, Kota, Hanumantha Rao
Format: Article in Journal/Newspaper
Language:English
Published: MDPI 2019
Subjects:
Online Access:http://hdl.handle.net/11250/2618332
https://doi.org/10.3390/min9020118
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spelling ftntnutrondheimi:oai:ntnuopen.ntnu.no:11250/2618332 2023-05-15T16:13:45+02:00 Investigation of Copper Recovery from a New Copper Deposit (Nussir) in Northern-Norway: Thionocarbamates and Xanthate-Thionocarbamate Blend as Collectors Dhar, Priyanka Thornhill, Maria Kota, Hanumantha Rao 2019 http://hdl.handle.net/11250/2618332 https://doi.org/10.3390/min9020118 eng eng MDPI Minerals. 2019, 9 (2), . urn:issn:2075-163X http://hdl.handle.net/11250/2618332 https://doi.org/10.3390/min9020118 cristin:1677969 Navngivelse 4.0 Internasjonal http://creativecommons.org/licenses/by/4.0/deed.no CC-BY 20 9 Minerals 2 Journal article Peer reviewed 2019 ftntnutrondheimi https://doi.org/10.3390/min9020118 2019-10-06T17:43:41Z Norway has newly seen an upsurge of interest in exploiting its mineral deposits influenced by fresh Government focus and survey support for previously under-prospected areas. One of the major areas of interest is a huge copper deposit, operated by Nussir ASA, located in the Repparfjord tectonic window in the Caledonides of west Finnmark. The latest mineral resource estimation is from July 2014, which states that Nussir consists of 5.8 million tonnes of indicated resources and 60.2 million tonnes of inferred resources, giving 66 million tonnes of copper ore. This paper represents the first study on processing characteristics of this ore to date. Our parallel studies using xanthates and dithiophosphates as collectors for Nussir ore flotation examined the grade and recovery of copper, silver, gold, and platinum group (PGM) minerals. Therefore, in this subsequent study, a chelating agent n-Butoxycarbonyl-O-n-butyl thionocarbamate (BBT) is used as a collector and it was found that the recovery and grades of the economically interesting minerals are improved at as low as 2 × 10−5 M collector concentration. Zeta potential, Hallimond flotation and adsorption studies were initially performed in order to assess the selective interaction of BBT and its blend with SIBX (Sodium Isobutyl xanthate) on the three copper minerals of the ore. The bench scale flotation experiments were performed using mixtures of xanthate and thionocarbamate collectors of the Nussir ore and both the resulting copper recovery and grade employing these collector mixtures is observed to be 2–8% superior to the use of a single collector system. Additionally, the current study revealed that the metallurgical results are strongly influenced by the ratio of the collectors in the mixture and particularly the sequence of the collector addition. publishedVersion © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Article in Journal/Newspaper Finnmark Northern Norway Finnmark NTNU Open Archive (Norwegian University of Science and Technology) Norway The Bench ENVELOPE(-53.181,-53.181,49.767,49.767) Repparfjord ENVELOPE(24.550,24.550,70.417,70.417) Nussir ENVELOPE(23.535,23.535,70.096,70.096) Minerals 9 2 118
institution Open Polar
collection NTNU Open Archive (Norwegian University of Science and Technology)
op_collection_id ftntnutrondheimi
language English
description Norway has newly seen an upsurge of interest in exploiting its mineral deposits influenced by fresh Government focus and survey support for previously under-prospected areas. One of the major areas of interest is a huge copper deposit, operated by Nussir ASA, located in the Repparfjord tectonic window in the Caledonides of west Finnmark. The latest mineral resource estimation is from July 2014, which states that Nussir consists of 5.8 million tonnes of indicated resources and 60.2 million tonnes of inferred resources, giving 66 million tonnes of copper ore. This paper represents the first study on processing characteristics of this ore to date. Our parallel studies using xanthates and dithiophosphates as collectors for Nussir ore flotation examined the grade and recovery of copper, silver, gold, and platinum group (PGM) minerals. Therefore, in this subsequent study, a chelating agent n-Butoxycarbonyl-O-n-butyl thionocarbamate (BBT) is used as a collector and it was found that the recovery and grades of the economically interesting minerals are improved at as low as 2 × 10−5 M collector concentration. Zeta potential, Hallimond flotation and adsorption studies were initially performed in order to assess the selective interaction of BBT and its blend with SIBX (Sodium Isobutyl xanthate) on the three copper minerals of the ore. The bench scale flotation experiments were performed using mixtures of xanthate and thionocarbamate collectors of the Nussir ore and both the resulting copper recovery and grade employing these collector mixtures is observed to be 2–8% superior to the use of a single collector system. Additionally, the current study revealed that the metallurgical results are strongly influenced by the ratio of the collectors in the mixture and particularly the sequence of the collector addition. publishedVersion © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
format Article in Journal/Newspaper
author Dhar, Priyanka
Thornhill, Maria
Kota, Hanumantha Rao
spellingShingle Dhar, Priyanka
Thornhill, Maria
Kota, Hanumantha Rao
Investigation of Copper Recovery from a New Copper Deposit (Nussir) in Northern-Norway: Thionocarbamates and Xanthate-Thionocarbamate Blend as Collectors
author_facet Dhar, Priyanka
Thornhill, Maria
Kota, Hanumantha Rao
author_sort Dhar, Priyanka
title Investigation of Copper Recovery from a New Copper Deposit (Nussir) in Northern-Norway: Thionocarbamates and Xanthate-Thionocarbamate Blend as Collectors
title_short Investigation of Copper Recovery from a New Copper Deposit (Nussir) in Northern-Norway: Thionocarbamates and Xanthate-Thionocarbamate Blend as Collectors
title_full Investigation of Copper Recovery from a New Copper Deposit (Nussir) in Northern-Norway: Thionocarbamates and Xanthate-Thionocarbamate Blend as Collectors
title_fullStr Investigation of Copper Recovery from a New Copper Deposit (Nussir) in Northern-Norway: Thionocarbamates and Xanthate-Thionocarbamate Blend as Collectors
title_full_unstemmed Investigation of Copper Recovery from a New Copper Deposit (Nussir) in Northern-Norway: Thionocarbamates and Xanthate-Thionocarbamate Blend as Collectors
title_sort investigation of copper recovery from a new copper deposit (nussir) in northern-norway: thionocarbamates and xanthate-thionocarbamate blend as collectors
publisher MDPI
publishDate 2019
url http://hdl.handle.net/11250/2618332
https://doi.org/10.3390/min9020118
long_lat ENVELOPE(-53.181,-53.181,49.767,49.767)
ENVELOPE(24.550,24.550,70.417,70.417)
ENVELOPE(23.535,23.535,70.096,70.096)
geographic Norway
The Bench
Repparfjord
Nussir
geographic_facet Norway
The Bench
Repparfjord
Nussir
genre Finnmark
Northern Norway
Finnmark
genre_facet Finnmark
Northern Norway
Finnmark
op_source 20
9
Minerals
2
op_relation Minerals. 2019, 9 (2), .
urn:issn:2075-163X
http://hdl.handle.net/11250/2618332
https://doi.org/10.3390/min9020118
cristin:1677969
op_rights Navngivelse 4.0 Internasjonal
http://creativecommons.org/licenses/by/4.0/deed.no
op_rightsnorm CC-BY
op_doi https://doi.org/10.3390/min9020118
container_title Minerals
container_volume 9
container_issue 2
container_start_page 118
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