The Antarctic stratospheric nitrogen hole: Southern Hemisphere and Antarctic springtime total nitrogen dioxide and total ozone variability as observed by Sentinel-5p TROPOMI
Denitrification within the stratospheric vortex is a crucial process for Antarctic ozone hole formation, resulting in an analogous stratospheric “nitrogen hole”. Sedimentation of large nitric acid trihydrate polar stratospheric cloud particles within the Antarctic polar stratospheric vortex that for...
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Copernicus Publications
2024
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ftnonlinearchiv:oai:noa.gwlb.de:cop_mods_00072930 2024-05-19T07:32:32+00:00 The Antarctic stratospheric nitrogen hole: Southern Hemisphere and Antarctic springtime total nitrogen dioxide and total ozone variability as observed by Sentinel-5p TROPOMI de Laat, Adrianus van Geffen, Jos Stammes, Piet van der A, Ronald Eskes, Henk Veefkind, J. Pepijn 2024-04 electronic https://doi.org/10.5194/acp-24-4511-2024 https://noa.gwlb.de/receive/cop_mods_00072930 https://noa.gwlb.de/servlets/MCRFileNodeServlet/cop_derivate_00071119/acp-24-4511-2024.pdf https://acp.copernicus.org/articles/24/4511/2024/acp-24-4511-2024.pdf eng eng Copernicus Publications Atmospheric Chemistry and Physics -- http://www.atmos-chem-phys.net/volumes_and_issues.html -- http://www.bibliothek.uni-regensburg.de/ezeit/?2069847 -- 1680-7324 https://doi.org/10.5194/acp-24-4511-2024 https://noa.gwlb.de/receive/cop_mods_00072930 https://noa.gwlb.de/servlets/MCRFileNodeServlet/cop_derivate_00071119/acp-24-4511-2024.pdf https://acp.copernicus.org/articles/24/4511/2024/acp-24-4511-2024.pdf https://creativecommons.org/licenses/by/4.0/ uneingeschränkt info:eu-repo/semantics/openAccess article Verlagsveröffentlichung article Text doc-type:article 2024 ftnonlinearchiv https://doi.org/10.5194/acp-24-4511-2024 2024-04-22T23:50:58Z Denitrification within the stratospheric vortex is a crucial process for Antarctic ozone hole formation, resulting in an analogous stratospheric “nitrogen hole”. Sedimentation of large nitric acid trihydrate polar stratospheric cloud particles within the Antarctic polar stratospheric vortex that form during winter depletes the inner vortex of nitrogen oxides. Here, 2018–2021 daily TROPOspheric Monitoring Instrument (TROPOMI) measurements are used for the first time for a detailed characterization of this nitrogen hole. Nitrogen dioxide total columns exhibit strong spatiotemporal and seasonal variations associated with photochemistry as well as transport and mixing processes. Combined with total ozone column data two main regimes are identified: inner-vortex ozone- and nitrogen-dioxide-depleted air and outer-vortex air enhanced in ozone and nitrogen dioxide. Within the vortex total ozone and total stratospheric nitrogen dioxide are strongly correlated, which is much less evident outside of the vortex. Connecting the two main regimes is a third regime of coherent patterns in the total nitrogen dioxide column–total ozone column phase space – defined here as “mixing lines”. These mixing lines exist because of differences in three-dimensional variations of nitrogen dioxide and ozone, thereby providing information about vortex dynamics and cross-vortex edge mixing. On the other hand, interannual variability of nitrogen dioxide–total ozone characteristics is rather small except in 2019 when the vortex was unusually unstable. Overall, the results show that daily stratospheric nitrogen dioxide column satellite measurements provide an innovative means for characterizing polar stratospheric denitrification processes, vortex dynamics, and long-term monitoring of Antarctic ozone hole conditions. Article in Journal/Newspaper Antarc* Antarctic Niedersächsisches Online-Archiv NOA Atmospheric Chemistry and Physics 24 7 4511 4535 |
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article Verlagsveröffentlichung de Laat, Adrianus van Geffen, Jos Stammes, Piet van der A, Ronald Eskes, Henk Veefkind, J. Pepijn The Antarctic stratospheric nitrogen hole: Southern Hemisphere and Antarctic springtime total nitrogen dioxide and total ozone variability as observed by Sentinel-5p TROPOMI |
topic_facet |
article Verlagsveröffentlichung |
description |
Denitrification within the stratospheric vortex is a crucial process for Antarctic ozone hole formation, resulting in an analogous stratospheric “nitrogen hole”. Sedimentation of large nitric acid trihydrate polar stratospheric cloud particles within the Antarctic polar stratospheric vortex that form during winter depletes the inner vortex of nitrogen oxides. Here, 2018–2021 daily TROPOspheric Monitoring Instrument (TROPOMI) measurements are used for the first time for a detailed characterization of this nitrogen hole. Nitrogen dioxide total columns exhibit strong spatiotemporal and seasonal variations associated with photochemistry as well as transport and mixing processes. Combined with total ozone column data two main regimes are identified: inner-vortex ozone- and nitrogen-dioxide-depleted air and outer-vortex air enhanced in ozone and nitrogen dioxide. Within the vortex total ozone and total stratospheric nitrogen dioxide are strongly correlated, which is much less evident outside of the vortex. Connecting the two main regimes is a third regime of coherent patterns in the total nitrogen dioxide column–total ozone column phase space – defined here as “mixing lines”. These mixing lines exist because of differences in three-dimensional variations of nitrogen dioxide and ozone, thereby providing information about vortex dynamics and cross-vortex edge mixing. On the other hand, interannual variability of nitrogen dioxide–total ozone characteristics is rather small except in 2019 when the vortex was unusually unstable. Overall, the results show that daily stratospheric nitrogen dioxide column satellite measurements provide an innovative means for characterizing polar stratospheric denitrification processes, vortex dynamics, and long-term monitoring of Antarctic ozone hole conditions. |
format |
Article in Journal/Newspaper |
author |
de Laat, Adrianus van Geffen, Jos Stammes, Piet van der A, Ronald Eskes, Henk Veefkind, J. Pepijn |
author_facet |
de Laat, Adrianus van Geffen, Jos Stammes, Piet van der A, Ronald Eskes, Henk Veefkind, J. Pepijn |
author_sort |
de Laat, Adrianus |
title |
The Antarctic stratospheric nitrogen hole: Southern Hemisphere and Antarctic springtime total nitrogen dioxide and total ozone variability as observed by Sentinel-5p TROPOMI |
title_short |
The Antarctic stratospheric nitrogen hole: Southern Hemisphere and Antarctic springtime total nitrogen dioxide and total ozone variability as observed by Sentinel-5p TROPOMI |
title_full |
The Antarctic stratospheric nitrogen hole: Southern Hemisphere and Antarctic springtime total nitrogen dioxide and total ozone variability as observed by Sentinel-5p TROPOMI |
title_fullStr |
The Antarctic stratospheric nitrogen hole: Southern Hemisphere and Antarctic springtime total nitrogen dioxide and total ozone variability as observed by Sentinel-5p TROPOMI |
title_full_unstemmed |
The Antarctic stratospheric nitrogen hole: Southern Hemisphere and Antarctic springtime total nitrogen dioxide and total ozone variability as observed by Sentinel-5p TROPOMI |
title_sort |
antarctic stratospheric nitrogen hole: southern hemisphere and antarctic springtime total nitrogen dioxide and total ozone variability as observed by sentinel-5p tropomi |
publisher |
Copernicus Publications |
publishDate |
2024 |
url |
https://doi.org/10.5194/acp-24-4511-2024 https://noa.gwlb.de/receive/cop_mods_00072930 https://noa.gwlb.de/servlets/MCRFileNodeServlet/cop_derivate_00071119/acp-24-4511-2024.pdf https://acp.copernicus.org/articles/24/4511/2024/acp-24-4511-2024.pdf |
genre |
Antarc* Antarctic |
genre_facet |
Antarc* Antarctic |
op_relation |
Atmospheric Chemistry and Physics -- http://www.atmos-chem-phys.net/volumes_and_issues.html -- http://www.bibliothek.uni-regensburg.de/ezeit/?2069847 -- 1680-7324 https://doi.org/10.5194/acp-24-4511-2024 https://noa.gwlb.de/receive/cop_mods_00072930 https://noa.gwlb.de/servlets/MCRFileNodeServlet/cop_derivate_00071119/acp-24-4511-2024.pdf https://acp.copernicus.org/articles/24/4511/2024/acp-24-4511-2024.pdf |
op_rights |
https://creativecommons.org/licenses/by/4.0/ uneingeschränkt info:eu-repo/semantics/openAccess |
op_doi |
https://doi.org/10.5194/acp-24-4511-2024 |
container_title |
Atmospheric Chemistry and Physics |
container_volume |
24 |
container_issue |
7 |
container_start_page |
4511 |
op_container_end_page |
4535 |
_version_ |
1799470620636872704 |