Atmospheric N2O and CH4 total columns retrieved from low-resolution Fourier transform infrared (FTIR) spectra (Bruker VERTEX 70) in the mid-infrared region
Nitrous oxide (N2O) and methane (CH4) are two important greenhouse gases in the atmosphere. In 2019, mid-infrared (MIR) solar absorption spectra were recorded by a Bruker VERTEX 70 spectrometer and a Bruker IFS 125HR spectrometer at Sodankylä, Finland, at spectral resolutions of 0.2 and 0.005 cm−1,...
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ftnonlinearchiv:oai:noa.gwlb.de:cop_mods_00070003 2023-12-24T10:24:50+01:00 Atmospheric N2O and CH4 total columns retrieved from low-resolution Fourier transform infrared (FTIR) spectra (Bruker VERTEX 70) in the mid-infrared region Zhou, Minqiang Langerock, Bavo Sha, Mahesh Kumar Hermans, Christian Kumps, Nicolas Kivi, Rigel Heikkinen, Pauli Petri, Christof Notholt, Justus Chen, Huilin De Mazière, Martine 2023-11 electronic https://doi.org/10.5194/amt-16-5593-2023 https://noa.gwlb.de/receive/cop_mods_00070003 https://noa.gwlb.de/servlets/MCRFileNodeServlet/cop_derivate_00068368/amt-16-5593-2023.pdf https://amt.copernicus.org/articles/16/5593/2023/amt-16-5593-2023.pdf eng eng Copernicus Publications Atmospheric Measurement Techniques -- http://www.bibliothek.uni-regensburg.de/ezeit/?2505596 -- http://www.atmospheric-measurement-techniques.net/ -- 1867-8548 https://doi.org/10.5194/amt-16-5593-2023 https://noa.gwlb.de/receive/cop_mods_00070003 https://noa.gwlb.de/servlets/MCRFileNodeServlet/cop_derivate_00068368/amt-16-5593-2023.pdf https://amt.copernicus.org/articles/16/5593/2023/amt-16-5593-2023.pdf https://creativecommons.org/licenses/by/4.0/ uneingeschränkt info:eu-repo/semantics/openAccess article Verlagsveröffentlichung article Text doc-type:article 2023 ftnonlinearchiv https://doi.org/10.5194/amt-16-5593-2023 2023-11-27T00:22:45Z Nitrous oxide (N2O) and methane (CH4) are two important greenhouse gases in the atmosphere. In 2019, mid-infrared (MIR) solar absorption spectra were recorded by a Bruker VERTEX 70 spectrometer and a Bruker IFS 125HR spectrometer at Sodankylä, Finland, at spectral resolutions of 0.2 and 0.005 cm−1, respectively. The N2O and the CH4 retrievals from high-resolution MIR spectra have been well investigated within the Network for the Detection of Atmospheric Composition Change (NDACC) but not for MIR spectra gathered with instruments operating at low spectral resolution. In this study, N2O and CH4 retrieval strategies and retrieval uncertainties from the VERTEX 70 MIR low-resolution spectra are discussed and presented. The accuracy and precision of the VERTEX 70 N2O and CH4 retrievals are assessed by comparing them with the coincident 125HR retrievals and AirCore measurements. The relative differences between the N2O total columns retrieved from 125HR and VERTEX 70 spectra are −0.3 ± 0.7 (1σ) % with a correlation coefficient (R) of 0.93. Regarding the CH4 total column, we first used the same retrieval microwindows for 125HR and VERTEX 70 spectra, but there is an underestimation in the VERTEX 70 retrievals, especially in summer. The relative differences between the CH4 total columns retrieved from the 125HR and VERTEX 70 spectra are -1.3±1.1 (1σ) % with a R value of 0.77. To improve the VERTEX 70 CH4 retrievals, we propose alternative retrieval microwindows. The relative differences between the CH4 total columns retrieved from the 125HR and VERTEX 70 spectra in these new windows become 0.0±0.8 (1σ) %, along with an increase in the R value to 0.87. The coincident AirCore measurements confirm that the VERTEX 70 CH4 retrievals using the latter window choice are better, with relative mean differences between the VERTEX 70 CH4 retrievals and AirCore measurements of −1.9 % for the standard NDACC microwindows and of 0.13 % for the alternative microwindows. This study provides insight into the N2O and CH4 retrievals from the ... Article in Journal/Newspaper Sodankylä Niedersächsisches Online-Archiv NOA Sodankylä ENVELOPE(26.600,26.600,67.417,67.417) Atmospheric Measurement Techniques 16 22 5593 5608 |
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article Verlagsveröffentlichung Zhou, Minqiang Langerock, Bavo Sha, Mahesh Kumar Hermans, Christian Kumps, Nicolas Kivi, Rigel Heikkinen, Pauli Petri, Christof Notholt, Justus Chen, Huilin De Mazière, Martine Atmospheric N2O and CH4 total columns retrieved from low-resolution Fourier transform infrared (FTIR) spectra (Bruker VERTEX 70) in the mid-infrared region |
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article Verlagsveröffentlichung |
description |
Nitrous oxide (N2O) and methane (CH4) are two important greenhouse gases in the atmosphere. In 2019, mid-infrared (MIR) solar absorption spectra were recorded by a Bruker VERTEX 70 spectrometer and a Bruker IFS 125HR spectrometer at Sodankylä, Finland, at spectral resolutions of 0.2 and 0.005 cm−1, respectively. The N2O and the CH4 retrievals from high-resolution MIR spectra have been well investigated within the Network for the Detection of Atmospheric Composition Change (NDACC) but not for MIR spectra gathered with instruments operating at low spectral resolution. In this study, N2O and CH4 retrieval strategies and retrieval uncertainties from the VERTEX 70 MIR low-resolution spectra are discussed and presented. The accuracy and precision of the VERTEX 70 N2O and CH4 retrievals are assessed by comparing them with the coincident 125HR retrievals and AirCore measurements. The relative differences between the N2O total columns retrieved from 125HR and VERTEX 70 spectra are −0.3 ± 0.7 (1σ) % with a correlation coefficient (R) of 0.93. Regarding the CH4 total column, we first used the same retrieval microwindows for 125HR and VERTEX 70 spectra, but there is an underestimation in the VERTEX 70 retrievals, especially in summer. The relative differences between the CH4 total columns retrieved from the 125HR and VERTEX 70 spectra are -1.3±1.1 (1σ) % with a R value of 0.77. To improve the VERTEX 70 CH4 retrievals, we propose alternative retrieval microwindows. The relative differences between the CH4 total columns retrieved from the 125HR and VERTEX 70 spectra in these new windows become 0.0±0.8 (1σ) %, along with an increase in the R value to 0.87. The coincident AirCore measurements confirm that the VERTEX 70 CH4 retrievals using the latter window choice are better, with relative mean differences between the VERTEX 70 CH4 retrievals and AirCore measurements of −1.9 % for the standard NDACC microwindows and of 0.13 % for the alternative microwindows. This study provides insight into the N2O and CH4 retrievals from the ... |
format |
Article in Journal/Newspaper |
author |
Zhou, Minqiang Langerock, Bavo Sha, Mahesh Kumar Hermans, Christian Kumps, Nicolas Kivi, Rigel Heikkinen, Pauli Petri, Christof Notholt, Justus Chen, Huilin De Mazière, Martine |
author_facet |
Zhou, Minqiang Langerock, Bavo Sha, Mahesh Kumar Hermans, Christian Kumps, Nicolas Kivi, Rigel Heikkinen, Pauli Petri, Christof Notholt, Justus Chen, Huilin De Mazière, Martine |
author_sort |
Zhou, Minqiang |
title |
Atmospheric N2O and CH4 total columns retrieved from low-resolution Fourier transform infrared (FTIR) spectra (Bruker VERTEX 70) in the mid-infrared region |
title_short |
Atmospheric N2O and CH4 total columns retrieved from low-resolution Fourier transform infrared (FTIR) spectra (Bruker VERTEX 70) in the mid-infrared region |
title_full |
Atmospheric N2O and CH4 total columns retrieved from low-resolution Fourier transform infrared (FTIR) spectra (Bruker VERTEX 70) in the mid-infrared region |
title_fullStr |
Atmospheric N2O and CH4 total columns retrieved from low-resolution Fourier transform infrared (FTIR) spectra (Bruker VERTEX 70) in the mid-infrared region |
title_full_unstemmed |
Atmospheric N2O and CH4 total columns retrieved from low-resolution Fourier transform infrared (FTIR) spectra (Bruker VERTEX 70) in the mid-infrared region |
title_sort |
atmospheric n2o and ch4 total columns retrieved from low-resolution fourier transform infrared (ftir) spectra (bruker vertex 70) in the mid-infrared region |
publisher |
Copernicus Publications |
publishDate |
2023 |
url |
https://doi.org/10.5194/amt-16-5593-2023 https://noa.gwlb.de/receive/cop_mods_00070003 https://noa.gwlb.de/servlets/MCRFileNodeServlet/cop_derivate_00068368/amt-16-5593-2023.pdf https://amt.copernicus.org/articles/16/5593/2023/amt-16-5593-2023.pdf |
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ENVELOPE(26.600,26.600,67.417,67.417) |
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Sodankylä |
geographic_facet |
Sodankylä |
genre |
Sodankylä |
genre_facet |
Sodankylä |
op_relation |
Atmospheric Measurement Techniques -- http://www.bibliothek.uni-regensburg.de/ezeit/?2505596 -- http://www.atmospheric-measurement-techniques.net/ -- 1867-8548 https://doi.org/10.5194/amt-16-5593-2023 https://noa.gwlb.de/receive/cop_mods_00070003 https://noa.gwlb.de/servlets/MCRFileNodeServlet/cop_derivate_00068368/amt-16-5593-2023.pdf https://amt.copernicus.org/articles/16/5593/2023/amt-16-5593-2023.pdf |
op_rights |
https://creativecommons.org/licenses/by/4.0/ uneingeschränkt info:eu-repo/semantics/openAccess |
op_doi |
https://doi.org/10.5194/amt-16-5593-2023 |
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