Antifreezes act as catalysts for methane hydrate formation from ice

• Published in: Angewandte Chemie International Edition
• Main Authors: McLaurin, Graham, Shin, Kyuchul, Alavi, Saman, Ripmeester, John A.
• Format: Article in Journal/Newspaper
• Language: English
• Published: Wiley 2014
• Subjects: Methanol; Molecular dynamics; Gas uptake; Methane hydrates; Powder X ray diffraction; Hydrates; Methane hydrate
• Online Access: https://doi.org/10.1002/anie.201403638; https://nrc-publications.canada.ca/eng/view/object/?id=946fcd26-4c59-4998-b55d-0413c180e5d5; https://nrc-publications.canada.ca/fra/voir/objet/?id=946fcd26-4c59-4998-b55d-0413c180e5d5

Contrary to the thermodynamic inhibiting effect of methanol on methane hydrate formation from aqueous phases, hydrate forms quickly at high yield by exposing frozen water-methanol mixtures with methanol concentrations ranging from 0.6-10 wt% to methane gas at pressures from 125 bars at 253 K. Formation rates are some two orders of magnitude greater than those obtained for samples without methanol and conversion of ice is essentially complete. Ammonia has a similar catalytic effect when used in concentrations of 0.3-2.7 wt%. The structure I methane hydrate formed in this manner was characterized by powder X-ray diffraction and Raman spectroscopy. Steps in the possible mechanism of action of methanol were studied with molecular dynamics simulations of the Ih (0001) basal plane exposed to methanol and methane gas. Simulations show that methanol from a surface aqueous layer slowly migrates into the ice lattice. Methane gas is preferentially adsorbed into the aqueous methanol surface layer. Possible consequences of the catalytic methane hydrate formation on hydrate plug formation in gas pipelines, on large scale energy-efficient gas hydrate formation, and in planetary science are discussed. Peer reviewed: Yes NRC publication: Yes